• Title/Summary/Keyword: isopropanol

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Photochemical hydrogen production from coupled semiconductor systems : CdS-WO3/RuO2, CdS-TiO2 (혼합반도체 시스템에서의 광화학적 수소제조 : CdS-WO3/RuO2, CdS-TiO2)

  • Suh, J.K.;Heo, G.S.
    • Transactions of the Korean hydrogen and new energy society
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    • v.4 no.2
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    • pp.5-15
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    • 1993
  • Hydrogen production in visible light with the following semiconductor systems, $CdS-WO_3$, $CdS-TiO_2$, have been investigated in the presence of redox catalyst (Pt, $RuO_2$). MeOH, EtOH, isopropanol, sulfide/sulfite mixture, lactic acid were used as sacrifical reagents. The optimal condition for $H_2$ evolution was found to be in qgueous lactic acid media for $CdS-WO_3/RuO_2$. The photochemical efficiency for this system was 1.05 % and the $H_2$ evolution rate was 26.5ml/min. at $6.07{\times}10^{-5}$ einstein/sec photon rate

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SIMPLE EXTRINSIC FIBER OPTIC METHOD TO EVALUATE ABSORBANCE IN AQUEOUS NANOPARTICLE

  • Hanh, Nguyen Thi Kieu;Kulkarnib, Atul;Kim, T.
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1723-1726
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    • 2008
  • In recent years, there has been a remarkable progress in the development of the fiber optic sensors for the detection of various chemicals. Fiber optic sensors have the advantages of very small size, flexibility and low cost. The fiber optic sensors employing different optical or spectroscopic phenomena have been reported such as bulk absorption, optical reflectance, fluoresces and energy transfer. In this study, the effect of nanoparticle concentration in liquid upon light absorption and scattering was studied using extrinsic fiber optic method. For the evaluation, we used Red (650 nm) and Blue (430 nm) light sources which are coupled through the standard cuvette using optical fiber to detector. The experiments are carried out with Polystyrene latex (400 - 800 nm), and Silicon (35 - 110 nm) nanoparticles suspended in Isopropanol. Differences in light absorption and scattering depending on nanoparticle concentration and type are discussed. This method may be useful to study nanoparticles properties for various application and research.

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Studies on Rhodopesudomonas palustris in Korea (한국산 Rhodopseudomonas palustris에 관한 연구)

  • 김경식;이현순
    • Korean Journal of Microbiology
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    • v.14 no.4
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    • pp.167-175
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    • 1976
  • Twenty one strains of Rhodopseudomonas palustris from 7 different regions in Korea have been isolated and identified on the basis of Bergey's Manual in order to study their regional variation. They can use fructose as carbon source (or hydrogen donor). Capacity to produce molecular hydrogen during photosynthesis was tested using liquid medium, modified by omission of $NH_4Cl$ and addition of L0glutamic acid. As nitrogen source nitrate can be used, and isopropanol can be used as hydrogen donor. their pH ranges are 5.9 - 9.1. Their growth are inhibited in the medium that contains 100 units of penicillin G/ml. as for the growing test in dark aerobic condition, the period needed for adptation is longer than that of Korea strain of Rhodopseudomonas gelatinosa.

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Preparation and In-Vitro Evaluation of Gelatin Micropellets Containing Rifampicin (리팜피신 마이크로펠렛의 제조에 관한 연구)

  • Kim, Ki-Man;Kim, Hyun-Soo;Kim, Seung-In;Kim, Young-Il
    • Journal of Pharmaceutical Investigation
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    • v.18 no.1
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    • pp.23-30
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    • 1988
  • The sustained-release micropellets containing rifampicin were prepared by spray congealing micropelleting technique using gelatin as the embedding matrix, and hardened by treating with the formalin-isopropanol mixture. Dissolution of rifampicin from micropellets was significantly retarded, and greatly dependent on formalin concentration, hardening time and pH of the dissolution medium. It was found that this prolongation was more distinguished in pH 1.2 dissolution medium rather than pH 7.4, which might be attributed to the swelling characteristics of gelatin used in the dissolution medium. In-vitro dissolution kinetics indicated that the drug release followed the first-order process.

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Removal of Heavy Metal and ACE Inhibition of Yam Mucilage (마 점질물의 중금속 제거능과 ACE저해 효과)

  • 하영득;이삼빈;곽연길
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.27 no.4
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    • pp.751-755
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    • 1998
  • Functional properties of yam mucilage were investigated by physicochemical analysis. Yam mucilage was extracted from the root of yam and then separated into two fractions by its selective aggregation with isopropanol concentration. Each mucilge fraction showed the excellent binding properties with heavy metal ions Co, Cr and Cu. Cr showed the higher affinity with mucilage than Co and Cu at pH 6.3. In ACE inhibition, IC50 values of mucilage fraction 1 and 2 showed 8.99$\mu\textrm{g}$/${mu}ell$ and 7.1$\mu\textrm{g}$/${mu}ell$, respectively.

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Dry-jet Wet Spinning of Polyhydroxyamide Fibers

  • Park, Seung-Koo;Cho, Seo-Hyun;Farris, Richard-John
    • Fibers and Polymers
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    • v.1 no.2
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    • pp.92-96
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    • 2000
  • A high molecular weight polyhydroxyamide (PHA) solution in N, N-dimethyl acetamide (DMAc) was prepared from 3, 3'-dihydroxybenzidine and isophthalic chloride (IPC), which was used for spinning PHA fiber. Before spinning, the diffusion property of DMAc into various coagulants was examined. The fiber was well formed in coagulants such as water/ethanol with a composition of 5/5, ethanol, and ethanol/isopropanol with a composition of 7/3 and 5/5. However, the PHA fiber spun in the water/ethanol mixture contained voids. After the fiber spun in ethanol was annealed at over $350^{\circ}C$, the ultimate stress and initial modulus of the fiber increased from 75.5 MPa and 3.22 GPa to 369 MPa and 29.5 GPa, respectively. These properties of the PHA fiber spun by the dry spinning method were also enhanced, attaining 154 MPa and 5.56 Gpa, respectivel.

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Development of a New Nonvolatile and Nonflammable Soldering Flux (비휘발성이며 불연성인 새로운 납땜 Flux의 개발)

  • Bae, J.H.;Jang, Y.Y.;Lee, T.Y.;Cho, K.S.
    • Clean Technology
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    • v.6 no.2
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    • pp.101-106
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    • 2000
  • A new nonvolatile and nonflammable soldering flux was developed. This flux was synthesized with dichloropropane as its solvent instead of VOC solvents such as isopropanol and methanol etc. which had been used in the conventional flux. It was confirmed that the nonflammable and nonvolatile flux(NFV-flux) was better in insulation resistance, workability, and reliability and that it was better in the enviromment and safety of the working place and more economic in comparison with the conventional flux.

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Enantiomeric Ratio of Shikonin Derivatives as a Possible Key for the Determination of the Origin of Lithospermi Radix

  • Kang, Jong-Seong;Ahn, Byung-Zun;Gottfried-Blaschke
    • Archives of Pharmacal Research
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    • v.21 no.5
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    • pp.565-569
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    • 1998
  • An HPLC method was developed to resolve the enantiomers of shikonin derivatives of the Lithospermi Radix. The optimum mobile phase on a Chiracel AD column was 5% isopropanol in n-hexane with folw rate of 1 ml/min. Establishment of this method made possible to determine the ratios of shikonin/acetylshikonin or alkanin/acetylalkanin in the same root. The correlation of the ratios of these substance pairs appeared characteristic for the country where they were originated from. All of the Korean species showed significantly higher ratios of shikonin/acetylshikonin and alkanin/acetylalkanin than the Chinese ones. this method would be useful to determine the orgin of Lithospermi Radix.

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Effect of Water Content on Partitioning Behavior of Printing Ink Solvent on Food Ingredients Before and After Baking (수분이 식품성분과 인쇄 용제와의 분배계수에 미치는 영향)

  • An, Duek-Jun;Kim, Youn-Uck;Park, Hoon
    • KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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    • v.9 no.1
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    • pp.1-6
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    • 2003
  • The partitioning behavior of five printing ink solvents was studied in various cookie ingredients before and after baking which had different water content and different structure. Solvents were ethyl acetate, hexane, isopropanol, methyl ethyl ketone, and toluene which represent different characteristic functional groups. Gas chromatography (G.C.) was used to measure partitioning values at $25^{\circ}C$ on each raw and baked cookie ingredients. Baking condition of cookie ingredients was $260^{\circ}C$ for 10 min. In cookie ingredients, decreases in water content generally affected Kp of polar solvents, but did not affect that of the non-polar solvents. However, as water content decreased in the cookie ingredient, the Kp of the non-polar and polar solvents showed mixed results.

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Hydroiminoacylation of Allyl and Homoallyl Alcohol Derivatives with Benzalimide and Solvolysis of Hydroacylated Products

  • 홍준배;전철호
    • Bulletin of the Korean Chemical Society
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    • v.16 no.4
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    • pp.363-369
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    • 1995
  • Hydroiminoacylations of allyl and homoallyl alcohol and their derivatives with benzaldimine by Wilkinson's complex have been studied. All these terminal alkene derivatives except allyl alcohol were hydroacylated according to anti-Markownikoff's rule to give the corresponding linear alkyl compounds without showing oxygen directing effect, even though hydroiminoacylation of 3-acetoxy-1,5-hexadiene showed strong allyloxy directing effect over homoallyloxy directing effect in a 92:8 ratio. Solvolysis of 4-acetoxy-1-phenylbutan-1-one, previously prepared by hydroiminoacylation, in ethanol led to etherification giving 4-ethoxy-1-phenylbutan-1-one through neighbouring group participation, while that of 5-acetoxy-1-phenylpentan-1-one led to common transesterification giving 5-hydroxy-1-phenylpentan-1-one. Application of branched alkanols such as isopropanol and t-butanolin solvolysis of 4-acetoxy-1-phenylbutan-1-one underwent competition between etherification and transesterification.