• Journal of the Korean Chemical Society
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• v.7 no.3
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• pp.197-202
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• 1963

The ${\alpha}-and\;{\beta}$-isomer of 4-nitroazoxybenzenes have been separated by liquid chromatography and their U.V. spectra were examined. The n${\to}{\pi}^{\ast}$ transition band of the compounds did not appear, likewise the cases of other compounds of the series. Transition band of the new isomer were as usual as those of other azoxy-compounds, whereas the ${\pi}{\to}{\pi}^{\ast}$ transition band of the other isomer which is reported in the literature shown peculier hypochromic shift and hypochromic effect. From the spectroscopic point of view it is very likely that the new isomer (m.p. $184-5^{\circ}C$) is ${\alpha}$-isomer and the other one (m.p. $152^{circ}C$) is ${\beta}$-isomer contrary to the literature.

• Korean Journal of Materials Research
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• v.9 no.8
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• pp.854-857
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• 1999

The properties of Fe-Se-Te system(FeSe(sub)1-xTe(sub)x, x=0.2, 0.5, 0.8) have been studied by means of the X-ray diffraction method and Mossbauer spectroscopy. The results of X-ray diffraction patterns show that three samples have the ixed structure of tetragonal PbO and a small amount of hexagonal NiAs structure respectively. For x=0.5 the lattice parameters of tetragonal PbO structure are a=3.795$\AA$, c=5.896$\AA$ and c/a=1.55. The Mossbauer spectra were obtained with the various temperature variation and than they do not exhibit magnetic hyperfine structure but show a strong doublet. The values of observed isomer shift and quadrupole splitting suggest that the irons of all samples exist in the +2 oxidation state with a major covalent contribution. The temperature dependence of isomer shift values for x=0.8 seems to be originated from the second order Doppler effect.

• Journal of the Korean Magnetics Society
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• v.17 no.1
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• pp.26-29
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• 2007

Fe-based powders, Fe-M(M=Cr, Mn, Cu, Zn), were prepared in Ar gas by mechanical alloying and their crystallographic and magnetic properties were investigated. X-ray diffraction indicates that the cubic lattice parameter increases for the M substitution. The distance of closest approach around M can explained the increase of lattice constant in Fe-M powders. $M\"{o}ssbauer$ spectroscopy measurements on Fe-M samples indicates the coexistence of ferromagnetic phases and paramagnetic phase that are created by the distribution of local environment M on Fe atom. On the other hand, The spread of line-width on $M\"{o}ssbauer$ spectra can be explained by the distribution of hyperfine magnetic fields. The results of quadrupole shift and isomer shift revealed that M substitutions in Fe-M powders didn't change both structure and the local charge distribution around Fe atom severely.

• Journal of the Korean Magnetics Society
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• v.9 no.6
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• pp.271-277
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• 1999

Amorphous $Fe_{83}B_9Nb_7Cu_1$ alloy has been studied by M$\"{o}$ssbauer spectroscopy. Revised Vincze method was used and distributions of hyperfine field, isomer shift, and quadrupole line broadening of the sample at various temperatures have been evaluated and Curie temperature and $H_{hf}\;(0)$ were calculated to be 393 K and 231 kOe, respectively. Temperature variation of reduced average hyperfine field shows a flattered curvein comparison with the Brillouin curve for S=1. This behavior can be explained on the basis of Handrich molecular field model, in which the parameter Δ, which is a measure of fluctuation in exchange interactions, is assumed to have the temperature dependence ${Delta}=0.75-0.64{\tau}+0.47{\tau}^2$ where $\tau$ is $T/T_C$. At low temperature, the average hyperfine field can be fitted to $H_{hf}\;(T)=H_{hf}\;(0)\;[1-0.44\;(T/T_C)^{3/2}-0.28(T/T_C)^{5/2}-… ]$, which indicates the presence long wave length spin wave excitations. At temperature near TC, reduced average hyperfine field varies as $1.00\;[1-T/T_C]^{0.39}$. It is also found that half-width of the hyperfine field distribution was 102 kOe (3.29 mm/s) at 13 K and decreased monotonically as temperature increased. Above the Curie temperature, an average quadrupole splitting value of 0.43 mm/s was found. Average line broadening due to quadrupole splitting distribution was 0.31 mm/s at 13 K and decreases monotonically to 0.23 mm/s at 320 K, whereas that due to the isomer shift distribution is 0.1 mm/s at 13 K and 0.072 mm/s at 320 K, which is much smaller than that of both hyperfine field and quadrupole splitting. The temperature dependence of the isomer shift can be fitted within the harmonic approximation to a Deybe model with a Debye temperature ${Theta}_D=424{\pm}5K$.TEX>.

• Journal of the Korean Vacuum Society
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• v.6 no.4
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• pp.337-342
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• 1997

We have investigated Mossbauer effect and emission properties of the Fe-doped GaAs grown by liquid phase epitaxy (LPE). The powder type of isotope $^{57}Fe$ was used as a dopant source in LPE-GaAs. From the analysis of Mossbauer effect the value of isomer shift, 0.303$\pm$0.018 mm/sec, is calculated at low temperature. This means that charge state of Fe ion in GaAs is 3+. The results of double crystal x-ray rocking curve (DCRC) and low temperature photoluminescence (PL) show the crystal quality of the epitaxial layers are good. Unusual luminescence peaks from the Fe-GaAs epitaxial layers appeared at emission energy of 0.99 eV and 1.15 eV. We attribute these emissions to Fe-acceptor related two deep radiative centers.

• Journal of the Korean Magnetics Society
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• v.1 no.1
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• pp.1-5
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• 1991

The magnetic properties of the polycrystalline ${(Fe_{2}O_{3})}_{1-x-y}{(In_{2}O_{3})}_{x}{(Eu_{2}O_{3})}_{y}$(x=0.01, y=0.02과 x=0.02, y=0.03) have been studied by the methods of X-ray diffraction, $M\"{o}ssbauer$ effect, and magnetic hysteresis measurement. The X-ray diffraction patterns show that the samples have a same crystal structure as $\alpha-Fe_{2}O_{3}$. From the analysis of the temperature dependence of the quadrupole splitting and average half-width, it is found that the Morin transition occurs in the sample of x=0.01 and y=0.02 and the spin angle defined as the angle between the [111] crystal axis and antiferromagnetic vector, changes from about $35^{\circ}$ to the (111) plane as increasing the temperature in the sample of x=0.02 and y=O.03. The temperature dependence of magnetic hyperfine field is analyzed by using the spin-wave theory. The isomer shift values at room temperature are found to be given by about 0.35mm/s for the samples which means that the Fe ions belong to $3^{+}ion$. The temperature dependence of isomer shift was analyzed by using the Debye model.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1997.06a
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• pp.253-259
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• 1997

The iron doped GaAs single crystals were grown by liquid phase epitaxial method and its some physical properties were evaluated with a view to investigate the crystal quality and emission property. The isomer shift of 0.303mm/sec is calculated from low-temperature M ssbauer spectroscopy and we know that charge state of iron ion is 3+ in GaAs crystal. In low temperature photoluminescence, the deep emission bands with wide-line width have been observed at 0.99eV and 1.15eV in addition to sharp excitonic peaks. We attributed that these deep emissions are originated from substitutional Fe-acceptor which has charge state of 3+ and 2+, respectively.

• Journal of Magnetics
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• v.14 no.2
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• pp.86-89
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• 2009

Structural and magnetic properties of polycrystalline $CaFe_2O_4$ prepared by the solid state reaction method were studied using powder X-ray diffraction (XRD) and $M{\ddot{o}}ssbauer$ spectroscopy. The structure of $CaFe_2O_4$ belongs to an orthorhombic system (space group: Pnma) with the lattice parameters $a=9.2373\;{\AA}$, $b=3.0237\;{\AA}$, and $c=10.7124\;{\AA}$. Results of structural refinement indicate, however, that there are two slightly different iron sites in the sample. The $M{\ddot{o}}ssbauer$ spectrum at 4.2 K shows a hyperfine sextet with a hyperfine magnetic field and an isomer shift of 47.3 T and 0.36 mm/s, respectively. An examination of the spectrum revealed that the line widths of the spectral lines were not uniform. The degree of asymmetric line broadening decreases with increasing temperature, suggesting that the difference in the degree of crystalline distortions between two $FeO_6$ octahedra is eliminated as the temperature rises.

• Journal of the Mineralogical Society of Korea
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• v.9 no.2
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• pp.55-63
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• 1996

Epidote occurs as veinlets in the propylitic alteration zone of the Bobae clay deposit, Pusan, Korea. Its cell parameters apparently decrease with the contents of Al, Fe, and Ca. Fourier transform infrared (FTIR) spectra show one hydrosyl environment related to AlM2 at 3357-3358 cm-1. In the mid-infrared region, the peaks at 950 and 1030 cm-1 sharper with increasing Al shifting to higher energy region. The peak at 885 cm-1 shifts slightly to a lower energy region with a decreasing intensity as the Fe content increases. In the far-IR region, epidote exhibits absorption bands at 120 and 140 cm-1, which are related to the Ca-O bonds in A-sites.M ssbauer spectra of epidote show that the isomer shifts of Fe3+ range from 0.36-0.37 at the M3 site and from 0.35-0.44 at M1 site. Fe2+ shows the isomer shift ranging from 1.11 to 1.13. Quadrupole splitting is 2.04 for Fe3+M3, 0.52-0.70 for Fe3+M1, and 2.61-2.70 for Fe2+M3. Calculation shows Fe3+M386-90.7%, Fe3+M12.5-3.6%, and Fe2+M35.8-11.4% of total iron, showing preferential distribution of Fe3+ in the M3 site. The Fe3+M3 content is between 0.486 and 0.513 per formula unit. in the Fe-rich epidote, less Fe3+ and more Fe2+ are accommodated in the M1 and M3 sites. Hence, the overall disorder increases as total Fe content increase. The ordering parameter of the Bobae epidote is 0.93-0.95, suggesting a disequilibrium state below 200$^{\circ}C$. The constant temperature over a long period may be essential for the transition from disordered state to equilibrium state, despite the possible variation in flux and composition of the hydrothermal fluid.

• Journal of the Korean Magnetics Society
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• v.17 no.1
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• pp.34-37
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• 2007

The crystallographic and magnetic properties of $Fe_{0.9}Zn_{0.1}Cr_2S_4$ have been studied by X-ray diffractometer(XRD), vibrating sample magnetometer(VSM) and $M\"{o}ssbauer$ spectroscopy measurement. The crystal structure was determined by the normal cubic spinel of space group Fd3m and the lattice constant was $a_0=9.9967\;{\AA}$. The specific phenomenon which looks like cusp pattern at 77 K was observed in magnetization corves(ZFC : Zero Field Cooling) under 100 Oe applied field. $N\acute{e}el$ temperature($T_N$) was determined to be 153 K by VSM and $M\"{o}ssbauer$ spectra. The asymmetric 8-line profile has been observed at 4.2 K, which was attributed by the colossal electric quadupole interaction(${\Delta}E_Q$), ${\Delta}E_Q$ has 2.22 mm/s at 4.2 K. The ${\Delta}E_Q$ abruptly decreases around 77 K and then it disappears above 77 K with diminishing of 8-line pattern. The isomer shift $\delta$ at room temperature is 0.48 mm/s relative to Fe metal, which means that the charge state of Fe ions is ferrous in character.