• International Journal of Air-Conditioning and Refrigeration
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• 제7권
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• pp.55-68
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• 1999

In this study, computer simulation programs were developed for single-stage, two-stage, and three-stage condensation heat pumps and their performance with CFC11, HCFC123, HCFC141b was examined under the same external conditions. The results showed that the coefficient of performance(COP) of an optimized 'non-split type' three-stage condensation heat pump is 25-42% higher than that of a conventional single-stage heat pump. The increase in COP, however, differed among the fluids tested. The improvement in COP is largely due to the decrease in average LMTDs in condensers, which results in the decrease in thermodynamic irreversibility in heat exchange process. For the three-stage heat pump, the highest COP is achieved when the total condenser area is evenly distributed among the three condensers. For the two-stage heat pump, however, the optimum distribution of the total condenser area varies with an individual working fluid. For the three-stage system, 'splitting the condenser cooling water'for the use of intermediate and high pressure subcoolers helps increase the COP further. When the individual cooling water entering the intermediate and high pressure subcoolers is roughly 10% of the total condenser cooling water, the maximum COP is achieved showing roughly an 11% increase in COP as compared to that of the 'non-split type' heat pump.

• 태양에너지
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• 제10권1호
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• pp.14-21
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• 1990

단일 핀-관열교환기와 관련된 열역학적 최적설계법을 기준하여 핀-관열교환기의 엔트로피 생성율을 조사하였다. 엔트로피 생성율(비가역성)해석법을 사용하여 최적설계조건을 구하였고 설계조건의 변화에 따른 총엔트로피 생성율과 핀의 길이, 관의 안지름과 바깥지름 및 핀간거리를 조사하였다. 이 연구의 결과에 따르면 바깥지름이 클수록 최적핀간거리와 핀높이는 커지고 엔트로피 생성율과 최적안지름은 작아진다. 또한 핀 두께를 증가시키면 계의 엔트로피 생성율과 최적핀간거리는 증가하고 핀높이를 증가시키면 엔트로피 생성율과 최적바깥지름은 증가한다.

• 한국초전도ㆍ저온공학회논문지
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• 제17권3호
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• pp.1-4
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• 2015

Production of $MgB_2$ film on metallic Hastelloy with SiC as the buffer layer was achieved by means of hybrid physical-chemical vapor deposition technique, whereas SiC buffer layers with varied thickness of 170 and 250 nm were fabricated inside a pulsed laser deposition chamber. Superconducting transition temperature and critical current density were verified by transport and magnetic measurement, respectively. With SiC buffer layer, the reduced delaminated area at the interface of $MgB_2$-Hastelloy and the slightly increased $T_c$ of $MgB_2$ tapes were clearly noticed. It was found that the upper critical field, the irreversibility field and the critical current density were reduced when $MgB_2$ tapes were buffered with SiC buffer layer. Clarifying the mechanism of SiC buffer layer in $MgB_2$ tape in affecting the superconducting properties is considerably important for practical applications.

• Carbon letters
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• 제1권3_4호
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• pp.148-153
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• 2001

The initial irreversible capacity, $Q_i$, is one of the parameters to express the material balancing of the cathode to anode. We introduced new terms, which are the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface ($Q_{is}$), to express precisely the irreversibility of an electrode/electrolyte system. Two terms depended on kinds of active-materials and compositions of the electrode, but did not change with charging state. MPCF had the highest value of IIE and the lowest value of $Q_{is}$ in 1M $LiPE_6$/EC + DEC (1 : 1 volume ratio) electrolyte. IIE value of $LiCoO_2$ electrode was 97-98%, although the preparation condition of the material and the electrolyte were different. $Q_{is}$ value of $LiCoO_2$ was 0~1 mAh/g. MPCF-$LiCoO_2$ cell system had the lowest of the latent capacity. $Q_{is}$ value increased slightly by adding conductive material. IIE and $Q_{is}$ value varied with the electrolyte. By introducing PC to EC+DEC mixed solvent, IIE values were retained, but $Q_{is}$ increased. In case of addition of MP, IIE value increased and $Q_{is}$ value also increased a little.

• 대한기계학회논문집
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• 제12권3호
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• pp.582-589
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• 1988

본 연구에서는 작동유체로서 습공기를 사용하였을때 수반되는 응축에 의한 전 압손실을 실험과 수치해석을 통하여 정체점에 있어서의 습공기의 온도, 과포화도 및 노즐 팽창율의 효과와 액적 질량비 (g)과의 관계로서 구명하였다.

• 한국초전도ㆍ저온공학회논문지
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• 제18권1호
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• pp.1-5
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• 2016

Field and temperature dependence of the critical current density, Jc, were measured for both un-doped and carbon doped $MgB_2/Nb/Monel$ wires manufactured by Hyper Tech Research, Inc. In particular, carbon incorporation into the $MgB_2$ structure using malic acid additive and a chemical solution method can be advantageous because of the highly uniform mixing between the carbon and boron powders. At 4.2 K and 10 T, Jc was estimated to be $25,000-25,300Acm^{-2}$ for the wire sintered at $600^{\circ}C$ for 4 hours. The irreversibility field, $B_{irr}$, of the malic acid doped wire was approximately 21.0 - 21.8 T, as obtained from a linear extrapolation of the J-B characteristic. Interestingly enough, the Jc of the malic acid doped sample exceeds $10^5Acm^{-2}$ at 6 T and 4.2 K, which is comparable to that of commercial Nb-Ti wires.

• 대한기계학회논문집B
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• 제28권12호
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• pp.1573-1581
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• 2004

Thermodynamic principles are described with a new point of view. In present study, the interaction between two systems is focused instead of the behavior of a system in conventional thermodynamics. The state change of a system cannot occur by itself but it is the result of the interaction between systems. However, the interaction itself is also the result of another kind of interaction, the interaction between two interactions. To reconstruct thermodynamics with such a point of view, the reversible world is imagined, in which conservations and measurements are discussed. There exists a conserved quantity for each mode of reversible interaction. The conserved transferring quantity in the interaction between interactions is the effective work, which is supposed to be measurable and conserved in reversible world. Effective work is the primary concepts of energy. It is the key factor to explain measurements, energy conservation and energy dissipation. The concepts developed in reversible world are applied to the real world in which irreversible phenomena may occur. Irreversibility is the result of effective energy dissipation, in which effective work irreversibly changes into entropy. A quantitative relation between the disappearing effective work and the generated entropy is dissipation equation which is given by experiments. A special temperature scale to give a very simple type of the dissipation equation is the absolute temperature scale, which gives the conventional conservation of energy.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2010년도 제39회 하계학술대회 초록집
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• pp.172-172
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• 2010

$MgB_2$ doped with $TiO_2$ was prepared by the in-situ solid state reaction to study the effects of $TiO_2$ dopant on the flux pinning behavior of $MgB_2$ superconductor. From the field-cooled and the zero-field-cooled temperature dependences of magnetization, the realms of vortex-glass and vortex-liquid states of $TiO_2$-doped $MgB_2$ were determined in the H-T diagram (the temperature dependence of upper critical magnetic field and irreversibility line). The critical current density was estimated from the width of hysteresis loops in the framework of Beam's model at different temperatures. The results indicate that nano-scale $TiO_2$ inclusions play a role of the effective pinning centers and lead to the enhanced upper critical field and critical current density. It is suggested that the grain-boundary pinning mechanism is realized in $TiO_2$-doped $MgB_2$ superconductor.

• 한국초전도ㆍ저온공학회논문지
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• 제16권3호
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• pp.7-9
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• 2014

Single-crystal like $MgB_2$ thin film was grown on (000l) $Al_2O_3$ substrate by using hybrid physical-chemical vapor deposition (HPCVD) system. Single crystal properties were studied by X-ray diffraction (XRD) and the full width at half maximum (FWHM) of the (0001) $MgB_2$ peak is $15^{\circ}$, which is very close to that has been reported for $MgB_2$ single-crystal. It indicates that the crystalline quality of thin film is good. Temperature dependence on resistivity was investigated by physical property measurement system (PPMS) in various applied fields from 0 to 9 T. The upper critical field ($H_{c2}$) and irreversibility field ($H_{irr}$) were determined from PPMS data, and the estimated values are comparable with that of $MgB_2$ single-crystals. The thin film shows a high critical temperature ($T_c$) of 40.4 K with a sharp superconducting transition width of 0.2 K, and a high residual resistivity ratio (RRR=21), it reflects that $MgB_2$ thin film has a pure phase structure.

• KIEE International Transactions on Electrophysics and Applications
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• 제3C권5호
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• pp.189-193
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• 2003

Initial irreversible capacity (IIC) can be defined by means of the initial intercalation Ah efficiency (IIE) and the initial irreversible specific capacity at the surface (IICs) with the linear-fit range of the intercalation so as to precisely express the irreversibility of an electrode-electrolyte system. Their relationship was IIC = Qc - Q$_{D}$ = (IIE$^{-1}$ - 1) Q$_{D}$ + IICs in the linear-fit range of IIE. Here, Qc and Qd signify charge and discharge capacity, respectively, based on a complete lithium ion battery cell. Charge indicates lithium insertion to carbon anode. Two terms of IIE and IICs depended on the types of active materials and compositions of the electrode and electrolyte but did not change with charging state. In an ideal electrode-electrolyte system, IIE and IICs would be 100%, 0 mAh/g for the electrode and mAh for the cell, respectively. These properties can be easily obtained by the Gradual Increasing of State of Charge (GISOC).OC).