• Korean Journal of Soil Science and Fertilizer
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• v.17 no.2
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• pp.147-154
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• 1984

Two Fe-hydrous oxide A,B and one Al-hydroxide minerals were synthesized precipitating Fe $Cl_3$ and $AlCl_3$ with alkali solution(NaOH) at pH 6.0, 12.0 and 4.5 respectively, for precise understanding of physico-chemical and surface charge characteristics of soils in which these minerals are dominant. Identification of these final products, effect of free and amorphous materials on X-ray diffraction analysis, particle size distribution and surface change characterics of these minerals were performed. Fe-hydroxide A and B were identified as great deal of X-ray amorphous material and as goethite with large amount of X-ray amorphous material, respectively. Dehydration by oven at $105^{\circ}C$ of these minerals exhibited akaganeite peaks with low X-ray amorphous hump and pure goethite peaks for Fe-hydroxide A and B, respectively. Both minerals, however, turned into hematite upon firing at $550^{\circ}C$. On the other hand, Al-hydroxide identified as mixture of gibbsite and bayerite of around 7:3 ratio. Application of sodium dithionite and ammonium oxalate solutions for removal of free or amorphous Fe and Al from these minerals revealed that only peak intensities of Al-hydroxide system were enhanced upon Al-extraction by oxalate solution even though dithionite solution was much powerful to extract Fe from Fe-hydrous oxide systems. Original(wet) Fe-hydrous oxide A has the highest specific surface and surface charge development(negative and positive), and the greatest amount of less than $2{\mu}m$ sized particles. Specific surface and clay sized particles(less than $2{\mu}m$) of Fe-hydrous oxide A, however, were drastically reduced upon dehydration($P_2O_5$ and oven drying) compare to the rest minerals. The Z.P.C. of these synthetic minerals were 8.0-8.5, 7.5-8.0 and 5.5-6.0 for Fe-hydrous oxide A, B and Al-hydroxide, respectively.

• Asian-Australasian Journal of Animal Sciences
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• v.15 no.1
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• pp.26-33
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• 2002

In order to assess the effect of feeding raw or processed cotton (Gossypium) seed meal (CSM) on meat and wool production, 30 male crossbred lambs (3-4 months) of uniform body weight were assigned equally to five dietary treatments in a completely randomised design. The CSM was processed by three different methods i.e., cooking the meal at $100^{\circ}C$ for 45 minutes, treatment with 1% calcium hydroxide ($Ca(OH)_2$) for 24 h and iron treatment in the ratio of 1 part free gossypol (FG) to 0.3 parts of iron for 30 minutes. The lambs were fed isonitrogenous and isocaloric concentrate mixtures, containing 30% deoiled peanut meal (reference diet) and 40% of either raw, cooked, $Ca(OH)_2$ or iron treated CSM for 180 days. The raw and variously processed CSM replaced about 50% nitrogen of reference concentrate mixture. The concentrate mixtures were fed to meet 80% of the protein requirements (NRC, 1985) along with ad libitum chopped maize (Zea mays) hay. The slaughter weight, empty body weight and carcass weight was higher ($p{\leq}0.01$) in lambs fed cooked CSM incorporated diets, compared to diets containing deoiled peanut meal (DPNM). These parameters were not influenced by feeding diets containing either raw, $Ca(OH)_2$ or iron treated CSM in comparison DPNM diets. The carcass length, loin eye area and edible and inedible portion of carcass and the meat: bone ratio in whole carcass were also not affected by feeding CSM based diets. Among various primal cuts, the yield of legs was lower ($p{\leq}0.05$) from raw CSM fed lambs in comparison to DPNM fed lambs. The fat content in the Longissimus dorsi muscle was reduced ($p{\leq}0.05$) in lambs fed processed CSM based diets compared to those fed DPNM diet. Replacing DPNM with either raw or processed CSM based diets did not influence the sensory attributes and overall acceptability of meat. The wool yield was higher ($p{\leq}0.05$) in iron treated CSM fed lambs. The fibre length and fibre diameter were comparable among lambs on various dietary regimes. Among lambs fed variously processed CSM diets, the feed cost per kg of edible meat production was lower ($p{\leq}0.05$) on $Ca(OH)_2$ treated CSM, followed by cooked CSM diet and then on raw CSM based diets compared to DPNM diet. The CSM after 1% $Ca(OH)_2$ treatment or cooking for 45 minutes appears to be a satisfactory protein supplement in lamb diets for meat and wool production to replace at least 50% nitrogen of scarce and costly peanut meal.

• Journal of the Korean Chemical Society
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• v.17 no.1
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• pp.15-19
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• 1973

A method was developed for the separation of titanium, niobium and zirconium together in a group from the coexisting ions of various metals such as iron, cobalt, nickel, yttrium and rare earths by means of the cation exchange column using ${\alpha}$-hydroxyisobutyric acid as the eluent. In the course of the present investigation, it was found that the tailing phenomena of zirconium were attributable to the hydroxide precipitation which was made prior to the elution. For example, if zirconium was precipitated by sodium hydroxide, the tailing of zirconium became very serious in contrast to the results reported by others. This paper describes how these tailing phenomena of zirconium were prevented and how a practical procedure for the separation of these ions was, achieved using ion-exchange method. Using the present method the nuclides of $^{90m}Y$ and $^{90}Y$ were separated with radiochemical purity from the irradiated zirconium.

• Clean Technology
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• v.21 no.2
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• pp.108-116
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• 2015

Hydrogen sulfide and ammonia are one of the common malodorous compounds that can be found in emissions from many sewages treatment plants and industrial plants. Therefore, removing these harmful gases from emissions is of significance in both life and industry because they can cause health problems to human and detrimental effects on the catalysts. In this work, pyrolytic carbon blacks from waste tires were used to develop adsorbent with good adsorption capacity for removal of hydrogen and ammonia. Pellet-type adsorbents were prepared by a mixture of carbon black, metal oxide and sodium hydroxide or hydrochloric acid, and their adsorption capacities were estimated by using breakthrough curve of a continuous fixed bed adsorption column at ambient condition. The adsorbent manufactured with a mixture of carbon black, iron oxide(III) and sodium hydroxide showed the maximum working capacity of hydrogen sulfide. For ammonia, maximum working capacity was obtained by the adsorbent manufactured with a mixture of carbon black, copper oxide(II) and hydrochloric acid.

• Journal of Korean Society on Water Environment
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• v.22 no.6
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• pp.991-995
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• 2006

The layered double hydroxide with the insertion of chloride ions (LDH-Cl), which was synthesized by the co-precipitation method, was applied to investigate the fundamental aspects of the absorptive agent for phosphate removal from wastewater. The adsorption capacity was best described by the Langmuir-FreundIich isotherm, and the estimated isotherm parameters indicate that the LDH-CI capacity for the phosphate removal is much higher than that observed using a natural adsorbent material such iron oxide tailing. The kinetic experiment also showed that the LDH-Cl adsorption reaction rapidly at the adsorptive rate of 0.55 mg-P/g-LDH/min, implying that this adsorbent can be of use in the full-scale applications. The pH had a minimal effect on the LDH adsorption capacity in the range of 5 to 11, although the capacity dropped at the low pHs because of the change in LDH surface properties. Furthermore, other anions such as $Cl^-$ and $NO_3{^-}$ commonly found in the wastewater streams insignificantly affected the phosphate removal efficiencies, while $HCO_3{^-}$ ions had a negative effect on the LDH adsorption capacity due to its high selectivity. The phosphate removal experiment using the actual secondary effluent from a wastewater treatment plant showed the similar decrease in adsorption capacity, indicating that the bicarbonate ions in the wastewater were competing with phosphate for the adsorptive site in the surface of the LDH-Cl. Overall, the synthetic adsorbent material, LDH-Cl, can be a feasible alternative over other conventional chemical agents, since the LDH-Cl exhibits the high phosphate removal capacity with the low sensitivity to other environmental conditions.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1845-1850
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• 2012

Layered metal hydroxides (LMHs) containing calcium were synthesized by coprecipitation in solution having two different trivalent metal ions, iron and aluminum. Two mixed metal solutions ($Ca^{2+}/Al^{3+}$ and $Ca^{2+}/Fe^{3+}$ = 2/1) were added to sodium hydroxide solution and the final pH was adjusted to ~11.5 and ~13 for CaAl-and CaFe-LMHs. Powder X-ray diffraction (XRD) for the two LMH samples showed well developed ($00l$) diffractions indicating 2-dimensional crystal structure of the synthesized LMHs. Rietveld refinement of the X-ray diffraction pattern, the local structure analysis through X-ray absorption spectroscopy, and thermal analysis also confirmed that the synthesized precipitates show typical structure of LMHs. The chemical formulae, $Ca_{2.04}Al_1(OH)_6(NO_3){\cdot}5.25H_2O$ and $Ca_{2.01}Fe_1(OH)_6(NO_3){\cdot}4.75H_2O$ were determined by inductively coupled plasma-atomic emission spectroscopy (ICP-AES). Particle morphology and thermal behavior for the synthesized LMHs were examined by field emission scanning electron microscopy and thermogravimetricdifferential scanning calorimetry.

• Journal of Soil and Groundwater Environment
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• v.27 no.5
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• pp.10-17
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• 2022

Inorganic acids such as HCl, HNO₃, and H₂SO₄ have been commonly applied to soil washing of heavy metals-contaminated soil due to their cost-effectiveness. However, implementing the 'Chemical Substance Control Act' requires off-site risk assessment of the chemicals used in the soil washing. Therefore, in this study, organic acids or Fe(III)-based washing agents were evaluated to replace commonly used inorganic acids. Ferric removed heavy metals via H⁺ generated by hydrolysis, which is similar to the HCl used in the control group. Oxalic acid and citric acid were effective to remove Cu, Zn, and Cd from soil. Organic acids could not remove Pb because they could form Pb-organic acid complexes with low solubility. Furthermore, Pb could be adsorbed onto the iron-organic acid complex on the soil surface. Ferric could remove exchangeable-carbonate, Fe-Mn hydroxide, and organic matter and sulfides bound heavy metals (F1, F2, and F3). Organic acids could remove the exchangeable-carbonate and Fe-Mn hydroxide bound metals (F1&F2). Therefore, this research shows that the fractionation of heavy metals in the soil and the properties of washing agents should be considered in the selection of agents in the process design.

• Journal of the Mineralogical Society of Korea
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• v.21 no.2
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• pp.139-159
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• 2008

Geochemical analysis of the various kinds of water including observation borehole groundwater was carried out for the assessment of the hydrological safety of the underground oil storage cavern and the potentiality of mineralogical and microbiological clogging was estimated. Most of water samples belonged to $Ca-HCO_3$ and $Ca-HCO_3-SO_4$ types. There was no distinct chemical difference in the various kinds of water. All kinds of water are undersaturated with the calcite which is the major clogging mineral. Most water samples have low Fe and Mn concentrations. However, they are saturated or oversaturated with the iron-oxide/hydroxide minerals and have high dissolved oxygen contents which suggests the possibility of clogging by the iron-oxide/hydroxide minerals as a long-term aspect. Several water samples from the ground observation borehole also show the high saturation indices far the clay minerals, which can fill up the fractures, indicating the possibility of clogging by the clay minerals. Statistical analysis shows the degree of mineral precipitation or dissolution is mainly controlled by pH, Eh and DO of water samples. According to the microbial analysis, the aerobic microbes and slime forming bacteria are dominant in most water samples and anaerobic microbes including sulfate reducing bacteria are very low or not detected. Although the slime forming bacteria which are known as a main microbial cause of the clogging is lower than $10^5\;CFUs/mL$ in all water samples, because the slime forming bacteria are dominant microbe in several observation boreholes, the clogging can be caused by it as a long-term aspect. In addition, the possibility of clogging can be increased if the microbial effect is combined with the mineralogical effect such as iron oxide/hydroxide minerals for the possibility of clogging. Therefore, the systematic and long-term program for the assessment of clogging is required for the safe operation of underground oil storage cavern.

• Journal of Soil and Groundwater Environment
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• v.10 no.1
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• pp.58-64
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• 2005

Several tests were conducted to determine the optimum operational conditions of soil washing techniques for floe-forming arsenic-contaminated soils, collected from D abandoned Iron-mine in Korea. The optimum cut-off size was 0.15 mm $(sieve\;\#100)$, about $94\%$ of the mass of soils. Both sodium hydroxide and hydrochloric acid were effective to remove arsenic and the optimum mixing ratio (soil [g] : washing solution [mL]) was 1:5 for both washing agents. Arsenic concentrations, determined by KST Methods, for the dried floe solids obtained from flocculation at pH 5-6 were $990\~1,086\;mg/kg$ dry solids, which were higher concentrations than at the other pH values. Therefore, batch tests for sequential washings with or without removing floc were conducted to find the enhancement of washing efficiencies. After removing floe with 0.2 M HCl, sequential washings of 1 M HCl followed by 1 M NaOH showed the best results (15 mg/kg dry soil). The arsenic concentrations of washing effluent from each washing step were about $2\~3\;mg/L$. However, when these acidic and basic effluents were mixed together, arsenic concentration was decreased to be less than $50\;{\mu}g/L$, due to the pH condition of coagulation followed by precipitation for arsenic removal.

• Journal of the Korean Recycled Construction Resources Institute
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• v.11 no.1
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• pp.9-15
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• 2023

The cement is a typical CO₂ emission industry. Manufacturing process improvements and increased use of alternative materials are needed to reduce energy consumption and CO₂ emissions. This study confirmed the basic characteristics of cement hydration by sintering CAF at low temperature as a CO₂ adsorbent material. For the hydration product of the synthetic CAF, crystal phase analysis, porosity, and structural images were confirmed, and the compressive strength was measured. The replacement rate of SCAF was 10, 20, and 100 %, and the compressive strength tended to decrease as the replacement rate increased. In addition, when the SCAF substitution rate is 100 %, the hydration products of the early age are calcium aluminum oxide hydrate (Ca₃Al₂O₆ x H₂O) and calcium iron hydroxide (Ca₃Fe(OH)₁₂), and at substitution rates of 10 and 20 %, CAF compounds other than general cement hydrates brownmillerite was observed. As for the porosity, the pore size increased and the porosity increased with the increase of the replacement ratio. As a result of this study, CAF manufactured by low-temperature sintering seems to be difficult to use alone and general curing for utilization as a CO₂ adsorbing material.