• 제목/요약/키워드: iron mineral

검색결과 619건 처리시간 0.031초

A Study on the Recovery of Zn from Electric Arc Furnace Dust by Carbon Reduction

  • Joo, Sung-Min;Kim, Hyung-Seok;Ahn, Ji-Whan;Kim, Hwan;Lee, Kyung-Hoon;Sung, Ghee-Woong;Kim, Jang-Su;Lee, Park-Seok
    • 대한전자공학회:학술대회논문집
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    • 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
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    • pp.398-403
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    • 2001
  • There is a potential usability of electric arc furnace(EAF) dust produced during the iron manufacturing process as a recycled resource, because valuable materials such as Zn, Pb and Fe are contained in it. In this study, metallic Zn was recycled from the fine electric arc furnace dust by a solid state reduction method using carbon at relatively low temperature. It was possible to recover metallic zinc by using of high vapour pressure of zinc with this reduction method. The feasibility of recycled zinc for cold bonded pellet(CBP) was investigated. The main composition of EAF dust were franklinite(ZnFe$_2$O$_4$), magnetite(Fe$_3$O$_4$) and zincite(ZnO), and Pb and Cl were completely removed by a heat treatment in oxidation environment. The reduction ratio increased as the solid carbon content increased, and it increased with decreasing of dust particle size and increasing of compaction pressure due to a increase of contact area.

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생물환원 철광물촉매에 의한 지하수 내 RDX 환원:군사격장 현장적용 실증결과 (Reduction of RDX in Ground Water by Bio-Regenerated Iron Mineral: Results of Field Verification Test at a Miliary Shooting Range)

  • 공효영;이광표;이종열;경대승;이우진;배범한
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제20권6호
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    • pp.62-72
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    • 2015
  • This study investigates the in-situ implementation of bio-regenerated iron mineral catalyst to remove explosive compounds in ground water at a military shooting range in operation. A bio-regenerated iron mineral catalyst was synthesized using lepidocrocite (iron-bearing soil mineral), iron-reducing bacteria Shewanella putrefaciens CN32, and electron mediator (riboflavin) in the culture medium. This catalyst was then injected periodically in the ground to build a redox active zone acting like permeable reactive barrier through injection wells constructed at a live fire military shooting range. Ground water and core soils were sampled periodically for analysis of explosive compounds, mainly RDX and its metabolites, along with toxicity analysis and REDOX potential measurement. Results suggested that a redox active zone was formed in the subsurface in which contaminated ground water flows through. Concentration of RDX as well as toxicity (% inhibition) of ground water decreased in the downstream compared to those in the upstream while concentration of RDX reduction products increased in the downstream.

Alamine 336을 이용한 염화네오디뮴 수용액으로부터 Fe 제거 (Iron Removal from Neodymium Chloride Solution with Alamine 336)

  • 엄형춘;이진영;김철주;손정수;윤호성
    • Korean Chemical Engineering Research
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    • 제46권3호
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    • pp.512-515
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    • 2008
  • 본 연구는 염화네오디뮴 수용액으로부터 Fe 성분 제거를 위하여 Alamine 336을 이용한 Fe의 용매추출을 수행함에 있어서, Alamine 336의 농도, 염산 및 염소이온 농도에 따른 Fe 추출 특성 및 유기상으로 추출된 Fe의 탈거공정에 있어 상비와 탈거 용액의 염산 농도의 영향들을 고찰하였다. Alamine 336을 사용하여 Nd, Fe 혼합 용액으로부터 Fe 만을 선택적으로 추출할 수 있다는 것을 확인하였으며, 수상의 염산 및 염소이온 농도 증가에 의해 Fe의 추출율이 증가하였다. Fe가 추출된 Alamine 336을 증류수로 탈거할 경우 A/O비 4인 조건에서 99%의 Fe를 탈거할 수 있었으며, 탈거 용액의 염산 농도가 증가할수록 Fe 탈거율이 감소하였다.

고지방 식이를 섭취한 흰쥐의 비만지수 및 식이 아연과 철분 수준에 따른 혈청 미량무기질 함량 변화 (Effects of Dietary Zinc and Iron Levels on Serum Trace Minerals and Obesity Index in High Fat Diet-Induced Obese Rats)

  • 김현숙;승정자
    • 한국식품영양과학회지
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    • 제30권2호
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    • pp.325-330
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    • 2001
  • The purpose of this study was to evaluate the obesity index and effect of dietary zinc and iron levels on serum trace minerals status in the high fat diet-induced obese rats. Male Sprague-Dawley rats were randomly assigned to control and high fat diet groups. Ten weeks later, the control and high fat diet group were rearranged into six groups by zinc and iron levels. After 16 wk serum zinc, iron, copper and manganese was analyzed. Obesity index was significantly higher in the group fed high fat diet (20% lard) than that of control group (5% corn oil). Body fat content was 12.10$\pm$4.51g/100g BW in high fat diet group and 7.64$\pm$4.18g/100g BW in control group. So, the obese rats were successfully induced by high fat diet. The trace mineral concentration of obese rats in serum were affected by zinc levels. Serum zinc concentration was increased by dietary zinc overload, whereas the iron, copper and manganese were decreased. Specially the manganese concentration was significantly affected by zinc levels. In both groups, serum trace mineral concentration was not changed significantly by the dietary iron levels. There were positive correlations between zinc, iron and manganese concentration according to dietary zinc and iron levels.

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Mineral Concentration in Blood of Grazing Goats and Some Forage in Lahar-Laden Area of Central Luzon, Philippines

  • Orden, E.A.;Serra, A.B.;Serra, S.D.;Aganon, C.P.;Cruz, E.M.;Cruz, L.C.;Fujihara, T.
    • Asian-Australasian Journal of Animal Sciences
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    • 제12권3호
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    • pp.422-428
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    • 1999
  • The mineral status of native goats and forage species, namely; Cynodon plectostachyus, Pennisetum purpureum. Eleusine indica, Cynodon dactylon, Calopogonium muconoides, Centrosema pubescens, Leucaena leococephala, and Mimosa pudica in lahar affected areas of Concepcion, Tarlac, Philippines were determined. Forage and blood samples were collected six times in 1996-97, and analyzed for calcium, phosphorus, magnesium, sulfur, copper, iron, molybdenum, selenium, and zinc. Forage calcium and sulfur are non-limiting. Most species had low phosphorus, copper and selenium, while some had magnesium and zinc levels lower than the critical limit because of low mineral content and high percolation rate of lahar deposits. Iron and molybdenum were in excess. The effect of seasonal variation was observed only in copper, sulfur and iron. Average blood mineral concentration of the animals was above critical limit, but there were no significant differences between seasons. All the animals had plasma phosphorus and magnesium above critical level; but 20 % had low copper, zinc and selenium especially in dry season possibly due to insufficient amount of these elements and excessive molybdenum and iron in most forage. Conversely, calcium in forage was high; but 40 % of the animals had low plasma calcium concentration. Although no clinical signs of mineral deficiencies were observed, supplemental feeding would be important since the condition of the pasture in lahar-laden areas is not expected to improve in the next five years. Intensified use of L. leucocephala with better mineral profile would be ideal.

수중 세슘 제거를 위한 층상 황화 금속 물질 자성화 연구 (A Study on Magnetization of Layered Metal Sulfide for the Removal of Cesium Ions from Aqueous Solution)

  • 전철민;박지원;류정호;장정윤;조동완
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제28권4호
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    • pp.1-5
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    • 2023
  • In the fabrication of magnetic adsorbent by incorporating iron species on base materials with layered structure, there can be a potential loss of adsorption capacity from the penetration of dissolved iron species into the structure. This work newly synthesized a magnetic adsorbent by incorporating nano magnetite and glucose into layered metal sulfide via hydrothermal treatment, and tested the removal efficiencies of cesium ions (Cs+) by the adsorbents fabricated under different conditions (final temperature and glucose mass ratio). As a result, the optimal fabrication condition was found to be mass ratio of 1 (layered metal sulfide): 0.1 (nano magnetite): 0.4 (glucose) and final temperature of 160℃. As-prepared adsorbent possessed good adsorption ability of Cs+ (54.8 mg/g) without a significant loss of adsorption capacity from attaching glucose and nano magnetite onto the surface.

자폐증 아동의 영양소 섭취 및 두발과 소변 중의 무기질 함량에 관한 연구 (The Study of Nutrient Intake and Mineral Contents of Hair and Urine in Autistic Children)

  • 허귀엽;손숙미
    • 대한지역사회영양학회지
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    • 제1권3호
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    • pp.346-353
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    • 1996
  • The anthropometric measurements, nutrient intake, concentrations of minerals in scalp hair and urine and urinary 5-hydroxyindoleacetic acid(5-HIAA) of 30 autistic children not taking psychoactive drugs and 30 nonautistic control children were determined. The autistic children were taking significantly lower amounts of vitamin A, niacin, ascorbic acid and iron. The intake of vitamin A, niacin, and iron in autistic children were found to be 22$\%$, 75$\%$ and 58 of RDA, respectively. The decreased anthropometric measurements in height and weight of autistic children seems partly due to lower intake of these micronutrients. The food intake in vitamin and mineral group of autistic children was significantly lower. It is probably related to decreased intake of fruit in autistic children. There was no toxicity of cadmium and aluminum in both groups according to their contents in scalp hair. Autistic children showed elevated levels of hair calcium and zinc but lowered levels of copper and iron. The urinary excretion urinary excretion of 5-HIAA.

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3차원 모델링을 활용한 북한 무산광산일대의 자원량 및 생산량 추정 (3D Modeling Approaches in Estimation of Resource and Production of Musan Iron Mine, North Korea)

  • 배성지;유재형;고상모;허철호
    • 자원환경지질
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    • 제48권5호
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    • pp.391-400
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    • 2015
  • 남한은 철강의 수요나 생산에 비해 그 원료가 되는 철광석의 생산이 미약한 반면, 북한은 상당한 철 매장량을 보유하고 있으나 자원량에 비해 생산량이 극히 미진하다. 또한 북한의 폐쇄성으로 인해 북한의 자원에 대한 정보가 미비하고, 그 신뢰성에 의문이 있다. 본 연구는 북한의 철광산 중 세계적인 노천광산으로 알려진 무산광산을 대상으로, Landsat MSS, ASTER 위성영상자료와 수치지형도를 통해 1976~2007년 사이의 자원량과 생산량을 추정하였다. 원격탐사를 통해 산정한 무산광산의 넓이는 1976년을 기준으로 총 약 $6.1km^2$의 면적이 증가하였으며, 광산 내 채광지의 크기는 지도대수기법을 통해 $4.9km^2$로 산정되었다. 또한, 산정된 채광지 내 약 3.2억 $m^3$의 체적을 3차원 모델링을 이용하여 산출한 후, 무산광산과 동일한 암상으로 간주되는 중국 안산층의 철광석 평균밀도와 연산하여 약 7.3억 톤의 자원량과 약 2.4억 톤의 생산량을 추정하였다. 이 수치는 연 평균 810만 톤 수준의 생산량으로, 기존에 보고된 수치와 비교하였을 때, 상당한 일치성을 보였다. 본 연구는 남북자원교류사업을 위한 기초자료로써 유용하게 이용될 수 있을 것으로 기대된다.

생활폐기물(生活廢棄物) 소각(燒却) 바닥재의 자력선별(磁力選別)에 따른 크롬과 니켈의 거동(擧動) (Effect of magnetic separation in removal of Cr and Ni from municipal solid waste incineration (MSWI) bottom ash)

  • 안지환;엄남일;조계홍;오명환;유광석;한기천;조희찬;한춘;김병곤
    • 자원리싸이클링
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    • 제16권6호
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    • pp.3-9
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    • 2007
  • 생활 폐기물은 대부분 유리류와 자기류뿐만 아니라 많은 양의 iron을 함유하고 있으며 약 $3{\sim}11%$에 달한다. 대부분의 iron은 Ni-Fe와 Ni-Cr-Fe 같은 합금으로 존재하거나, 부식방지와 광택을 위해 Ni와 Cr로 도금된 iron으로 존재하고 있기 때문에 소각로에서 소각될 경우 철 재품 표면에 심하게 파손된 $Fe_3O_4$층과 함께 $NiFe_2O_4$FeCr_2O_4$을 형성하게 되어 바닥재에 존재하게 되어 중금속산화물 층을 형성시킬 수 있다. iron은 자력이 매우 강해 자력선별에 의해 쉽게 선별되며 이러한 효과로 인해 중금속 산화물의 선별까지 얻을 수 있다. 또한 바닥재는 다양한 Ni와 Cr 산화물들을 함유하고 있으며, Ni와 Cr은 강자성을 띈 물질이기 때문에 자력선별에 의해 큰 영향을 받을 수 있다. 따라서 자력선별에 따른 Ni와 Cr의 거동에 대해 조사하였으며 그 밖의 다른 중금속(Cu, Pb, Cd, As)들의 거동 또한 확인해 보았다. 그 결과 Ni와 Cr은 약 $45{\sim}50%$의 선별율을 보였으며, Cu와 Pb는 $15{\sim}20%$을 나타냈다. 또한 자력선별 전과 후의 바닥재에 대해 Ni와 Cr의 용출량을 확인해본 결과 자력선별 후 바닥재의 용출량이 더 낮음을 확인할 수 있었다.

구리, 니켈, 코발트, 철 혼합용액(混合溶液)으로부터 구리의 제거(除去) (Removal of Copper from the Solution Containing Copper, Nickel, Cobalt and Iron)

  • 박경호;남철우;김현호
    • 자원리싸이클링
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    • 제22권6호
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    • pp.48-54
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    • 2013
  • 니켈, 코발트와 철의 혼합용액에 미량 함유되어 있는 구리 (399 ppm 구리, 208 ppm 철, 15.3 g/L 니켈, 2.1 g/L 코발트)를 분리, 제거를 위한 방법들을 검토하였다. 중화침전법의 경우 용액의 pH가 7.0 에서 구리는 철과 함께 전부 수산화물로 침전, 제거되었으나 니켈과 코발트의 일부도 함께 침전되었다. 황화침전법의 경우 1.25% 농도의 $Na_2S$를 구리의 2당량비 첨가하고 용액의 pH가 1.0인 경우 구리가 99.7% 제거 되었다. TP207 양이온 흡착제를 사용한 이온교환수지법은 평형 pH 2.0 에서 구리만이 선택적으로 흡착되었으며 탈착용액으로는 5% 황산이 적당하였다.