• 제목/요약/키워드: iron depletion

검색결과 61건 처리시간 0.026초

리튬 함량 및 단위 셀 압력이 열전지용 리튬 음극의 방전 성능에 미치는 영향 (Effect of Lithium Contents and Applied Pressure on Discharge Characteristics of Single Cell with Lithium Anode for Thermal Batteries)

  • 임채남;안태영;유혜련;하상현;여재성;조장현;윤현기
    • 한국전기전자재료학회논문지
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    • 제32권2호
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    • pp.165-173
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    • 2019
  • Lithium anodes (13, 15, 17, and 20 wt% Li) were fabricated by mixing molten lithium and iron powder, which was used as a binder to hold the molten lithium, at about $500^{\circ}C$ (discharge temp.). In this study, the effect of applied pressure and lithium content on the discharge properties of a thermal battery's single cell was investigated. A single cell using a Li anode with a lithium content of less than 15 wt% presented reliable performance without any abrupt voltage drop resulting from molten lithium leakage under an applied pressure of less than $6kgf/cm^2$. Furthermore, it was confirmed that even when the solid electrolyte is thinner, the Li anode of the single cell normally discharges well without a deterioration in performance. The Li anode of the single cell presented a significantly improved open-circuit voltage of 2.06 V, compared to that of a Li-Si anode (1.93 V). The cut-off voltage and specific capacity were 1.83 V and $1,380As\;g^{-1}$ (Li anode), and 1.72 V and $1,364As\;g^{-1}$ (Li-Si anode). Additionally, the Li anode exhibited a stable and flat discharge curve until 1.83 V because of the absence of phase change phenomena of Li metal and a subsequent rapid voltage drop below 1.83 V due to the complete depletion of Li at the end state of discharge. On the other hand, the voltage of the Li-Si anode cell decreased in steps, $1.93V{\rightarrow}1.72V(Li_{13}Si_4{\rightarrow}Li_7Si_3){\rightarrow}1.65V(Li_7Si_3{\rightarrow}Li_{12}Si_7)$, according to the Li-Si phase changes during the discharge reaction. The energy density of the Li anode cell was $807.1Wh\;l^{-1}$, which was about 50% higher than that of the Li-Si cell ($522.2Wh\;l^{-1}$).

Experimental Studies on the Effect of Gamibaegi-eum

  • Kim Won-Ill
    • 대한한의학회지
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    • 제25권4호
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    • pp.61-78
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    • 2004
  • Objective : This study was undertaken to determine whether Gamibaegi-eum (BGU) in vitro and in vivo exerts a beneficial effect against cell injury induced by reactive oxygen species (ROS) in the human intestine. Methods : Effects of BGU in vitro on cell injury were examined using Caco-2 cells, cultured human intestinal cell line. Exposure of cells to H₂O₂ induced increases in the loss of cell viability in a time and dose-dependent fashion. Results : BGU prevented H₂O₂-induced cell death and its effect was dose-dependent over a concentration range of 0.05­1%. H₂O₂-induced cell death was prevented by catalase, the hydrogen peroxide scavenger enzyme, and deferoxamine, the iron chelator. However, the potent antioxidant DPPD did not affect H₂O₂-induced cell death. H₂O₂ increased lipid peroxidation, which was inhibited by BGU and DPPD. H₂O₂ caused DNA damage in a dose-dependent manner, which was prevented by BGU, catalase, and deferoxamine, but not DPPD. BGU restored ATP depletion induced by H₂O₂. BGU inhibited generation of superoxide and H₂O₂ and scavenged directly H₂O₂. Oral administration of mepirizole in vivo at a dose of 200mg/kg resulted in ulcer lesions in the stomach and the proximal duodenum. Pretreatment of BGU(0.1%/kg, orally) and catalase (800Units/kg, i.v.) significantly decreased the size of ulcers. Mepirizole increased lipid peroxidation in the mucosa of the duodenum, suggesting an involvement of ROS. Pretreatment of BGU and catalase significantly inhibited lipid peroxidation induced by mepirizole. Morphological studies showed that mepirizole treatment causes duodenal injury and its effect is prevented by BGU. Conclusion : These results indicate that BGU exerts a protective effect against cell injury in vitro and in vivo through antioxidant action. The present study suggests that BGU may playa therapeutic role in the treatment of human gastrointestinal diseases mediated by ROS.

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정상 구강 점막 소견의 구강 통증 환자의 진단 및 치료 (Treatment and diagnosis of oral pain without identifiable oral mucosa lesion)

  • 김태수;김상윤;남순열;노종렬;최승호
    • 대한기관식도과학회지
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    • 제14권1호
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    • pp.29-33
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    • 2008
  • Objectives : Oral pain without identifiable oral mucosa lesion is probably multifactorial origin, which include burning mouth syndrome (BMS), oral candidiasis and so on. The aim of this study was to analyze the characteristics of oral pain without identifiable oral mucosa lesion and to evaluate treatment outcome of those patients. Materials and Methods : We reviewed 50 patients without identifiable oral mucosa lesion who were complaint of oral pain. The patients were analyzed according tothe sites, associated symptoms, laboratory tests and fungus culture. The questionnaire included questions on their current diseases, smoking and alcoholic history, psychological factors, and symptoms. Results : The average age of patients was 60 years old. The most frequently involved site was tongue (92%), followed by palate, lower lip, oropharynx, and gingiva. 60% of the patients has psychological disorder as self reported. Culture for Candida was positive in 36% of patients and serum zinc deficiency was present in 60% of patients. Serum iron, vitamin B12, hemoglobin, folic acid deficiency were present in 6-2% of patients. Seventeen patients (65%) with BMS and twelve patients (66%) with oral candidiasis were improved after treatment. Conclusion : We recommend oral candida culture to oral pain patients without oral mucosa lesion. Zinc supplementation of zinc depletion patients may be helpful whereas other laboratory tests have no diagnostic values.

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지속가능한 휴폐광산 관리 및 공해 방지를 위한 환경.광산 지리정보체계 구축 및 개선 연구 - 환경부분 중심으로 - (A Study on Environmental.Mine Geographic Information System Approach for the Sustainable Mine Management and Prevention of Mine Hazards - Focused on the Environmental Section -)

  • 이주영;한무영;양중석;최재영
    • 환경정책연구
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    • 제8권1호
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    • pp.129-143
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    • 2009
  • 국내 광산은 1960년대 및 70년대에 원료자원확보를 위한 기간산업으로 육성 개발되었고, 90년대 이후 광량 고갈 및 국제자원가격 하락으로 인한 채산성 악화로 거의 대부분의 광산이 폐광되었으며, 대다수의 폐광산의 폐광석 및 광미 적치장의 관리가 불안전하여 오염물질의 확산으로 토양과 수질이 오염되고 있는 실정이다. 이러한 토양오염실태에도 불구하고 정확한 중금속 오염원 파악 및 위해성을 인지하지 못한 상태에서 지속적으로 환경오염에 노출되어 있어, 이로 인한 주변생태계 파괴가 우려되는 상황이다. 이에 본 논문에서는 현재 진행 중인 지속가능한 휴폐광산 정화 및 관리를 위한 기존 환경 광산지리정보시스템 활용뿐만 아니라 추가적 기능 확대방법에 관한 제언을 통해 정책결정자 및 관리자들이 체계적이고 통합적인 광해방지정책 마련과 사업에 이바지할 수 있도록 할 것이다.

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전과정평가(LCA)를 이용한 금속캔의 환경성 평가에 관한 연구 (A Study on Environmental Impact Evaluation of Metallic Can Using Life Cycle Assessment)

  • 백승혁;김형진;권영식;김승섭;최윤근;정찬교
    • 한국환경과학회지
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    • 제20권11호
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    • pp.1395-1401
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    • 2011
  • In this study, Life Cycle Assessment(LCA) has been carried out to evaluate the environmental impacts of a metallic can. A 360 mL volume of an aluminum can bottle was used as the functional unit. The results of Life Cycle Inventory(LCI) showed that iron ore and coal were the major parts of the input materials, whereas aluminum can products, carbon dioxide, wastewater, and hazardous wastes were those of the output ones. According to LCA weighting, it was observed that the most significant impact potential was found to be global warming(49.11%) followed by abiotic resource depletion(47.72%). In the whole system, cold rolled steel coil showed the largest environmental impact potential(86%), followed by electricity(14%). Meanwhile, lubricating oil and industrial water had the minor portion of the total environmental impact potentials. It was suggested that the use of cold rolled steel and electricity should be the main source for $CO_2$, resulting in the big impact on global warming.

간략화 전과정 평가(S-LCA) 기법을 이용한 전동차 구체의 환경성 평가 (Environmental Impact Assessment of the Carbody of a Electric Motor Unit(EMU) Using Simplified Life Cycle Assessment(S-LCA))

  • 이재영;목재규;정인태;김용기
    • 한국철도학회논문집
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    • 제8권6호
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    • pp.520-524
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    • 2005
  • It is consequential to reduce the environmental impact of a product for sustainable development in 21st Century. In the field of transportation, especially, the technological market concerned about reduction and assessment of greenhouse gas emission is expected to be extended. The LCA gas been esteemed and utilized as a realistic alternative greenhouse gas emission is expected to be extended. The LCA has been esteemed and utilized as a realistic alternative to improve the environment by the assessment of environmental impacts. In this study, simplified life cycle assessment(S-LCA), was performed to analyze the environmental impacts quantitatively, which were produced through the life cycle of a electric motor unit(EMU). The object of the present work is rth investigate main parameters of environmental impacts and to establish the plans to improve the environment impact of EMU. As a result of quantitative assessment for environmental impact and manufacturing, the EMU carbody made of SUS showed acidification(AD) and marine water aquatic ecotoxicity(MAET) the most, while that made of Mild showed high impact of global warning(GW) and abiotic resources depletion(ARD). For the SUS EMU, the high AD and MAET impact is occurred by the discharged pollutants during acid-washing process. Also, high value of GW and ARD for Mild EMU is resulted from the consumption of iron ore, coal and crude oil during manufacturing. Therefore, the environment impact of carbody would be decreased by enhancing of energy efficiency and the lightening the weight of it.

해수(海水)로부터 희유금속(稀有金屬) 회수(回收) 연구동향(硏究動向) (R&D Trends of Rare Metals Recovery from Seawater)

  • 김종헌;노경란;김상우;최성배;길상철
    • 자원리싸이클링
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    • 제22권6호
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    • pp.73-80
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    • 2013
  • 해양광물자원은 크게 해저면에 부존되어 있는 해저광물자원과 해수 중에 녹아 있는 해수광물자원으로 대별된다. 해수에는 막대한 양의 유용광물이 녹아 있어 회수기술 개발이 완료되면 상업화 가능성이 큰 것으로 알려져 있다. 21세기에 들어 육상금속자원의 저품위화 및 매장량 고갈에 따라 자원 보유국들이 자원을 무기화 하는 경향이 심화되고 있다. 따라서 대부분의 금속자원을 수입에 의존하는 우리나라는 삼면이 바다인 지리적 특성을 살려 해수로부터 희유금속 회수기술 개발에 적극적으로 나설 필요가 있다. 본 연구에서 해수로부터 희유금속 회수관련 논문분석 결과, 미국이 495편의 논문을 게재하여 양적 질적으로 가장 우수한 것으로 나타났다. 연구기관별로 보면 Chinese Acad. Sci.가 152편의 논문을 게재하여 양적으로 많은 연구가 이루어졌으며, 31편의 논문을 게재한 Univ. Oxford는 질적으로 가장 우수한 것으로 나타났다.

Hydrogen Peroxide-induced Alterations in Na+-phosphate Cotransport in Renal Epithelial Cells

  • Jung, Soon-Hee
    • 대한임상검사과학회지
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    • 제41권2호
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    • pp.83-92
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    • 2009
  • This study was undertaken to examine the effect of oxidants on membrane transport function in renal epithelial cells. Hydrogen peroxide ($H_2O_2$) was used as a model oxidant and the membrane transport function was evaluated by measuring $Na^+$-dependent phosphate ($Na^+$-Pi) uptake in opossum kidney (OK) cells. $H_2O_2$ inhibited $Na^+$-Pi uptake in a dose-dependent manner. The oxidant also caused loss of cell viability in a dose-dependent fashion. However, the extent of inhibition of the uptake was larger than that in cell viability. $H_2O_2$ inhibited $Na^+$-dependent uptake without any effect on $Na^+$-independent uptake. $H_2O_2$-induced inhibition of $Na^+$-Pi uptake was prevented completely by catalase, dimethylthiourea, and deferoxamine, suggesting involvement of hydroxyl radical generated by an iron-dependent mechanism. In contrast, antioxidants Trolox, N,N'-diphenyl-p-phenylenediamine, and butylated hydroxyanisole did not affect the $H_2O_2$ inhibition. Kinetic analysis indicated that $H_2O_2$ decreased Vmax of $Na^+$-Pi uptake with no change in the Km value. Phosphonoformic acid binding assay did not show any difference between control and $H_2O_2$-treated cells. $H_2O_2$ also did not cause degradation of $Na^+$-Pi transporter protein. Reduction in $Na^+$-Pi uptake by $H_2O_2$ was associated with ATP depletion and direct inhibition of $Na^+$-$K^+$-ATPase activity. These results indicate that the effect of $H_2O_2$ on membrane transport function in OK cells is associated with reduction in functional $Na^+$-pump activity. In addition, the inhibitory effect of $H_2O_2$ was not associated with lipid peroxidation.

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페로니켈슬래그를 혼입한 황토투수블럭 물성에 관한 연구 (A Study on the Properties of Hwangto Permeable Block Using Ferro Nickel Slag)

  • 김순호
    • 한국건축시공학회지
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    • 제22권6호
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    • pp.607-618
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    • 2022
  • 본 연구는 황토와 무기질 결합재의 수화반응을 이용하여 빗물저류조용 황토투수블록을 개발한 연구로서 제조과정의 산업부산물인 고로슬래그 미분말과 페로니켈슬래그 순환자원을 골재로 활용하고 황토투수블럭을 제작하여 물성분석을 하였다. 도심지 내 투수성 포장을 확대하고 공극이 막혀 투수기능 상실을 방지하여 우수유출저감용 빗물관리시설에 사용하기 위한 것으로써 도시지역에서 열섬현상과 도심 집중강우에 따른 도로침수 포장체 파손 등이 대한 방안으로 활용이 가능하다.

재제조 기술을 이용한 노후 플래너 밀러의 CNC 제어 장치 성능평가에 관한 연구 (A Study on the Performance Evaluation of CNC Control Units of an Old Planar Miller Using Remanufacturing Technology)

  • 이성원;정원지;노영화;공석환;이현준;김진우
    • 한국산업융합학회 논문집
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    • 제25권6_2호
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    • pp.1097-1102
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    • 2022
  • With the continuous development of the current industry, the current global environment is in a very serious situation, with resource supply and demand dependent on imports and huge costs for waste disposal due to the depletion of resources and mass generation of industrial waste. Its limitations have already been revealed in many fields, and the importance of re-manufacturing is drawing attention as a countermeasure to these problems. Re-manufacturing aims to recover products that are in the aging and disposal stages, recover to performance close to new products, and re-commercialize them. Among them, most of the machine tools are made of materials such as steel and cast iron with large structures, and raw materials are widely used when producing new products. In addition, since a lot of carbon is generated due to production, it is an object that can obtain a great re-manufacturing effect. Planner millers belonging to large machine tools are one of the machine tool equipment that can greatly reduce resources and energy through re-manufacturing because the structure is very large and the casting is several to tens of tons. Through this machine tool, performance tests and results are derived on the development of re-manufacturing source technology and domestic servo motor and CNC control device.