• 제목/요약/키워드: iron and manganese

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콘크리트용 골재로서 실리콘 망간슬래그의 물리적 적합성 평가 (Physical Suitability Evaluation of Silicon manganese slag as Aggregate for Concrete)

  • 정의인;김봉주;김진만
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2015년도 추계 학술논문 발표대회
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    • pp.41-42
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    • 2015
  • The concrete aggregate generates carbon dioxide in production but its demanding is gradually increased in accordance with the depletion of natural resources. Therefore we evaluated compatibility and basic physical properties of Silicon manganese slag generated in iron production as an applicable concrete aggregate. In our test, the silicon maganese slag shows 2.8g/㎥ of density in 10mm of maximum particle size similar to a natural aggregate, and its absorption rate was 0.3% similar to the electric furnace slag. Unit volume weight and ratio of absolute volume was respectively 2,001㎏/㎥ and 51%. Strength properties of Silicon manganese slag will be evaluated with further studies and experiments.

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UNS G41400 강의 인산염 표면 처리에 따른 국부 부식 저항성 (Effect of Phosphate Surface Treatment on the Localized Corrosion Resistance of UNS G41400 Steel)

  • 이준섭;박시욱
    • Corrosion Science and Technology
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    • 제22권6호
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    • pp.429-434
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    • 2023
  • This study investigated the localized corrosion behavior of a UNS G41400 steel surface treated with manganese phosphate. The phosphate coating, primarily composed of oxygen (O), phosphorus (P), and manganese (Mn) elements, had an approximate thickness of 6 ㎛. The particles comprising the coating varied in size by several micrometers; smaller particles were mainly composed of O, P, Mn, and iron (Fe) elements, indicating incomplete formation of the manganese phosphate film. Potentiodynamic polarization curves revealed a decrease in anodic current after surface treatment and a shift in corrosion potential toward the noble direction after treatment. After immersion in a 3.5 wt% NaCl solution for 96 hours, localized corrosion was observed, with some regions retaining residual phosphate film. Even though localized corrosion occurred on the treated surface, it was less severe than that on the untreated UNS G41400 steel surface. These findings suggest that manganese phosphate coating improved resistance to localized corrosion.

KURT 지하심부 지하수 내 토착 금속환원미생물의 종 다양성 및 철/망간의 환원과 생광물화작용 (Characterization of Microbial Diversity of Metal-Reducing Bacteria Enriched from Groundwater and Reduction/Biomineralization of Iron and Manganese)

  • 김유미;오종민;정혜연;이승엽;노열
    • 자원환경지질
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    • 제47권4호
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    • pp.431-439
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    • 2014
  • 이 연구의 목적은 KURT(KAERI underground research tunnel) 지하수 내에 금속이온을 환원시키는 미생물의 존재 여부를 확인하고 배양하여, 이들의 활동에 따른 철과 망간 환원의 관찰과 환원물의 광물학적 특성을 연구함으로써, 금속환원미생물에 의한 산화상태로 존재하는 철과 망간의 환원과 광물 상전이 가능성을 확인하는 것이다. KURT 지하수 내 금속을 환원하는 미생물은 전자공여체로 포도당, 초산, 젖산, 개미산, 피루브산을, 전자수용체로 Fe(III)-citrate를 사용하여 농화배양 하였으며, 16S rRNA 분석을 통해 종 다양성을 확인하였다. 농화배양된 금속환원미생물에 의한 철과 망간의 환원과 생광물화작용을 알아보기 위해 전자공여체로 포도당, 초산, 젖산, 개미산, 피루브산을, 전자수용체로 철수산화물인 아카가나이트(akaganeite, ${\beta}$-FeOOH)와 망간산화물(manganese oxide, ${\lambda}-MnO_2$)을 이용하여 금속환원 실험을 실시하였다. 미생물 활동에 의해 형성된 환원물의 광물학적 특성은 SEM, EDX, XRD 분석을 통해 확인되었다. 연구 결과 KURT 지하수에서 금속을 환원하는 혐기성 미생물로는 Fusibacter, Desulfuromonas, Actinobacteria, Pseudomonas sp. 등이 확인되었고, 이 미생물들은 체외에서 철과 망간을 환원하여 이들 광물의 상전이를 확인하였다. 철(Fe)은 $Fe^{3+}$을 포함한 아카가나이트(${\beta}$-FeOOH)에서 $Fe^{2+}/Fe^{3+}$를 포함한 자철석($Fe_3O_4$)으로 환원되었고, 망간(Mn)은 $Mn^{4+}$를 포함한 망간산화물(${\lambda}-MnO_2$)에서 $Mn^{2+}$을 포함한 능망간석($MnCO_3$)으로 환원되었다. 이러한 지하 140 m의 KURT 지하수에서 서식하는 미생물들에 의해 철과 망간이 환원됨은 다른 중금속과 핵종원소의 환원 가능한 환경이 조성되었을 뿐 만 아니라, 미생물에 의하여 환원된 철의 재산화에 의해서도 주변 핵종원소가 환원될 수 있음을 의미한다. 따라서 이러한 직 간접적인 산화-환원 반응에 의해 KURT 지하수 내에서는 금속환원미생물들이 유해금속물질을 침전시켜 이동성을 줄일 수 있을 뿐만 아니라 고준위 폐기물에서 유해물질의 유출시 핵물질의 확산을 막는데 중요한 역할을 할 수 있을 것으로 사료된다.

태평양 심해저 망간단괴 개발사업의 경제적 파급효과 (The Economic Impacts of Pacific Ocean Deep-sea Manganese Nodule Development Project)

  • 유승훈;정동원;박세헌
    • Ocean and Polar Research
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    • 제32권4호
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    • pp.489-499
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    • 2010
  • The securing of raw material is an important requirement for economic development. Many countries, including Korea, actively seek out a stable supply of minerals such as manganese. Manganese nodules are rock concretions on the sea bottom formed of concentric layers of iron and manganese hydroxides around a core and include several strategic minerals necessary for economic development. In particular, the manganese nodule development project (MNDP) plays an important role in the Korean national economy. This study attempts to apply input-output (I-O) analysis in investigating the economic impacts of the MNDP in the Korean national economy. A static I-O framework was employed, focusing on four topics in its application; the production-inducing impacts, the value-added-inducing impacts, the employment-inducing impacts and R&D-inducing impacts of MNDP investments on other sectors. To this end, several versions of the demand-driven models are utilized. In addition, inter-industry linkage analysis is performed to obtain information on the forward and backward linkage effects of industries, including MNDP, to quantify the strength of causation among these industries.

원자흡광 분광광도계에 의한 사료중 중김속의 정량 (Determination of Trace Metals in Formula Feed by Atomic Absorption Spectrophotometry)

  • Park, Sung Woo;Lee, Wan Koo
    • 한국환경보건학회지
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    • 제11권2호
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    • pp.55-63
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    • 1985
  • The quantities of chrome, lead, iron, copper and manganese in the formula feed were determined by A.A.S. and the results were summarized as follows 1. The content of chromium in the leather and meat meals(SN-2) were 13-66 times as much as the level of permission. 2. In the meantime, lead content in the meat meal (SN-1) was about 20 times as much as permitted level. 3. The iron which is essential constituent of the formula feed was contained in the meat and leather meals and these values were 2-10 times as much as feeding regulations, on the contrary copper and manganese content in the shaving and flesh were below the feeding regulations.

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일반계 및 다수계 현미와 백미의 무기질 함량 (Mineral Contents of Japonica and J/Indica Brown and Milled Rices)

  • 김성곤;한양일;김을상
    • 한국식품영양과학회지
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    • 제19권4호
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    • pp.285-290
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    • 1990
  • 일반계(34품종)와 다수계(25품종) 쌀의 무기질 함량은 현미에서는 인과 마그네슘, 백미에서는 철과 망간만이 유의적인 차이를 보였다. 무기질의 변이계수는 현미와 백미 모두 다수계 품종이 일반계 품종보다 낮았다. 일반계 현미의 칼슘, 마그네슘, 철, 구리, 망간 및 아연의 함량은 백미와 높은 정의 상관을 보엿으나, 다수계 현미의 경우에는 칼슘, 구리, 망간 및 아연은 높은 정의 상관을, 철은 높은 부의 상관을 보였다. 무기질 끼리의 상관관계는 현미보다 백미에서 일반계와 다수계 품종간에 비슷한 결과를 보였다.

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Performance of membrane filtration in the removal of iron and manganese from Malaysia's groundwater

  • Kasim, Norherdawati;Mohammad, Abdul Wahab;Abdullah, Siti Rozaimah Sheikh
    • Membrane and Water Treatment
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    • 제7권4호
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    • pp.277-296
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    • 2016
  • The aim of this research was to investigate the ability of nanofiltration (NF) and ultrafiltration (UF) membranes as a filtration unit for groundwater treatment for drinking water resources. Commercial membranes denoted as TS40, TFC-SR3 and GHSP were used to study the performance based on rejections and fluxes. The investigation has been conducted using natural groundwater obtained from a deep tube well with initial concentration of iron (Fe) and manganese (Mn) at 7.15 mg/L and 0.87 mg/L, respectively. Experimental results showed that NF membranes exhibited higher fluxes than UF membrane with pure water permeability at 4.68, 3.99 and $3.15L.m^{-2}.h^{-1}.bar^{-1}$, respectively. For metal rejection, these membranes have performed higher removal on Fe with TS40, TFC-SR3 and GHSP membranes having more than 82%, 92% and 86% respectively. Whereas, removal on Mn only achieved up to 60%, 80% and 30%, for TS40, TFC-SR3 and GHSP membranes respectively. In order to achieve drinking water standard, the membranes were efficient in removing Fe ion at 1 and 2 bar in contrast with Mn ion at 4 and 5 bar. Higher rejection of Fe and Mn were achieved when pH of feed solution was increased to more than 7 as TFC-SR3 membrane was negatively charged in basic solution. This effect could be attributed to the electrostatic effect interaction between membrane material and rejected ions. In conclusion, this study proved that NF membrane especially the TFC-SR3 membrane successfully treated local groundwater sources for public drinking water supply in line with the WHO standard.

동해 울릉분지에서 대륙사면과 분지 퇴적물의 지화학적 특성에 따른 황산염 환원 비교 (Comparison of Sulfate Reduction Rates Associated with Geochemical Characteristics at the Continental Slope and Basin Sediments in the Ulleung Basin, East Sea)

  • 유옥례;목진숙;김성한;최동림;현정호
    • Ocean and Polar Research
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    • 제32권3호
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    • pp.299-307
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    • 2010
  • In conjunction with geochemical characteristics, rate of sulfate reduction was investigated at two sediment sites in the continental slope and rise (basin) of the Ulleung Basin in the East Sea. Geochemical sediment analysis revealed that the surface sediments of the basin site (D2) were enriched with manganese oxides (348 ${\mu}mol$ $cm^{-3}$) and iron oxides (133 ${\mu}mol$ $cm^{-3}$), whereas total reduced sulfur (TRS) in the solid phase was nearly depleted. Sulfate reduction rates (SRRs) ranged from 20.96 to 92.87 nmol $cm^{-3}$ $d^{-1}$ at the slope site (M1) and from 0.65 to 22.32 nmol $cm^{-3}$ $d^{-1}$ at the basin site (D2). Depth integrated SRR within the top 10 cm depth of the slope site (M1; 5.25 mmol $m^{-2}$ $d^{-1}$) was approximately 6 times higher than that at the basin site (D2; 0.94 mmol $m^{-2}$ $d^{-1}$) despite high organic content (>2.0% dry wt.) in the sediment of both sites. The results indicate that the spatial variations of sulfate reduction are affected by the distribution of manganese oxide and iron oxide-enriched surface sediment of the Ulleung Basin.