• Title/Summary/Keyword: iron additive

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Characteristics of Redox Agent with Additive in Steam-Iron Process for the High Purity Hydrogen Production (고순도 수소 생성을 위한 SIP법에서 첨가제에 따른 환원 특성)

  • Jeon, Bup-Ju;Kim, Sun-Myung;Park, Ji-Hun
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.3
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    • pp.340-348
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    • 2011
  • Effects of various inorganic-metal oxide (Zr, Zn, Si, Al and Ca as promoters and stabilizers) additive on the reduction rate of iron oxide and the composition of forming hydrogen using the steam-iron cycle operation was investigated. The reduction rate of redox agent with additive was determined from weight change by TGA. The changes of weight loss and reduction rate according to redox agent with various additive affected the hydrogen purity and cycle stability of the process. The cyclic micro reactor showed that hydrogen purity exceeding 95% could be obtained by the water splitting with Si/Fe, Zn/Fe, Zr/Fe redox agents. The redox agents with these elements had an affect on redox cycle stability as a good stabilizer for forming hydrogen by the steam-iron process.

Preparation and Characterization of Liposome for Iron-Fortified Food Additive (철분 강화 식품첨가제용 리포좀의 제조 및 특성)

  • 이종우;전수진
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.33 no.5
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    • pp.864-868
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    • 2004
  • Iron is an essential ingredient for all metabolism in a living body However, because of the very low content of the iron in foods, many researches have been performed about iron-fortified food additives. We developed an iron-fortified food additive using the liposome that contain ferrous sulfate and hemin. For preventing the autoxidation of the ferrous sulfate, ascorbic acid was applied. Also, to prevent the oxidation of the liposome induced by the added ferrous sulfate and/or hemin, $\alpha$ -tocopherol was additionally applied. Though the effect of the added aqueous ascorbic acid did not show the antioxidative activity on the liposome containing ferrous sulfate and/or hemin, the added $\alpha$ -tocopherol in the phospholipid bilayer could retard the oxidation of the liposome. These results support that the liposome containing ferrous sulfate, hemin and ascorbic acid with the incorporated $\alpha$ -tocopherol could be applied in the food industry as an iron-fortified additive.

Current Limiting Characteristics of a Flux-Lock Type SFCL for a Single-Line-to-Ground Fault

  • Oh, Geum-Kon;Jun, Hyung-Seok;Lee, Na-Young;Choi, Hyo-Sang;Nam, Gueng-Hyun
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.9
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    • pp.70-77
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    • 2006
  • We have fabricated an integrated three-phase flux-lock type SFCL, which consists of an YBCO($YB_a2Cu_3O_7$) thin film and a flux-lock reactor wound around an iron core of each phase. In order to apply the SFCL in a real power system, fault analyses for the three-phase system are essential. The short-circuit currents were effectively limited by adjusting the numbers of winding of each secondary coil and their winding directions. The flux flow generated in the iron core cancelled out under the normal operation due to the parallel connection between primary and secondary windings. However, the flux-lock type SFCL with same iron core was operated just after the fault due to the flux generating in the iron core. To analyze the current limiting characteristics, the additive polarity winding was compared with the subtractive one in the flux lock reactor. Whenever a single line-to-ground fault occurred in any phase, the peak value of the line current of the fault phase in the additive polarity winding increased up to about 12.87 times during the first-half cycle. On the other hand, the peak value in the subtractive polarity winding increased up to about 34.07 times under the same conditions. This is because the current flow between the primary and the secondary windings changed to additive or subtractive status according to the winding direction. We confirmed that the current limiting behavior in the additive polarity winding was more effective for a single-line-to-ground fault

Heme Derived from Corynebacterium glutamicum: A Potential Iron Additive for Swine and an Electron Carrier Additive for Lactic Acid Bacterial Culture

  • Choi, Su-In;Park, Jihoon;Kim, Pil
    • Journal of Microbiology and Biotechnology
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    • v.27 no.3
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    • pp.500-506
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    • 2017
  • To investigate the potential applications of bacterial heme, aminolevulinic acid synthase (HemA) was expressed in a Corynebacterium glutamicum HA strain that had been adaptively evolved against oxidative stress. The red pigment from the constructed strain was extracted and it exhibited the typical heme absorbance at 408 nm from the spectrum. To investigate the potential of this strain as an iron additive for swine, a prototype feed additive was manufactured in pilot scale by culturing the strain in a 5 ton fermenter followed by spray-drying the biomass with flour as an excipient (biomass: flour = 1:10 (w/w)). The 10% prototype additive along with regular feed was supplied to a pig, resulting in a 1.1 kg greater increase in weight gain with no diarrhea in 3 weeks as compared with that in a control pig that was fed an additive containing only flour. To verify if C. glutamicum-synthesized heme is a potential electron carrier, lactic acid bacteria were cultured under aerobic conditions with the extracted heme. The biomasses of the aerobically grown Lactococcus lactis, Lactobacillus rhamosus, and Lactobacillus casei were 97%, 15%, and 4% greater, respectively, than those under fermentative growth conditions. As a potential preservative, cultures of the four strains of lactic acid bacteria were stored at $4^{\circ}C$ with the extracted heme and living lactic acid bacterial cells were counted. There were more L. lactis and L. plantarum live cells when stored with heme, whereas L. rhamosus and L. casei showed no significant differences in live-cell numbers. The potential uses of the heme from C. glutamicum are further discussed.

Effects of supplementation cysteine-coated Fe3O4 nanoparticles compared to FeSO4, on reproductive performance in male quail

  • Abdolvand, Esmail;Farzinpour, Amjad;Vaziry, Asaad
    • Advances in nano research
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    • v.9 no.1
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    • pp.15-24
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    • 2020
  • Iron has a crucial role in growth as part of metalo-proteins like haemoglobin or myoglobin, enzymes; they are also involved in energetic reactions. Iron plays a vital role in fertility. At high doses, Iron has a harmful consequence on the reproductive system, which can be strongly reflected the final stage of spermatogenesis. Nutritional products are claiming to use nanotechnology and it is important to recognize the potential toxicity of nano-sized nutrients. Recently iron nanoparticles were proposed as a food additive for poultry. The objective of this study was to investigate the effects of L-cystein coated iron oxide nanoparticles on reproductive performance in male quails. The results of Fourier Transform Infrared Spectrometer, Alternating Gradient Force Magnetometer and Scaning Electron Microscopy showed that iron oxide nanoparticles was produced and have been coated with L-cycstein (Fe3O4-Cys NPs). A total of 100 one-week-old quail chicks were randomly placed to five groups of five replicates. Four quails (two male and two females) were raised in an individual cage for each replicate. The five experimental treatment diets consisted; negative control diet, with no Iron supplementation; positive control diet supplemented with 60 mg/kg of Fe3O4; treatment diets supplemented with 0.6, 6 and 60 mg/kg of L-cystein coated iron oxide nanoparticles. The hemoglobin, Red blood cell, mean corpuscular volume, mean corpuscular hemoglobin, mean corpuscular hemoglobin concentration, gonadal somatic index, daily sperm production, total testicular sperm and sperm viability of the male quails that were fed with diet supplemented by 0.6 mg/kg of Fe3O4-Cys NPs were improved as compare with negative control. This study showed that not only the use of the Fe3O4-Cys nanoparticles had no side effects but also it can be used as a feed additive to improve the reproductive performance in male quails.

Quench Characteristics of Flux-lock type Superconducting Fault Current Limiter using Open-loop Iron Core (개루프 철심을 이용한 자속구속형 초전도한류기의 퀜치특성)

  • Nam, Gueng-Hyun;Choi, Hyo-Sang;Park, Hyoung-Min;Cho, Yong-Sun;Lee, Na-Young;Lim, Sung-Hun;Park, Chung-Ryul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.159-160
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    • 2005
  • The superconducting fault current limiter(SFCLs) provides the effect such as enhancement in the power system reliability due to limiting fault current in a few miliseconds. The Flux-lock type SFCL using the YBCO film among various type SFCLs consists of the primary and the secondary copper coils that are wound in parallel each other through the iron core. The operation can be controlled by adjusting the inductances and the winging directions of each the coil. We compared the current limiting performance on the additive and the subtractive polarity winding directions in case of an open-loop iron core. To analyze quench characteristics, we experimented various phase angle.

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Effects of Thickness, Base Element and Additive to Inoculant on the Number of Eutectic Cells and Chill Depth of Thin-Section Gray Cast Iron (박육주철의 공정 셀 수와 칠 깊이에 미치는 두께, 기본 원소 및 접종제 첨가 원소의 영향)

  • Kim, Tae-Hyeong;Lee, Woo-Jong;Kwon, Hae-Wook
    • Journal of Korea Foundry Society
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    • v.32 no.6
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    • pp.261-268
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    • 2012
  • The effects of thickness, base element and additive to inoculant on the number of eutectic cells and chill depth of thin-section gray cast iron were investigated. Meanwhile the number of eutectic cells increased by inoculation, chill depth decreased. The former decreased and the latter increased by holding the melt at the temperature range between 1,450 and $1,500^{\circ}C$. The former was more for the thinner casting with the thickness of 5 mm than the other. The result of thermal analysis coincided well with the change of macrostructure. The former increased and the latter decreased with the increased contents of carbon, silicon and the silicon content by inoculation. The former decreased and the latter increased with increased manganese content. The number of eutectic cells decreased as the amounts of rare earth and the bismuth added to this inoculant increased. With the addition of sulfur of 0.10 wt% of the weight of this inoculant, the maximum number of eutectic cells was obtained.

Analysis of Effect of Fuel Additive on Soot Suppression Using Laser Scattering Technique (광 산란 기술을 이용한 연료 첨가제의 그을음 억제 효과 분석)

  • Seo, Hyoungseock;Kim, Kibum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.7
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    • pp.204-210
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    • 2016
  • This paper presents an experimental analysis of the growth and oxidation processes of soot particles generated in an isooctane diffusive laminar flame due to incomplete combustion. The effects of iron-based diagnostics were employed to measure the elastic scattering light from soot particles in a flame at different flame heights, and the differential scattering coefficients were calculated through a calibration process. The growth and oxidation of soot particles in flame was investigated by comparing differential scattering coefficients, and the soot volume fraction was seen to decrease in the soot oxidation process. In the same manner, the differential scattering coefficients were calculated for iron-based fuel-additive seeded flame, and these coefficients were revealed to be smaller than those obtained in the fuel-additive unseeded flame. In addition, transmission through the radial direction of the flame was measured, and transmission in the soot oxidation regime was approximately 5% higher for the seeded flame. The propensity of the data coincided well with the differential scattering coefficients, and it can be concluded that the iron component of the fuel additive plays a crucial role as a catalyst, which eventually enhanced soot particle oxidation.

A Study for the Effects of Sb Addition on the Wear Resistance of Ductile Cast Iron (구상흑연주철(球狀黑鉛鑄鐵)의 내마모성(耐磨耗性)에 미치는 Sb첨가(添加)의 효과(效果)에 관한 연구(硏究))

  • Lee, B.Y.;Lee, K.W.
    • Journal of Korea Foundry Society
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    • v.6 no.2
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    • pp.93-103
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    • 1986
  • It is very important to obtain wear resistant ductile iron by adding more economical alloying elements. In this study, 10 heat of Mg-treated ductile iron were made according to Sb content (0-0.1% Sb). Each melt was tasted to 30 ${\o}test$ bars in $CO_2$ mold under the same condition and inspected wear characteristics, mechanical properties and microstructures. The results obtained from this study are as follows; 1. It is confirmed that Sb should be a simple and useful additive for improving wear resistance in ductile iron. 2. Hardness of ferrite and pearlite is improved with increasing Sb amount in ductile iron. 3. For ductile iron, the recommended ladle addition of Sb amount is to 0.02-0.03%. 4. Sb has adverse influence on spheroidizing of graphite if the amount is over 0.04%.

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A study for the Effects of Sb Addition on the properties of Cast Iron (I) (주철(鑄鐵)의 성질(性質)에 미치는 Sb 첨가(添加)의 효과(效果)에 관(關)한 연구(硏究)(I);기계적(機械的) 성질(性質)과 Pearlite의 안정화효과(安定化效果)를 중심(中心)으로)

  • Lee, Byeong-Yehp;Lee, Kye-Wan
    • Journal of Korea Foundry Society
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    • v.4 no.4
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    • pp.20-29
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    • 1984
  • It is very important to obtain gray and ductile cast irons with completely pearlitic structure by addition more economical alloying elements. In this study, 9 melts of gray iron and 5 melts of Mg-treated ductile cast iron were made according to Sb content (0-0.08% Sb). Each melt were casted to ${\phi}20mm$ test bars in sand mold under the same condition and inspected microstructure, mechanical and thermal properties. The results obtained from this study are as follows: 1. It is confirmed that Sb should be an economical, simple and useful additive for avoiding ferrite in gray and even in ductile cast irons. 2. For gray cast iron, the recommended ladle addition of metallic Sb amounts to 0.05%. At these levels, Sb has no detrimental influence on the mechanical properties of gray cast irons, which are normally modified according to their pearlite content without increasing the chilling tendency. 3. Despite its adverse influence on graphite shape in ductile iron, Sb can be used as a pearlite stabilizing alloying element even in the case of Mg - treated iron. The quantity to be added does not exceed 0.04% in the case of thinwalled castings. 4. The nodule count is increased very much and the shape of graphite particles become remarkably spheroidal. The matrix may be fully pearlitized, except for thin - walled castings, because the high nodule count results inevitably in some ferrite. 5. The $Ac_1$ and pearlite decomposition temperature are rised in accordance with increasing of additive Sb amount.

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