• Title/Summary/Keyword: ion transport

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TiO2 Branched Nanostructure Anode Material Prepared by Seeding Method for High-performance Lithium Ion Batteries

  • Han, Biao;Kim, Si-Jin;Hwang, Bo-Mi;Hwang, Eui-Tak;Park, Han Chul;Koh, Mun-Hyun;Park, Kyung-Won
    • Journal of the Korean Electrochemical Society
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    • v.16 no.2
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    • pp.81-84
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    • 2013
  • We demonstrate rutile $TiO_2$ branched nanostructure ($TiO_2$-BN) electrodes synthesized by seeding method for enhanced lithium intercalation properties. The morphology and crystalline nature of the $TiO_2$-BN were clearly observed by field-emission transmission electron microscopy and fast Fourier transform pattern. The $TiO_2$-BN electrodes showed excellent capacity and high rate performance. The improved lithium-ion intercalation properties of the $TiO_2$- BN may be attributed to relatively large specific surface area and short transport distance of the branched nanostructure.

An Analysis on the KSTAR neutral beam injection line (KSTAR 중성입자빔 수송라인 해석)

  • 임기학;김진춘;권경훈;조승연
    • Journal of the Korean Vacuum Society
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    • v.8 no.4B
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    • pp.556-564
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    • 1999
  • The analysis on heat fluxed on and transmission efficiencies by the collimators of neutral beam injection lines in KSTAR tokamak device has been carried out. And a mathematical model describing non-Gaussian beam distribution profile has been established. A neutral beam injection device is composed of 3 separate ion sources and corresponding beam transport lines, which deal with 7.8 MW of beam power, respectively. The divergence angles of ion beam are $1.2^{\circ}$and $0.5^{\circ}$, in vertical and horizontal directions, respectively. The maximum normal heat load on source exit scraper is 9.1 kW/$\textrm{cm}^2$ and net beam transmission efficiency is ~28%. The effect of misalignment of ion source and scrapers on the scraper heat load and beam transmission also has been analyzed.

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Ion Migration in Organic Metal Halide Perovskites (유기 금속 할라이드 페로브스카이트에서 이온 이동)

  • Oh, Ilwhan
    • Journal of the Korean Electrochemical Society
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    • v.21 no.2
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    • pp.21-27
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    • 2018
  • In this review, recent researches on ion transport phenomena in organic metal halide perovskite materials, which have been popular all over the world, are summarized. Although different results have been reported depending on the perovskite material composition and applied voltage, iodide seems to migrate under actual solar cell operating conditions, and occasionally methylammonium migration is observed. Perovskite is a so-called mixed conductor in which electrons and ions move simultaneously at room temperature, which greatly influences the hysteresis of the perovskite solar cell current-voltage curve and the performance degradation due to long-term operation.

A finite Element Analysis on the discharge characteristics of $SF_6$ gas ($SF_6$ 가스 방전 특성의 유한요소해석)

  • 최승길;심재학;강형부
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.3
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    • pp.265-272
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    • 2000
  • In this paper the corona discharge in SF$_{6}$ gas used as insulating material in lots o high voltage equipment, is simulated by finite element method with Flux-Corrected Transport(FCT) method. By application of proposed method the negative corona discharge characteristics in needle to plane electrode is analyzed with time step. For the accuracy of analysis the secondary electron emission by photon and ion are also considered as well as the accuracy of analysis the secondary electron emission by photon and ion are also considered as well as townsend first ionization and electron attachment. The calculated results show that the electric field intensity between anode and ion group is decreased as times go-by according to field distortion by those space charge. Accordingly the electron density is decreased strongly by the attatchment effect of SF6 gas so that the corona discharge becomes extinguished abruptly.y.

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A Survey on Measurement and Estimation Methods for State of Health of EV Lithium-ion Batteries (전기 자동차 리튬-이온 배터리 SOH 측정 및 추정 방법에 대한 조사연구)

  • Koog-Hwan Oh;Hyun-Chang Cho
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.462-469
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    • 2023
  • Electric vehicles (EVs) have recently been in the spotlight and have been rapidly developed to reduce the carbon emission with respect to the transport sector. Most EVs currently employ lithium-ion batteries (LIBs) as power sources because they have a higher energy density and a lower self-discharge than other batteries. However, the LIBs cannot respond to high power demands when the state of health (SOH) falls below 80%. Therefore, the SOH of the LIBs must be accurately measured or estimated. To date, many methods have been studied and proposed for measuring or estimating the SOH. In this paper, representative methods among them are reclassified and introduced.

Effect of Partial Substitution of Magnetic Rare Earths for La on the Structure, Electric Transport And Magnetic Properties of Oxygen Deficient Phase LaSr2MnCrO7-δ

  • Singh, Devinder;Sharma, Sushma;Mahajan, Arun;Singh, Suram;Singh, Rajinder
    • Bulletin of the Korean Chemical Society
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    • v.34 no.6
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    • pp.1679-1683
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    • 2013
  • Intergrowth perovskite type complex oxides $La_{0.8}Ln_{0.2}Sr_2MnCrO_{7-{\delta}}$ (Ln=La, Nd, Gd, and Dy) have been synthesized by sol-gel method. Rietveld profile analysis shows that the phases crystallize with tetragonal unit cell in the space group I4/mmm. The unit cell parameters a and c decrease with decreasing effective ionic radius of the lanthanide ion. The magnetic studies suggest that the ferromagnetic interactions are dominant due to $Mn^{3+}$-O-$Mn^{4+}$ and $Mn^{3+}$-O-$Cr^{3+}$ double exchange interactions. Both Weiss constant (${\theta}$) and Curie temperature ($T_C$) increase with decreasing ionic radius of lanthanide ion. It was found that the transport mechanism is dominated by Mott's variable range hopping (VRH) model with an increase of Mott localization energy.

Molecular Simulation for Ion Transport and High Frequency Dielectric of the Hollandite $Nax(Ti_8-_xCr_x)O_{16}$ (Hollandite $Nax(Ti_8-_xCr_x)O_{16}$의 이온 전송과 고유전율을 위한 분자 시뮬레이션)

  • Jung, In-Ho;Choi, Yong-Sung;Lee, Kyung-Sup
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.2299-2300
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    • 2008
  • The Velocity Autocorrelation Function (VAF) of the sodium ions is calculated for a range of temperature from 250K to 1000K and converted into the linear ac-conductivity and ac-susceptibility response via Fourier transformation. A peak is found in the conductivity around $6{\times}10^{12}$ Hz that has some of the character of a Poley absorption. Here it is shown to be due to an harmonically coupled site vibrations of the sodium atoms, which extend only over a limited range. At frequencies below the peak the conductivity tends towards a constant i.e. dc value corresponding to a constant flow of ions through the simulation cell. At high temperatures the conductivity due to this ion transport process behaves like a metal with an insulator to metal transition occurring around a specific temperature.

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