• Bulletin of the Korean Chemical Society
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• 제22권12호
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• pp.1345-1349
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• 2001

New quadruply-bridged calix[6]arenes (I-V) have been studied as cesium selective ionophores in poly(vinyl chloride) (PVC) membrane electrodes. PVC membranes were prepared with dioctyl sebacate (DOS) or 2-nitrophenyl octyl ether (o-NPOE) as the sol vent mediator and potassium tetrakis(p-chlorophenyl)borate as the lipophilic salt additive. These ionophores produced electrodes with near-Nernstian slope. The selectivity coefficients for cesium ion with respect to alkali, alkaline earth and ammonium ions have been determined. The lowest detection limit (logaCs+ = -6.3) and the higher selectivity coefficient (logkpotCs+,Rb+ = -2.1 by SSM, -2.3 by FIM for calix[6]arene I) for Cs+ have been obtained for membranes containing quadruply-bridged calix[6]arenes (I, Ⅱ, Ⅲ), which have no para t-butyl substituents on the bridging benzene ring.

• 한국세라믹학회지
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• 제37권6호
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• pp.530-536
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• 2000

During the grain growth of the PZT thin films by selective nucleation method using PZT seed, it was found that the grain size was saturated with the annealing temperature. The saturation of grain size was analyzed by the interfacial energy which appeared during the crystallization. The factors affecting the saturation of grain size were found to be the interfacial energy between perovskite phase and pyrochlore phase, and PZT thin film and the bottom Pt electrode. When the ion damage was introduced to the grain-size saturated PZT thin films, further lateral growth was observed. Pt bottom electrode thickness was changed to control the interfacial energy between the PZT thin film and the Pt bottom electrode. When Pt thickness was increased, the grain size was also increased, because the lattice parameter of Pt films was increased with the thickness of the Pt films. The incubation time of nucleation was increased with the amount of the ion damage on the Pt films.

• Bulletin of the Korean Chemical Society
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• 제31권6호
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• pp.1601-1608
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• 2010

A scandium(III) porphyrin-based fluoride-selective potentiometric sensor and its application in the analysis of hydrofluoric acid is described. Scandium(III) octaethylporphyrin, an ionophore recently developed for the optical fluoride sensor, was employed as a host molecule for the selective binding with fluoride in the plasticized PVC membrane. Nernstian response for $F^-$ between $10^{-4.6}$ to $10^{-1}$ M was observed at a glycine-phosphate buffer (pH 3.0). The selectivity pattern was observed as $F^-$, salicylate $\gg$ $SCN^-$ > $Cl^-$, $Br^-$, $NO_3{^-}$, $ClO_4{^-}$, which is consistent with the binding constant data measured in the plasticized PVC membrane based on a sandwich membrane method. This highly selective and reversible fluoride-sensitive electrode was employed for the analysis of hydrofluoric acid (HF). A disposable differential-type HF sensor was fabricated on the screen-printed electrode and demonstrated its ability to detect the neutral HF in the acidic solution.

• 멤브레인
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• 제3권3호
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• pp.126-135
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• 1993

감응물질로 제4급 암모늄염을 사용하여 PVC를 지지체로 과염소산이온의 농도 $10^{-6}M$까지 측정가능한 이온 선택성 전극을 제작하였다. 감응물질의 화학적 구조와 함량, 가소제의 종류 및 막 두께에 따른 선형응답 범위와 Nernst의 기울기 등 전극특성을 검토하여, 최적 막조건을 구한 다음 측정가능 pH범위와 여러 방해이온에 대한 선택계수를 비교 검토하였다. 과염소산 이온선택성 전극에서 감응물질의 화학적 구조 즉, 알킬기의 탄소고리수가 증가할수록 선형응답 범위 등 전극 특성은 Aliquat 336P, TOAP, TDAP 및 TDDAP의 순서로 좋아졌다. 가소제는 DBP가 가장 좋았고, 감응물질의 양은 최적 함량 이상에서 적을수록 좋았다. 최적 막 조성은 TDDAP 9.09, PVC 30.3 및 DBP 60.61wt%이었고, 막두께 0.45mm이었다. 이 조건에서 선형응답 범위 $10^{-1}~1.2 {\times} 10^{-6}M$, 검출한계 $5.1{\times}10^{-7}M$ 및 Nernst기울기 $57mV/pClO_4$이었다. 막전위는 pH 4~11 범위에서 pH의 영향을 받지 않았으며, 선택계수 서열은 다음과 같았다. $SCN^->I^->NO_3^->Br^->ClO_3^->F^->Cl^->SO_4^{2-}$

• 대한화학회지
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• 제35권1호
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• pp.51-58
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• 1991

새로운 管形 PVC膜 질산이온 選擇性 電極을 제작하여 그 性能을 조사하였다. 電極膜의 組成을 5${\%}$ aliquat-NO$_3$ 용액+ 32${\%}$ poly(vinyl chloride) + 63${\%}$ dibutyl sebecate로 하였을 때 전극의 感應特性이 최적이었으며, 이 때의 감응기울기는 58.5 ${\pm}$ 0.1 mV/decade, 檢出限界는 0.02mM, 感應時間 (t$_{99}$)은 25초이었다. 이 전극을 써서 아질산이온을 連續${\cdot}$自動化法으로 정량하였다. Recipient 용액은 pH 7.6의 10$^{-2}$ M 燐酸鹽 緩衝溶液을 쓰고, 여기에 酸化劑로서 過酸化水素를 0.3${\%}$가 되도록 포함시켰다. 전극계의 最適條件에서 아질산이온 標集溶液 8.0 ${\times}$ 10$^{-5}$ M ∼ 5.0 ${\times}$ 10$^{-2}$ M의 범위에서 직선적인 감응을 나타내었으며, 이 때의 감응기울기는 56.8 ${\pm}$ 0.2 mV/decade이었다.

• 한국막학회:학술대회논문집
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• 한국막학회 1998년도 춘계 총회 및 학술발표회
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• pp.49-52
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• 1998

1. 서론 : 화약이나 고체 충진제, 고체로\ulcorner 추진제의 산화제, slurry blasting agent 및 동물사료의 식품첨가제로 사용되고 있는 과염소산은 발화나 폭발성이 매우 강한 산화제로 정확한 순도를 측정하는 것은 중요하다. 용량분석법과 중량분석법에 비교하여 조작이 간단하고 편리한 과염소산이온의 농도를 직접 측정할 수 있는 PVC막 전극에 대한 많은 연구가 진행되고 있다. (생략)

• 대한화학회지
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• 제26권6호
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• pp.427-429
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• 1982

• 한국막학회:학술대회논문집
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• 한국막학회 2002년도 춘계 총회 및 학술발표회
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• pp.69-72
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• 2002

No Abstract, See Full-text

• Bulletin of the Korean Chemical Society
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• 제25권1호
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• pp.59-62
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• 2004

The ammonium ion-selective electrodes ($NH^+_4$-ISEs) based on the tetrahydrofuran(THF)-containing-16-crown-4 derivatives,1,4,6,9,11,14,16,19-tetraoxocycloeicosane ($L^1$) and 5,10,15,20,-tetramethyl-1,4,6,9,11,14,16,19-tetraoxocycloeicosane ($L^2$), were prepared and the electrode characteristics were tested. The conditioned $NH_4^+$-ISEs (E1) based on $L^1$ with TEHP as a plasticising solvent mediator gave best results with near-Nernstian slope of 53.9 mV/decade of activity, detection limit of $10^{-4.9}$ M, and enhanced selectivity coefficients for the $NH^+_4$ ion with respect to an interfering $K^+$ ion (log $K^{pot}_{NH_4^+,K^+}$ = -1.84). This result was compared to other ammonium ionophores reported previously, for example, that of nonactin (log $K^{pot}_{NH_4^+,K^+}$ = -0.92). The proposed electrode showed no significant potential changes in the range of 3.0 < pH < 9.0.

• Bulletin of the Korean Chemical Society
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• 제25권10호
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• pp.1484-1488
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• 2004

The thiocyanate-selective PVC membrane electrodes based on 5,10,15,20-tetrakis(2,4,6-trimethylphenyl)-porphyrinatomanganese(III) chloride [Mn(TMP)Cl] and 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinatomanganese(III) chloride $[Mn(Cl_8TPP)Cl]$ as ion carriers were investigated. The effect of ionophores, membrane compositions, plasticizers, and solution pHs on the response characteristics were studied. The Mn(TMP)Cl as an ionophore shows the best potentiometric sensitivity with a slope of -58.7 mV/decade and a detection limit of $log[SCN^-]$ = -6.90, and selectivity for thiocyanate over strong hydrophobic interfering anions such as ${ClO_4}^-$ and salicylate. The potentiometric response is affected by the electronic effect of the substituents and solution pHs. The presence of substituents with electron donating and more liphophilic characters around the ligated metal center produces an improved response toward $SCN^-$.