• Title/Summary/Keyword: ion absorption

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변성암의 분광특성 (Spectral Characteristics Visible and Near-infrared of Metamorphic Rocks)

  • 조민조;강필종;이봉주
    • 대한원격탐사학회지
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    • 제8권1호
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    • pp.1-13
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    • 1992
  • The study is to analize the spectral characteristics of metamorphic rocks by their spectral reflectance curves obtained from CARY 17-D Spectrophotometer. Coarse grained rocks generally show strong absorption at 1.4 and 1.9 $\mu\textrm{m}$ due to preserved water inclusion in quartz of feldspar. The basic rocks show a broad absorption due to Fe$^{++}$ ion rich in mafic minerals. Strong absorption near 2.0$^+\mu\textrm{m}$ suggests existence of carbonate or clay minerals.

MICROSTRUCTURAL STUDY OF $Fe_{1-x}Ti_x$ ALLOYS FORMED BY ION BEAM MIXING

  • Jeon, Y.;Lee, Y.S.;Choi, B.S.;Woo, J.J.;Whang, C.N.
    • 한국진공학회지
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    • 제6권S1호
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    • pp.127-132
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    • 1997
  • Microstructure of the Fe-Ti system by ion beam mixing of multilayers at 300 K and 77 K has been studied in a wide composition range. The ion bombardment was carried out using $Ar^+$ ions at 80 keV. Using grazing angle x-ray diffraction we find that the lattice parameters of these bcc solid solutions are very close to that of $\alpha$-Fe. Extended x-ray absorption fine-structure spectroscopy have been performed to investgate the short-range order in the ion-beam-mixed state. The structure parameters, such as the interatomic distance and the coordination number are estmated from the Fe K-edge Fourier filtered EXAFS spectra. The interatomic distance is independent of the alloy concentration and it is almost constant. The study of x-ray absorption near-edge structure gives information on the individual $\rho$components of the partial densityof states of the conduction band of the Fe and Ti We also find that a charge transfer from Ti to Fe atoms takes place.

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The Fluorescent 7-Aminodipyrido[3,2-a:2',3'-c] phenazine(7-amino-dppz) Functionalized as an Europium Ion ($Eu^{3+}$) Sensor

  • Choi, Chang-Shik;Lee, Ki-Hwan
    • Rapid Communication in Photoscience
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    • 제1권2호
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    • pp.31-33
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    • 2012
  • The Fluorescent 7-aminodipyrido[3,2-a:2',3'-c]phenazine (7-amino-dppz, 1) is functionalized as an europium ion ($Eu^{3+}$) sensor, which showed the effective emission quenching when europium cation is chelated to the bpy site of 1 compound. The complexation ratio indicated that the 1 compound forms a 1 : 1 complex with $Eu^{3+}$.

X-Ray Absorption Spectroscopic Study of 120 MeV $Ag^{9+}$ Ion-Irradiated N-Doped ZnO Thin Films

  • Gautam, Sanjeev;Lim, Weon Cheol;Kang, Hee Kyung;Lee, Ki Soo;Song, Jaebong;Song, Jonghan;Asokan, K.;Chae, Keun Hwa
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.315-315
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    • 2013
  • We report the electronic structure modification in the swift heavy ion (SHI) irradiated N-doped ZnO thin films prepared by RF sputtering from ZnO target in different ratio of Ar/$N_2$ gas mixture using highly pure $N_2$ gas. The different N-ZnO thin lms were then irradiated with 120 MeV Ag ion beam with different doses ranging from $1{\times}10^{11}$ to $5{\times}10^{12}$ ions/$cm^2$ and characterized by XRD and near edge X-ray absorption ne structure (NEXAFS) at N and O K-edges. The NEXAFS measurements provide direct evidence of O 2p and Zn 3d orbital hybridization and also the bonding of N ions with Zn and O ions. The minimum value of resistivity of $790{\Omega}cm$, a Hall mobility of $22cm^2V^-1s^-1$ and the carrier concentration of $3.6{\times}10^{14}cm^{-3}$ were yielded at 75% $N_2$. X-ray diffraction (XRD) measurements revealed that N-doped ZnO films had the preferential orientation of (002) plane for all samples, while crystallinity start decreasing at 32.5% $N_2$. The average crystallite size varies from 5.7 to 8.2 nm for 75% and then decreases to 7.8 nm for 80% $Ar:N_2$ ratio.

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$Na^+$$\longleftrightarrow$$Ag^+$ 이온교환에 따른 Na_2O-Al_2O_3-SiO_2$ 계 유리의 특성 및 살균효과 (Characterization and Bacteicidal Effect of Na_2O-Al_2O_3-SiO_2$ Glass System by $Na^+$$\longleftrightarrow$$Ag^+$ Ion Exchange)

  • 이광희;최세영
    • 한국세라믹학회지
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    • 제33권2호
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    • pp.242-250
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    • 1996
  • Glasses of Na2O-Al2O3-SiO2 system were prepared and ion-exchange characteristics change of properties and bactericidal effects by Na+↔Ag+ ion exchange were studied. Parent glasses with three compositions of varying Na2O in the 20~30 wt% were ion-exchanged in the molten salt of 2 mol% AgNO3+98 mol% NaNO3 at 320~36$0^{\circ}C$ for 15~16min. Amount of ion exchange and penetration depth of Ag+ ion increased with Na2O content in the parent glass ion exchange temperature and time. After ion exchange densities and Vickers hardness of the glasses increased and the glasses showed yellow-brown color and as amount of ion exchange increased the color turned deep because partial reduction and agglomeration of Ag+ into Ag0 results in absorption of visible light. After ion exchange chemical durability of the glass to wter was enhanced compara-bly that weight loss and change of surface of the glass were not found for the leaching test in 5$0^{\circ}C$ K.I water for 240hrs. Bactericidal effect of ion exchanged glass on Staphylococcus aureus and E. coli was determined by microorganism test and bactericidal effect increased with amount of ion exchange and incubation time.

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Sulfonated Polyethylene Terephthalate의 중금속 흡착능 (Heavy Metal Absorption Properties of Sulfonated Polyethylene Terephthalate)

  • 강영구;김동현
    • 한국안전학회지
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    • 제18권4호
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    • pp.92-97
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    • 2003
  • The purpose of this study is heavy metal absorption of recycled PET(poly ethylene terephatalate) NWF(non woven faric). The results of test are summarized as follows; Heavy metal abworption rates in Ni ions were higher then Zn and Cu ions, whereas heavy metal absorption rates by sulfonation times were not different. The heavy metal absorption times have a higher tendency from 60 min to 120 min. There were significant negative correlations among the amount used CSA(Chloro Sulfuric Acid) and the amount of absorption Zn(r = -0.33784, p < 0.05), Cu(r = -0.61177, p < 0.01) ions, whereas correlations between heavy metal absorption rates and sulfonation times were not significant. There were significant positive correlations among the amount of absorption Zn ions and the amount of absorption Ni(r = 96475, p < 0.014), Cu(r = 0.51614, p < 0.01) ions, likewise the positive correlations between the amount of absorption N ions and the amount of absorption Cu(r = 0.54766) ions were significant(p < 0.01).

고형배지를 이용한 순환식 딸기 수경재배에서 배지 종류별 무기이온 흡수 특성 (Characteristics of Inorganic Ion Absorption of Strawberries Cultivated in Closed Hydroponic System with Different Substrates)

  • 전하준;황진규;류습생;장미순
    • 생물환경조절학회지
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    • 제20권1호
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    • pp.33-39
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    • 2011
  • 시설재배 딸기를 위한 생력적이고 환경친화적인 순환식 수경재배기술을 확립하기 위하여 고형배지 종류별로 딸기의 무기이온 흡수 특성을 조사하였다. 톱밥배지를 제외한 나머지 세 종류의 배지에서는 대체적으로 많은 양의 질산태질소의 흡수를 나타내었는데, 펄라이트배지와 입상양면배지 보다는 코코피트배지에서 약간 높은 흡수농도를 나타내었다. 인은 톱밥배지를 제외한 세 종류의 배지에서는 초기에는 $5me{\cdot}L^{-1}$의 높은 흡수농도를 나타내었으며 생육이 진행됨에 따라 점차 감소하여 $3me{\cdot}L^{-1}$ 정도의 흡수량을 나타내었는데, 이것은 비교적 높은 농도로서 추후 검토를 할 필요가 있을 것으로 생각되었다. 그러나 톱밥배지에서는 3월 중순까지 인의 흡수가 거의 없는 것으로 나타났다. 칼륨의 흡수농도는 톱밥배지를 제외하고는 세 배지 모두 비슷한 흡수량을 나타내었는데 생육초기에는 비교적 높은 흡수량을 나타내었지만 점차적으로 감소하여 $4me{\cdot}L^{-1}$ 전후의 흡수량을 나타내었다. 칼슘의 흡수량은 펄라이트배지와 입상암면배지에서는 생육초기에 약간 높은 농도를 나타내기는 하였지만 생육전반에 걸쳐서 $2me{\cdot}L^{-1}$ 정도의 안정적인 흡수양상을 나타내었다. 마그네슘은 코코피트배지에서 생육 전반기에 $3me{\cdot}L^{-1}$ 정도의 높은 흡수농도를 나타내었으며 생육 후반기까지도 다른 배지에 비해서 가장 높은 흡수 농도를 나타내었다. 다음으로는 펄라이트 배지와 입상암면배지 순이었으며 세 배지 모두 마그네슘의 흡수는 대체적으로 $1me{\cdot}L^{-1}$ 정도의 농도를 나타내었다. 본 실험의 결과는 고형배지를 이용한 순환식 딸기 수경재배에서 유용하게 활용될 것으로 생각된다.

집속이온빔 (FIB) 레지스트를 위한 비정질 $Se_{75}Ge_{25}$ 박막의 이온 및 광유기특성 (-The Optical- and Ion-Induced Characteristics of a-$Se_{75}Ge_{25}$ Thin Film for Focused Ion Beam (FIB)-)

  • 이현용;박태성;김종빈;이영종;정홍배;조광섭;강승언;황호정;박선우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1992년도 하계학술대회 논문집 B
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    • pp.843-846
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    • 1992
  • This thesis was investigated on optical-and ion-induced characteristics in positive(a-$Se_{75}Ge_{25}$) and negative (Ag/a-$Se_{75}Ge_{25}$) resists for focused-ion-beam microlithogaphy. The a-$Se_{75}Ge_{25}$ inorganic thin film shows an increase in optical absorption after exposure to$\sim$$10^{16}$ dose(ions/$cm^{2}$) of Ga ions. The observed shift in the absorption edge toward longer wavelengths is consistent with that in films exposed to band-gap photons ($\sim$$10^{20}$ photons/$cm^{2}$). But, ion induced shift is twice as much as that in film exposed to optical radiation. This result may be related with microstructural rearrangements with in the short range of SeGe network. Due to changes in the short range order, the chemical bonding may be affected, which results in increased chemical dissolution in ion-induced film. Also, this resist exhibits good thermal stability because of its high Tg(~220$^{\circ}C$). The composition of deposited film measured by AES is consistent with that of bulk.

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무염 원자흡광도법과 흡광광도법에 의한 제제중의 Metoclopramide의 정량 (Determination of Metoclopramide by Flameless Atomic Absorption and Spectrophotometry)

  • 박만기;임병연;유경수;용군호
    • 약학회지
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    • 제22권1호
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    • pp.27-32
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    • 1978
  • Metoclopramide reacts with ammonium cobaltothiocyanate to form a stable ion pair which has an absorption maximum of 625mm. The reaction product was insoluble in water but soluble in most organic solvents. 1,2-Dichlorethane was the best extracting solvent among the several organic solvents tested. Metoclopramide can be determinded not only by visible light spectrophotometry but also indirectly by estimation of cobalt in the organic phase by flameless atomic absorption spectrophotometry. Linear relationship was found between absorbance and concentration in the range of 10$^{-4/}$-10$^{-3}$M by spectrophotometry and 10$^{-5}$-10$^{-4}$M by flameless atomic absorption spectrophotometry. The coefficient of variation by spectrophotometry was 0.9% and that of flameless atomic absorption was 1.8%. There was no interference with excipients, pH, temperature and reaction time. With this method, it is possible to determine accurately metoclopramide and tertiary amines in pharmaceutical preparations.

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Spectroscopic Properties and Ligand Field Analysis of trans -Dibromo(2,2-dimethyl-1,3-diaminopropane)chromium(III) Moiety

  • Choi, Jong-Ha;Oh, In-Gyung;Lim, Woo-Taik;Ryoo, Keon-Sang;Kim, Dong-Il;Park, Yu-Chul
    • Bulletin of the Korean Chemical Society
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    • 제26권6호
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    • pp.903-908
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    • 2005
  • The sharp-line absorption and emission spectra of $(H_{13}O_6)${$trans-[Cr(Me_2tn)_2Br_2]$}$_2Br_2(ClO_4)\;(Me_2$tn = 2,2-dimethyl-1,3-diaminopropane) have been measured between 13000 $cm^{-1}$ and 16000 $cm^{-1}$ at 5 K. The 298 K infrared and visible absorption spectra have also been measured. The nine electronic bands due to spin-allowed and spin-forbidden transitions were assigned. Using observed transitions, a ligand field analysis has been performed to probe the ligand field properties of coordinated atoms in the title chromium(III) complex ion. The zero-phonon line in the sharp-line absorption spectrum splits into two components by 286 $cm^{-1}$, and the large $^2E_g$ splitting can be reproduced by the modern ligand field theory. It is confirmed that nitrogen atoms of the Me2tn ligand have a strong $\sigma$-donor character, but the bromide has weak $\sigma$- and $\pi$-donor properties toward chromium(III) ion.