• 제목/요약/키워드: interstitial element

검색결과 18건 처리시간 0.027초

오스테나이트계 Fe-18Cr-10Mn-2Ni 합금의 연성-취성 천이 거동에 미치는 침입형 원소의 영향 (Effect of Interstitial Elements on Ductile-Brittle Transition Behavior of Austenitic Fe-18Cr-10Mn-2Ni Alloys)

  • 황병철
    • 한국재료학회지
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    • 제23권11호
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    • pp.649-654
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    • 2013
  • The effect of interstitial elements on the ductile-brittle transition behavior of austenitic Fe-18Cr-10Mn-2Ni alloys with different nitrogen and carbon contents was investigated in this study. All the alloys exhibited ductile-brittle transition behavior because of unusual low-temperature brittle fracture, even though they have a faced-centered cubic structure. With the same interstitial content, the combined addition of nitrogen and carbon, compared to the sole addition of nitrogen, improved the low-temperature toughness and thus decreased the ductile-brittle transition temperature (DBTT) because this combined addition effectively enhances the metallic component of the interatomic bonds and is accompanied by good plasticity and toughness due to the increased free electron concentration. The increase in carbon content or of the carbon-to-nitrogen ratio, however, could increase the DBTT since either of these causes the occurrence of intergranular fracture that lead to the deterioration of the toughness at low temperatures. The secondary ion mass spectroscopy analysis results for the observation of carbon and nitrogen distributions confirms that the carbon and nitrogen atoms were significantly segregated to the austenite grain boundaries and then caused grain boundary embrittlement. In order to successfully develop austenitic Fe-Cr-Mn alloys for low-temperature application, therefore, more systematic study is required to determine the optimum content and ratio of carbon and nitrogen in terms of free electron concentration and grain boundary embrittlement.

유체상과 변형율속도를 고려한 해면골의 거동해석 (Behavior of trabecular bone considered by fluid phase and strain rate)

  • 민성기;홍정화;문무성;이진희
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2002년도 추계학술대회 논문집
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    • pp.1078-1080
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    • 2002
  • The pressure variation of interstitial fluid is one of the most important factors in bone physiology. In order to understand the role of interstitial fluid and the biomechanical interactions between fluid and solid constituents within bone, poroelastic theory was applied. The purpose of this study is to describe the behavior of calf vertebral trabecular bone composed of the porous solid trabeculae and the viscous bone marrow by using a commercial finite element analysis program based on the poroelasticity. In this study, the model was numerically tested for 5 different strain rates, i. e., 0.001, 0.01, 0.1, 1.0, and 10 per second. The material properties of the calf vertebral trabecular bone were utilized from the previous experimental study. Two asymptotic poroelastic response, the drained and undrained deformation, were predicted. From the predicted results for the simulated five strain rate, it was found that the pore pressure generation has a linearly increasing behavior when the strain rate is the highest at 10 per second, other wise it showed a nonlinear the strain rate Increased. Based on the results of the present study, it was suggested that the calf vertebral trabecular bone could be modeled as a porous material and its strain rate dependent material behavior could be predicted.

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Skaergaard 암체의 희토류의 분화경향 (Differentiation Trend of Rare Earth Elements of the Skaergaard Intrusion)

  • Yun D. Jang
    • 자원환경지질
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    • 제34권6호
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    • pp.617-625
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    • 2001
  • Skaergaard 암체는 광범한 in situ 화성분화작용을 격은 층상관입암의 대표적인 예로 널리 알려져 있다. 따라서 이 암체는 폐쇄계에서 미량원소변이를 modeling 할 수 있는 적지가 될 것이다. 그러나, 기존의 연구에 의하면 본 암체의 전암 및 광물의 회토류는 폐쇄계로서의 예상된 경향을 보이지 않는다(Haskin and Haskin, 1968; Paster et al., 1974). 발표된 분배계수, 공존광물들의 mode,그리고 전암 및 광물의 미량원소함량을 사용한 미량원소modeling에 의하면 Skaergaard 암체의 희토류는 분화후기에 일어난 광범한 인회석 결정작용에 크게 영향을 받았음을 보여준다. 미량원소modeling은 Upper Border Series에서 간헐적으로 나타나는 인회석이 기존에 주장되어 온 바와 같은 liquldus상이 아니라 진화하는 magma의 미량원소함량에는 영향을 끼칠 수 없는 interstitial phase임을 시사한다. 분화작용 말기에 Skaerganrd 마그마가 대류를 멈추거나 소규모로 대류를 할 때, 마그마 암장의 상부에 축적되는 휘발성분에 기인한 증가된 $PH_2$O가 인회석이 UBS에서 정출 되는 것을 방해하였을 것이다. 이와 같은 인회석의 특성을 고려해서 Skaergaard분화작용을 modeling하면 희토류는 폐쇄계로서의 예상된 경향을 따른다 이와 같은 결과는 최종 20% 분화작용기간 중에 양적으로 상당한 양의 마그마의 주입이나 분출을 수반하는 그 어떤 Skaergaard 암체의 분화model도 배격한다.

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반용융 재료의 압출공정에 관한 유한요소해석 (Finite Element Analysis of Extrusion Process in Semi-Solid State)

  • 황재호;고대철;민규식;김병민;최재찬
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1997년도 고액공존금속의 성형기술 심포지엄
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    • pp.5-15
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    • 1997
  • It is the objective of this study that by conducting the serni-solid extrusion using A12024, the effect of various process variables on the quality of extruded product and extrusion force is understood. The results of experiment are compared with those of finite element simulation in order to verify the effectiveness of the developed FE-simulation code. In order to simulate densification in the deformation of serni-solid material, the semi-solid material is assumed to be composed of solid region as porous skeleton following compressible visco-plastic model and liquid region following Darcy's equation for the liquid flow saturated in the interstitial space. Then the flow and deformation of the semi-solid alloy are analyzed by coupling the deformation of the porous skeleton and the flow of the eutectic liquid. It is assumed that initial solid fraction is homogeneous. Yield and plastic potential function presented by Kuhn and constitutive model developed by Gunasekera are used for solid skeleton.

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Transient analysis of point defect dynamics in czochralski-grown silicon crystals

  • Wang, Jong-Hoe;Oh, Hyun-Jung;Park, Bong-Mo;Lee, Hong-Woo;Yoo, Hak-Do
    • 한국결정성장학회지
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    • 제11권6호
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    • pp.259-263
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    • 2001
  • The continuum model of transient point defect dynamics to predict the concentrations of interstitial and vacancy is established by estimating expressions for the thermophysical properties of intrinsic point defects. And the point defect distribution in a Czochralski-grown 200 mm silicon crystal and the location of oxidation-induced stacking fault ring(OiSF-ring) created during the cooling of crystals are calculated by using the numerical analysis. The purpose of this paper is to show that his approach lead to predictions that are consistent with experimental results. Predicted point defect distributions by transient point defect dynamic analysis are in good qualitative agreement with experimental data under widely and abruptly varying crystal pull rates when correlated with the position of the OiSF-ring .

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Ag925의 전기화학적 특성에 미치는 네오디뮴 함량의 영향 (Effect of Neodymium concentration on electrochemical properties of 925 silver)

  • 신병현;정승진;정원섭
    • 한국표면공학회지
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    • 제54권2호
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    • pp.71-76
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    • 2021
  • Ag925, silver with added copper, is popular alloy due to its low price. However, it has a difficult to use because of the low corrosion resistance. In various alloys, neodymium (Nd) works as an element to improve corrosion resistance by reacting with interstitial elements in the alloy. When 1.5 wt. % Neodymium was added to Ag925, the potential on the activated polarization in a potentiodynamic polarization test was increased from -0.15 V to -0.05 V. Ag925 with added neodymium showed the passivation after activation polarization. But When the potential increased around 50 mV, the current density is increased to 3 × 10-3. Ag925 with the 1.5 wt. % Nd had the low corrosion rate.

8 MHz 라디오파를 이용한 자입식 온열치료 -조직등가물질을 통한 온도분포 및 개 뇌실질의 조직병리 변화에 관한 연구- (Interstitial Hyperthermia by Radiofrequency Needle Electrode System : Phantom and Canine Brain Studies)

  • 이형식;추성실;성진실;서창옥;김귀언;노준규;김영수;김선호;정상섭;한은경;김태승
    • Radiation Oncology Journal
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    • 제9권1호
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    • pp.27-35
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    • 1991
  • 8MHz 라디오파를 이용한 자입식 온열치료를 위한 기초실험의 일환으로 조직등가물을 이용하여 다양한 needle electrode의 배열을 통한 적정 온도분포를 규명하고자 하였고, 직접 개의 뇌실질에 자입 온열요법을 시도하여 이에 따른 조직 병리학적 소견을 관찰하고자 하였다. 조직등가물 실침에서 저자들은 needle electrode 1 cm 간격의 정방형 배치에서 횡단면상 $90\%$ relative SAR 분포가 약 1.25 cm 반경의 균일한 원형으로 관찰됨을 알 수 있었고 종단면상 needle electrode의 길이에 따라 균일한 온도분포가 이루어짐을 관찰할 수 있었다. 정상 개의 뇌실질에 자입하여 직접 정방형의 중심을 $43^{\circ}C$로 유지하며 50분간 온열요법을 시행한 후 관찰한 조직 병리학적 소견은 liquefactive necrosis, pyknosis of neuronal element 및 Polymorphonuclear leukocytes들이 회백질에서 급성기에 관찰 되었고 liquefactive necrosis 주위에 lipid-laden macrophage들이 관찰됨이 공통적인 특징 이었으며 후기 변화로 괴사조직 주위로 신경교세포의 증식이 관찰되었다.

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Distribution of Nutrients in Dae-Cheong Reservoir Sediment

  • Hwang Jong Yeon;Han Eui Jung;Kim Tae Kehn;Kim Shin Jo;Yu Soon Ju;Yoon Young Sam;Jung Yong Soon;Park Pan Wook
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • 제2권2호
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    • pp.169-179
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    • 1998
  • This paper was performed to estimate interrelations between humus level of sediments and nutrient release from sediments in Dae-cheong reservoir. For investigations, sediments were sampled in June and October, in 1997 at fish farms, embayment, and the main stream of Dae-cheong reservoir. Items for investigation are as follows; water content, weight loss on ignition(IG), porosities of sediments, contents of element such as hydrogen, nitrogen, carbon, and nutrient release rates. Water contents and porosities were measured to conjecture the physical trait and grain size trait. Weight loss on ignition was measured to determine the contents of organic substance. For determination of the humus level of sediments, carbon and nitrogen contents were measured by elemental analyzer. As a result of elemental analysis, C/N ratio was determined in the range of $3.0\~13.1$. From the elemental analysis, humus level of Dae-cheong reservoir sediment was estimated from mesohumic state to oligotrophic state. For the determination of nutrient release rate, $PO_4-P$ and $NH_4-N$ concentrations of interstitial water and overlying water were measured. By using the concentration difference between interstitial water and overlying water and using the Fick's diffusion law, the release rates of phosphorus and nitrogen from the sediment samples were calculated. Release rates of nutrients which directly influence to the water quality were $0.05\~8.63mgP/m^2day$ and $4.99\~36.56mgP/m^2day$. It was found that release rate was measured higher in the 1st sampling period than in the 2nd sampling period. For the determination of phosphorus content in sediment, TPs were measured in 807\~1542{\mu}g/g$ in the 1st samling period and $677\~5238{\mu}g/g$ in the End samling period. Phosphorus release rate and phosphorus content were not interrelated each other.

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고 선량율 근접 및 온열치료 병용 삽입관의 제작과 특성 (Fabrication of Combined Probes for Interstitial hyperthermia and Brachyradiotherapy)

  • 추성실;김성규
    • 한국의학물리학회:학술대회논문집
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    • 한국의학물리학회 2004년도 제29회 추계학술대회 발표논문집
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    • pp.85-87
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    • 2004
  • 원격조정 아프터로딩 시스템에 사용하는 폴리에틸렌 삽입관에 금박을 입혀 라디오파(RF) 안테나로도 병행사용할수 있는 열 방사선 병용삽입관 을 제작하였다. 30W의 RF 전력으로 15분간 한천 판톰에 가열하였을 때 폴리에틸렌관은 약 5oC 상승하였으나 금박으로 코팅 된 폴리에틸렌관은 약 20${\circ}$C 상승하여 RF 안테나로 대용할 수가 있었다. 한천 팬텀 중앙부에 길이가 2 cm 인 4개의 전극을 1 cm 간격으로 정사각형이 되도록 삽입하여 가열하였을 때 90%등온곡선이 반경 1.25 cm 의 원형으로 균일하게 분포되었고 2 cm 간격으로 삽일 하였을 때 1.75 cm 반경으로 거의 4 각형의 균일한 분포를 얻었다. 개의 뇌 실질에 정방형의 중심을 43${\circ}$C로 50분간 온열 요법을 시행한 후 관찰한 조직병리학적 소견에서 의미있는 변화를 보였다.

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