• Title/Summary/Keyword: internal oxidation

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A Effect of the Oxidation Process on the Lifetime Properties of Ag-CdO Contact Materials (산화 방식이 Ag-CdO계 전기접점재료의 수명 특성에 미치는 영향)

  • Kwon, Gi-Bong;Nam, Tae-Woon
    • Journal of Korea Foundry Society
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    • v.25 no.6
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    • pp.233-239
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    • 2005
  • Contact material is widely used in the field of electrical parts. Ag-CdO has a good wear resistance and stable contact resistance. We studied a lifetime of Ag-CdO material because of getting better properties of Ag-CdO using Post-oxidation. The experimental procedure were melting using high frequency induction, heat treatment, rolling and internal oxidation. And we experimented on difference process, Post-oxidaion. Then we tested a lifetime and analysed. We obtained the optimizing oxidation temperature was $750^{\circ}C$. Using Pre-oxidation, coarse oxide and depleted oxidation layer existed but finer oxides were existed and depleted oxidation layer was not using Post-oxidation. In Post-oxidation, The density was 10 $g/cm^{3}$, the hardness was Hv 80 and the adhesive strength was 9000N. The specimen of Post-oxidation had better lifetime properties than that of Pre-oxidation. We predicted that the lifetime of Post-oxidation specimen is more longer twice than that of Pre-oxidation one.

Oxidation of STS304 Stainless Steel between 1050 and 1200℃ for 1 Hour in Air (STS 304 스테인리스강의 대기중 1050~1200℃, 1시간 동안의 산화)

  • Nguyen, Thuan Dinh;Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.47 no.4
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    • pp.235-241
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    • 2009
  • The STS304 stainless steel was oxidized isothermally and cyclically at temperatures between 1050 and $1200^{\circ}C$ for 1 hr in air. During isothermal oxidation, it displayed good oxidation resistance at $1050^{\circ}C$. However, it suffered from breakaway oxidation above $1100^{\circ}C$, being accompanied with internal oxidation. During cyclic oxidation, it also displayed good oxidation resistance at $1050^{\circ}C$, but it suffered from massive weight loss above $1125^{\circ}C$. The oxide scales formed consisted primarily of $Fe_2O_3$, $Fe_3O_4$ with and without $Cr_2O_3$. They were generally non-adherent.

Heat Resistance Properties of Thin Section HiSiMo Ductile Iron for Exhaust Manifold (배기 매니폴드용 박육 고규소 구상흑연주철의 내열 특성)

  • Lee, Do-Kyung;Kim, Sung-Gyu;Lee, Byung-Woo
    • Journal of Power System Engineering
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    • v.17 no.4
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    • pp.109-114
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    • 2013
  • In this study, the microstructure, mechanical properties and high temperature oxidation characteristics of HiSiMo and HiSiMoM ductile iron for exhaust manifold were investigated. The HiSiMoM ductile iron was developed by optimization of alloying element addition and casting design. The exhaust manifold prototype was fabricated using the HiSiMoM iron and this resulted in the weight saving of 0.73kg. The microstructures of the HiSiMo and HiSiMoM irons were similar each other and graphite nodularity was 89% and 93% respectively. Tensile strengths of them were 663.5 and 674.4 MPa and Brinell hardness were 235.3 and 243.9 respectively. Both irons showed parabolic weight gain behavior in high temperature oxidation atmosphere. Oxidation layer was divided into external and internal layers. The weight gain of the HiSiMoM iron was lower than that of the HiSiMo iron after isothermal oxidation test at $900^{\circ}C$. This should be rationalized by higher Si enrichment at the interface of the matrix and internal layer of the HiSiMoM iron.

High-Temperature Oxidation of Ti Containing Stainless Steel in O2-N2 Atmosphere

  • Onishi, Hidenori;Saeki, Isao;Furuichi, Ryusaburo;Okayama, Toru;Hanamatsu, Kenko;Shibayama, Tamaki;Takahashi, Heishichiro;Kikkawa, Shinichi
    • Corrosion Science and Technology
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    • v.3 no.4
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    • pp.140-147
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    • 2004
  • High temperature oxidation of Fe-19Cr and Fe-19Cr-0.2Ti alloys is studied at 1173-1373 K in 16.5 kPa $O_2$ - balances $N_2$ atmosphere aimed at clarifying the effect of titanium addition. Oxidation rate of Fe-19Cr alloy was accelerated with titanium. For both alloys chromium rich $(Fe,\;Cr)_2O_3$ was formed as a major oxidation product. On Fe-19Cr-0.2Ti alloy, a thin layer composed of spinel type oxide and titanium oxide was also formed and an internal oxidation of titanium was observed. Titanium was concentrated at the oxide surface and internal oxidation zone but a small amount of titanium was also found in the intermediate corundum type $(Fe,\;Cr)_2O_3$ layer. Crystals of corundum type $(Fe,\;Cr)_2O_3$ formed on Fe-19Cr alloy are coarse but that formed on Fe-19Cr -0.2Ti alloys were fine and columnar. Reason for the difference in oxidation kinetics and crystal structure will be discussed relating to the distribution of aliovalent titanium in corundum type $(Fe,\;Cr)_2O_3$ oxide layer.

High-Temperature Oxidation Behavior of Commercial Pure Titanium in Mixed Gases (혼합가스 분위기 중에서 공업용 순 타이타늄의 고온산화 거동)

  • Park, S.H.;Ahn, Y.S.
    • Journal of Power System Engineering
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    • v.11 no.2
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    • pp.44-50
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    • 2007
  • The oxidation behavior of commercial pure titanium is investigated in the temperature range of $727^{\circ}C{\sim}950^{\circ}C$ in mixed gases. The weight change is measured by TGA during oxidation in mixed gases. The oxidation behavior indicated by weight gain or the growth of oxide layer is based on the linear rate law at high temperatures. The structure of the oxide scale formed during oxidation is analysed by optical microscopy, electron probe microanalyzer, scanning electron microscope and x-ray diffraction. Oxide scales have a $TiO_2$ structure, and are constituted with multi-layered or two layered porous external one and a dense internal one. Ti-O solid solution region is formed at the interface of metal and scale layer. The formation of oxide scale is influenced by the oxidation temperature, time, crystal structure and the condition of atmosphere.

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The Effect of the Te on the Microstructure of Rapidly Solidification Ag-Sn-In Contact Material (급속응고한 Ag-Sn-In계 접점재료의 미세조직에 미치는 Te 의 영향)

  • Chang, Dae-Jung;Kwon, Gi-Bong;Kim, Young-Ju;Cho, Dae-Hyoung;Nam, Tae-Woon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.1
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    • pp.86-91
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    • 2007
  • Contact material is widely used as electrical parts. Ag-CdO has a good wear resistance and stable contact resistance. But the disadvantages of Ag-Cd alloy are coarse Cd oxides and harmful metal, Cd. Then Ag-Sn alloy that has stable and fine Sn oxide at high temperature has been developed. In order to investigate the effect of Te additional that affects the formation of the oxide layer on the surface and the formation of oxide in matrix Ag, we studied the microstructures and properties of Ag-Sn-In(-Te) material fabricated by rapid solidification process. The experimental procedure were melting using high frequency induction, melt spinning, and internal oxidation. Specimens were examined and analyzed by Transmission electron microscopy(TEM), energy dispersive X-ray spectroscopy(EDS) and Vickers hardness. As a result, internal oxidation was completed even at $600^{\circ}C$. Te forms coarse $In_{2}TeO_{6}$ phase and makes fine and well dispersed $SnO_{2}$ Phase. 0.3 wt% Te shows favorable properties.

High Temperature Oxidation Behavior and Surface Defect in Fe-25Mn-1.5Al-0.5C Steel (Fe-25Mn-1.5Al-0.5C강의 고온 산화 거동과 표면 결함)

  • Park, Shin Hwa;Hong, Soon Taik;Kim, Tai Wung;Chung, In-Sang
    • Journal of the Korean Society for Heat Treatment
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    • v.13 no.3
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    • pp.158-162
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    • 2000
  • The high temperature oxidation behavior and the surface defect in Fe-25Mn-1.5A1-0.5C steel was investigated by XRD (X-ray Diffractin) and electron microscopy. The intra- and inter-granular oxides were formed by the selective oxidation of manganese and aluminum, which were identified to MnAl2O4 phase. Aluminum nitride (AlN) was formed in front of these oxides. The ${\gamma}$-matrix was transformed to ${\alpha}$- and ${\varepsilon}$- phases by the selective oxidation of manganese. The surface defect, micro-scab was induced by the difference of the high temperature ductility between the matrix and the inter-granular oxide.

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Effects of Ethanol Extract of Benincasa Seeds on the Experimental Cellular Model of Nonalcoholic Fatty Liver Disease (동과자 에탄올 추출물이 비알코올성 지방간 세포 모델에 미치는 효과)

  • Choi, Jun-Young;Kim, So-Yeon;Kwun, Min-Jung;Kim, Kyun-Ha;Joo, Myung-Soo;Han, Chang-Woo
    • The Journal of Internal Korean Medicine
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    • v.33 no.4
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    • pp.438-447
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    • 2012
  • Objectives : In this study, we investigated the effect and the underlying mechanism of ethanol extract of Benincasa seeds on a cellular model of non-alcoholic fatty liver disease (NAFLD) established by treating HepG2 cells with palmitate. Methods : We evaluated ethanol extract of Benincasa seeds (EEBS) for its hepatic lipid-lowering potential in fatty acid overloaded HepG2 cells. After incubation in palmitate containing media with or without EEBS, intracellular neutral lipid accumulations were quantified by Nile red staining. We also investigated the effect of EEBS on lipogenesis and ${\beta}$-oxidation. $LXR{\alpha}$-dependent SREBP-1c activation, expression of lipogenic genes, and expression of ${\beta}$-oxidation related genes were determined with or without pretreatment of EEBS. Results : EEBS significantly attenuated palmitate-induced intracellular neutral lipid accumulation in HepG2 cells. EEBS suppressed fatty acid synthesis by inhibiting $LXR{\alpha}$-dependent SREBP-1c activation. EEBS also repressed SREBP-1c mediated induction of lipogenic genes, including ACC, FAS, and SCD-1. However, EEBS had no effect on ${\beta}$-oxidation related CPT-1 and $PPAR{\alpha}$ gene expression. Conclusions : Our results suggest that EEBS has an efficacy to decrease hepatic lipid accumulation, and this effect was mediated by inhibiting the $LXR{\alpha}$-SREBP-1c pathway that leads to expression of lipogenic genes and hepatic steatosis. Therefore, the Benincasa seeds may have a potential clinical application for treatment of this chronic liver disease.

A Study on the Treatment of Nutrients and Organic Carbon in Wastewater through Spatial Separation and Internal Recycling in a Modified Oxidation Ditch (격벽에 의한 조분리와 내부반송을 이용한 산화구 시설의 고도처리개선에 관한 연구)

  • Lee, Young-Shin;Oh, Dae-Min
    • Journal of Environmental Health Sciences
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    • v.37 no.1
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    • pp.64-72
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    • 2011
  • This study was performed to assess the removal efficiency on nitrogen, phosphorus and organic carbon in wastewater by spatial separation and internal recycling in a modified oxidation ditch process (modified OD). The performances of the modified OD were evaluated via laboratory-scale experiments. The process was operated at hydraulic retention times of 6-48 hours and solid retention times of 17-38 days. We found that organic carbon removal efficiency increased after the modified OD operation period. T-N removal efficiency remained stable; average T-N concentration of effluent was 8.02 mg/l after modified OD operation. In contrast, T-P concentration of effluent was over 1 mg/l. Nitrogen and phosphorus removal efficiency of modified OD at HRT 12 hr were 83.1% and 74.1%, respectively. Also, maximum efficiency was found at SRTs from 20 to 30 days. T-N removal efficiency was 83.1% at a C/N ratio from 3.0 to 3.5. However, T-N removal efficiency decreased at C/N ratios over 3.5. Also, T-P removal efficiency increased with HRT at C/P ratios in the same condition. Maximum efficiency was 74.1% at a C/P ratio from 25 to 28. T-N removal efficiency was 79.2% and T-P removal efficiency was 65.3% after M4 mode operation (added to the internal recycle line connected to the anoxic reactor). The modified OD with spatial separation and internal recycling developed in this study is, therefore, believed to be an improvement for solving problems in the nutrient removal technologies.

Effects of a Hwanggi-tang Ethanol Extract on Glucose Uptake and Metabolism in Murine Myotubes (근육세포주에서 당 흡수 및 대사 조절에 대한 황기탕 에탄올 추출물의 효과)

  • Jang, Chul-yong;Shin, Sun-ho;Shin, Yong-jeen
    • The Journal of Internal Korean Medicine
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    • v.41 no.4
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    • pp.599-611
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    • 2020
  • Objectives: The aim of this study was to evaluate the effects of Hwanggi-tang on glucose digestion, uptake, and metabolism in murine C2C12 myotubes. Methods: Hwanggi-tang was prepared according to the Dong-ui-bo-gam (≪東醫寶鑑≫) prescription by 70% ethanol extraction. The effect on glucose digestion was examined by determining the inhibitory effect of Hwanggi-tang on α-glucosidase activity. We also compared and verified the gene and protein expression of genes related to glucose uptake in C2C12 myotubes treated with Hwanggi-tang or insulin. Glucose metabolism was assessed by the expression levels of associated enzymes. Results: Hwanggi-tang caused a dose-dependent inhibition of α-glucosidase activity, induced glucose uptake by activation of the PI3K/Akt/mTOR pathway in the insulin signaling pathway, and promoted glucose oxidation and β-oxidation. Conclusions: Hwanggi-tang exerts an anti-diabetic effect on murine myotubes by inhibiting glucose digestion and inducing glucose uptake and consumption.