• Journal of Photoscience
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• 제6권1호
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• pp.13-19
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• 1999

Irradiation of 1-(o-allyloxyphenyl)-2-pentamethyldisilanylenthyne 2a in methanol yields two 1 : 1 photoaddition products 3 and 4 via silacyclopropene intermediate. Photolysis of 2a with acetone in deaerated methylene chloride yields site specific and regioselective 1 : 1 adducts 6 ad 7 via silacyclopropene and 1-sila-1, 2-propdiene intermediate, respectively. Photolysis of 2a and 1-(o-(3', 3'-dimethyl-2'-propenylox)phenyl)-2-pen-tamethyldisilanylethyone 2b in benzene provides novel stereoselevtive intramolecular cyclization products 10 and 11, respectively. Irradiation of 1-(o-acetoxyphenyl)-2-pentamethyldisilanyl ethyne 2c in benzene yields the photo-Fries rearrangement products 18 and 19 and a photoproduct 17 via silacyclopropene intermediate. Photolysis of 1-(o-methoxycarbonlymethoxyphenyl)-2-pentamethyl disilanylenthyne 2d in benzene provides a novel intramolecular cycloaddition product 25 and 1-(o-methoxycarbonylemthoxiyphenyl)-2-trimethylsilylethyne 26 via silacyclopropene intermediate.

• 소성∙가공
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• 제18권4호
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• pp.283-289
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• 2009

The multi-stage shape drawing is used to obtain long shaped products with high levels of dimensional accuracy and quality. It is important to design the cross sectional shapes of the intermediate passes to meet the required dimensional accuracy of the final product in the multi-stage shape drawing. Until now, the cross sectional shapes of the intermediate passes have been designed by the experiences. It is still remained unsolved problem to design the cross sectional shapes of intermediate pass drawing dies in the multi-pass shape drawing. In this study, a new technique is proposed to design the cross sectional shapes of intermediate passes. The proposed method is applied to a multi-stage shape drawing for a LM-guide which is one of the representative shape drawing products. In order to verify the effectiveness of the proposed method, FE-simulation and experiments have been carried out. The dimensional accuracy of the proposed method is compared with that of the conventional shape drawing process designed by the industrial engineers.

• 소성∙가공
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• 제24권3호
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• pp.155-160
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• 2015

One of the most important aspects in multi-stage shape drawing is the proper design of the intermediate dies especially to provide adequate metal distribution. In the current study, a method for designing the intermediate dies has been developed to manufacture hollow linear motion guide rails by multi-stage shape drawing. The design method is based on the modified virtual die method. The effectiveness of the proposed design method was verified by FE-simulations and experiments using Mn55Cr carbon steel. From the results of the FE-simulations and the experiments, the proposed design method led to a drawn product with a sound shape. The dimensional tolerances of the product were within the allowable specified tolerances.

• 한국환경과학회지
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• 제3권4호
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• pp.439-443
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• 1994

In aqueous acid solution ${[Cr(CN)_6]}^{3-}$ aquates via a series of stepwise stereospecific reactions to give ${[Cr{(H_2O)}_6]}^{3+}$as the final product.Some of the intermediate cyanoaquo complexes in the sequence have been isolated.These complexes aquate by both acid independent and acid denpendent pathways, the latter involving protonation of the cyano ligands followed by aquation of the singly protonated species. The kinetic data for the aquation of {[CrCN{(H_2O)}_5]}^{2+}$ are consistent with the transition state structure ${[{(H_2O)}_4Cr(CN)-OH-Cr{(H_2O)}_5]}^{3+}$. Addition of $Cr^{2+}$ to solutions of cyanocobalt(III) complexes produces the metastable intermediate${[CrNC{(H_2O)}_5]}^{2+}$ This isomerizes to in a $Cr^{2+}$-catalyzed reaction which occurs by a ligand-bridged electron-change mechnism. From acid catalysis on these aquation reactions, it product HCN. Especially, $HSO_3$-ions do the role of catalyst in the formation of HCN from $CrCN^{3-}$

• 제어로봇시스템학회논문지
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• 제12권9호
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• pp.945-953
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• 2006

Though a fully thermally coupled distillation column consumes less energy than an original column, it is not widely implemented in practice due to its operational difficulty. A new fully thermally coupled distillation column is proposed for the operability improvement, and its performance is investigated. The main improvement is the separation of a main column to give an upper and lower columns and the installation of an intermediate heat exchanger between them to regulate the fluctuation of product compositions. A proper manipulation of column pressure in the separated main columns made easy vapor flow without a compressor. The operability improvement is examined in a hexane process from the dynamic simulation using a commercial design software HYSYS. The simulation results indicate that the coupling among inputs and outputs is loosened to make easy manipulation of product compositions in the proposed distillation system.

• Bulletin of the Korean Chemical Society
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• 제17권2호
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• pp.153-158
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• 1996

The synthesis of common skeleton of podosporin A and aureol was studied through cationic olefin cyclization as a key step. The generation of thermodynamic silyl enol ether or enol acetate under known conditions gave regioselectivity of 88:12. The enolate alkylation of 2,3-dimethylcyclohexanone with 2,5-dimethoxybenzyl bromide at the more substituted site via lithium enolate gave poor yield. In this case an organozincate or an ammonium enolate also proved to be ineffective or not practical in terms of yield. Side chain elongation of the substituted cyclohexanone 13 through Grignard reaction, Wittig reaction, or Shappiro reaction did not proceed because of steric hindrance and side reactions. However, Stille coupling reaction via enol triflate produced the desired product 18 in high yield. The advanced intermediate 22, which was efficiently synthesized from 18, produced 24 instead of the desired product under a cationic olefin cyclization condition, indicating that the cyclization occurred in a stepwise mannervia the organomercury intermediate 23.

• 한국소성가공학회:학술대회논문집
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• 한국소성가공학회 2008년도 추계학술대회 논문집
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• pp.337-340
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• 2008

The cross section shape of intermediate die is one of important parameters to obtain dimensional accuracy of final product in shaped drawing process. Until now it has been designed by the experience or trial and error of the expert. In this study, the cross section shape of intermediate die fur spline shape is determined by the electronic field analysis, shape factor method. The result of the electronic field analysis, shape factor method has been compared with that of the present method. The effects of cross section shape on the dimensional accuracy were investigated by using FE analysis. And then the multi-stage shaped drawing experiments were performed to verify the results of FE analysis. As a result, the cross section shape from the electronic field analysis had the good dimensional accuracy. The electronic field analysis can be used for the method to obtain the cross section shape of intermediate die in shaped drawing process.

• 복식문화연구
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• 제16권4호
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• pp.775-783
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• 2008

Nowadays much amounts and various kinds of fashion products are sold through cyber shopping malls. Vendor type and intermediate type cyber shopping mall among many types of cyber shopping malls were selected to analyze assortment and price of fashion products. fashion products 'Best 100' from two cyber shopping malls were listed and classified. The results were as followed: First, the portion of fashion products at vendor type cyber shopping mall was higher than that of intermediate type. Second, fashion products items such as coat, Jacket, one-piece dress, sweater, t-shirt, pants, skirt, and underwear were sold at cyber shopping malls. Underwear and t-shirt were the best selling items at intermediate type shopping mall, and more expensive and fashionable coat, Jacket, and one-piece dress were the best selling items at vendor type shopping mall. Third, the price range of fashion items at vendor type shopping mall was higher than that of intermediate type shopping mall from 1,000 won to 99,000 won.

• 소성∙가공
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• 제17권8호
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• pp.627-632
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• 2008

The cross sectional shape of intermediate die is one of important parameters to improve dimensional accuracy of final product in shaped drawing process. Until now, it has been designed by the experience or trial and error of the expert. In this study, the cross sectional shape of intermediate die for spline shape is determined by the electric fields analysis and scale factor method. The result of the electric fields analysis and scale factor method have been compared with that of the expert method. The effects of cross sectional shape on the dimensional accuracy were investigated by using FE-simulation. And then the multi-stage shaped drawing experiments were performed to verify the results of FE-simulation. As a result, the cross sectional shape from the electric fields analysis and scale factor method had the good dimensional accuracy. These two methods can be used for the method to obtain the cross sectional shape of intermediate die in shaped drawing process.

• 한국분말재료학회지
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• 제22권3호
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• pp.187-196
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• 2015

With the stabilization of Korea's industrialization, it has become interested in the efficient use of rare metals, climate change and industrial environment and safety etc. It is thus making efforts to implement economic policies that address such issues. Therefore it is necessary to understand the demand, supply and use of metal materials. Since 2010, the Korean government has developed the integrated material flow methodology and has been trying to examine the demand, supply and use of metal materials. In 2013, the Korean government surveyed the material flow of chromium. Material flow analysis and environment emission of chromium were investigated 8 steps; (1) raw material, (2) first process, (3) Intermediate product, (4) End product, (5) Use/accumulation, (6) Collection, (7) Recycling, (8) Disposal. Chromium was used for stainless steel, alloy steel, coated sheets, refractory material and coating materials. Recycling was done mainly in use of stainless steel scrap. To ensure efficient use of chromium, process improvement is required to reduce the scrap in the intermediate product stage. In the process of producing of the products using chromium, it was confirmed that chromium was exposed to the environment. It requires more attention and protection against environment emission of chromium.