• Bulletin of the Korean Chemical Society
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• v.12 no.4
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• pp.434-437
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• 1991

Irradiation of 5-styryl-1,3-dimethyluracil (5-SDU) with 2,3-dimethyl-2-butene (DMB) gives a [4+2] cycloadduct which is converted into a [2+2] cycloadduct on the prolonged irradiation. Triplet sensitization, quenching, and external heavy atom effect on the [4+2] photocycloaddition reaction demonstrate the singlet pathway and salt effect excludes a radical ion pair precursor possibility. Polar solvents increase the reaction efficiency implying a polar exciplex involvement in the [4+2] photocycloaddition reaction. Inverse temperature dependence both on the reaction and DMB fluorescence quenching of 5-SDU indicates the presence of a singlet exciplex intermediate.

• Ocean and Polar Research
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• v.27 no.2
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• pp.183-188
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• 2005

Using data from Argo floats collected in the Southern Ocean, we describe water mass prop erties and flow fields at intermediate levels (1000m and 2000m levels). Water mass properties from Argo floats, which are consistent with those from previous hydrographic surveys, reflect the movement of the floats well even without quality control on the Argo data. Since the flow fields from the Argo floats do not cover the entire Southern Ocean, we could not obtain a general circulation pattern, especially at the 2000m level. We, however, can confirm the general eastward tendency due to ACC largely following the topography.

• Proceedings of the IEEK Conference
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• 2006.06a
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• pp.437-438
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• 2006

Virtual view synthesis is essential for 3DTV systems, which utilizes the motion parallax cue. In this paper, we propose a multi-step view synthesis algorithm to efficiently reconstruct an arbitrary view from limited number of known views of a 3D scene. We describe an efficient image rectification procedure which guarantees that an interpolation process produce valid views. This rectification method can deal with all possible camera motions. The idea consists of using a polar parameterization of the image around the epipole. Then, to generate intermediate views, we use an efficient dense disparity estimation algorithm considering features of stereo image pairs. Main concepts of the algorithm are based on the region dividing bidirectional pixel matching. The estimated disparities are used to synthesize intermediate view of stereo images. We use computer simulation to show the result of the proposed algorithm.

• Ocean and Polar Research
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• v.28 no.2
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• pp.153-161
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• 2006

To investigate inflow path of the East Sea Intermediate Water (ESIW) into the Ulleung Basin, hydrographic data surveyed in July 2005 were analyzed. The ESIW was characterized by the Salinity Minimum Layer (SML) within a depth range of 100 to 360 meters. Averaged potential temperature and salinity of the SML were $1.835^{\circ}C$ and 34.049 psu, respectively. Mean potential density $({\sigma}_{\theta})$ of the SML was 27.221 with a standard deviation of 0.0393. On isopycnal surfaces of 27.14 and 27.18 $({\sigma}_{\theta})$ which correspond to upper layers of the ESIW, the coastal low salinity water was separated from the offshore low salinity water by the relatively warm and saline water which might be affected by the Tsushima Warm Current Water. Relatively cold and fresh water, however, intruded into the Ulleung Basin from the region of Korean coast on isopycnal surfaces of 27.22 and 27.26 which was lower layer of the ESIW. The salinity distribution in the isopycnal layer of $27.14{\sim}27.26$ with acceleration potential on 27.22 up surface also showed clearly that the low salinity water flowed from the coastal area and intruded into the Ulleung Basin. This implies that the ESIW flows ken the north to the south along the east coasts of Korea and spreads into the Ulleung Basin in summer.

• Ocean and Polar Research
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• v.37 no.4
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• pp.265-278
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• 2015

We analyzed the North Pacific Intermediate Water (NPIW) that was simulated in 25 coupled general circulation models (CGCMs) using historical and Representative Concentration Pathway 4.5 (RCP4.5) scenario experiments of Coupled Model Intercomparison Project Phase 5 (CMIP5), focusing on the evaluation of the performance of HadGEM2-AO. A large inter-model diversity in salinity, density, and depth of the NPIW exists even though the multi-model ensemble mean (MME) is comparable to observations. It was found that the depth of the NPIW tends to be deeper in the models in which the NPIW is relatively saltier. HadGEM2-AO simulates the lightest NPIW having the lowest salinity at shallower depth, compared with other CGCMs. Future projections of the NPIW show that the temperature of the NPIW increases, but the density decreases in all CMIP5 models. It was shown that the salinity of the NPIW decreases in most models and the decrease tends to be larger in models simulating the lighter NPIW. The HadGEM2-AO projects moderate changes in the temperature and density of the NPIW out of the CMIP5 models.

• Biotechnology and Bioprocess Engineering:BBE
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• v.9 no.5
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• pp.405-413
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• 2004

The rheological properties of an exopolysaccharide, EPS-R, produced by the marine bacterium Hahella chejuensis strain 96CJ 10356 were investigated. The $E_{24}$ of $0.5\%$ EPS-R was $89.2\%$, which was higher than that observed in commercial polysaccharides such as xanthan gum ($67.8\%$), gellan gum ($2.01\%$) or sodium alginate ($1.02\%$). Glucose and galactose are the main Sugars in EPS-R, with a molar ratio of ${\~}1:6.8$, xylose and ribose are minor sugar components. The average molecular mass, as determined by gel filtration chromatography, was $2.2{\times}10^3$ KDa, The intrinsic viscosities of EPS-R were calculated to be 16.5 and 15.9 dL/g using the Huggins and Kraemer equations, respectively, with a 2.3 dL/g overlap. In terms of rigidity, the conformation of EPS-R was similar to that of caboxymethyl cellulose ($5.0{\times}10^{-2}$). The rheological behavior of EPS-R dispersion indicated that the formation of a structure intermediate between that of a random-coil polysaccharide and a weak gel. The aqueous dispersion of EPS-R at concentrations ranging from 0.25 to $1.0\%$ (w/w) showed a marked shear-thinning property in accordance with Power-law behavior. In aqueous dispersions of $1.0\%$ EPS-R, the consistency index (K) and flow behavior index (n) were 1,410 and 0.73, respectively. EPS-R was Stable to pH and salts.

• Ocean and Polar Research
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• v.24 no.2
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• pp.153-166
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• 2002

Particle fluxes were measured by using time-series sediment traps in the Bransfield Strait from December 27th, 1999 to December 26th, 2000. Total mass fluxes showed distinct seasonal variations with high fluxes in the austral summer and low fluxes in the austral winter at a 678m water depth in the eastern Bransfield Strait, while they were high only in January and fairly low in other months at a 960m water depth in the central Bransfield Strait. The reason that total mass fluxes occurred only in January at a 960m water depth in the central Bransfield Strait seems to be the strong current in the surface waters, which leads to a substantial amount of terrestrial materials and locally produced organic matter being advected away from the mooring site. Total mass fluxes were very high from January to October at a 1678m water depth in the eastern Bransfield Strait, while they were high only in January and February at a 1860m water depth in the central Bransfield Strait. The fact that total mass fluxes were higher at the deep water in the both sites than at the intermediate water depth may reflect that a substantial amount of terrestrial and organic materials are laterally transported by strong tidal current from the shallow environments to the deep basins.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.08a
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• pp.259-259
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• 2010

Periodically polarity inverted (PPI) ZnO structures on (0001) Al2O3 substrates are demonstrated by plasmas assisted molecular beam epitaxy. The patterning and re-growth methods are used to realize the PPI ZnO by employing the polarity controlling method. For the in-situ polarity controlling of ZnO films, Cr-compound buffer layers are used.[1, 2] The region with the CrN intermediate layer and the region with the Cr2O3 and Al2O3 substrate were used to grow the Zn- and O-polar ZnO films, respectively. The growth behaviors with anisotropic properties of PPI ZnO heterostructures are investigated. The periodical polarity inversion is evaluated by contrast images of piezo-response microscopy. Structural and optical interface properties of PPI ZnO are investigated by the transmission electron microcopy (TEM) and micro photoluminescence ($\mu$-PL). The inversion domain boundaries (IDBs) between the Zn and the O-polar ZnO regions were clearly observed by TEM. Moreover, the investigation of spatially resolved local photoluminescence characteristics of PPI ZnO revealed stronger excitonic emission at the interfacial region with the IDBs compared to the Zn-polar or the O-polar ZnO region. The possible mechanisms will be discussed with the consideration of the atomic configuration, carrier life time, and geometrical effects. The successful realization of PPI structures with nanometer scale period indicates the possibility for the application to the photonic band-gap structures or waveguide fabrication. The details of application and results will be discussed.

• Ocean and Polar Research
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• v.32 no.3
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• pp.331-336
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• 2010

The CREAMS (Circulation Research of the East Asian Marginal Sea) survey in 1999 revealed a sharp mid-depth discontinuity of the phosphate:silicate ratio in all basins of the East/Japan Sea. Incidentally, this discontinuity layer corresponds to the oxygen minimum layer. Directly below the discontinuity layer, oxygen concentration is increased. This increase in oxygen concentration is interpreted as a proof of intermediate water formation. Oxygen minimum indicates that the water parcel is old and stable against mixing. So it seems be an efficient barrier to vertical exchange of materials. This means that, once materials enter the lower domain, they rarely return to the upper domain. Therefore, the biogeochemistry of the East/Japan Sea depends heavily on material input through the Korea Strait, and flux is expected to be sensitive to the climate change. As a result, the East/Japan Sea ecosystem seems vulnerable to tipping (regime shift), which occurred on a decadal time scale.

• Applied Chemistry for Engineering
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• v.8 no.3
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• pp.473-481
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• 1997

Enhanced videomicroscopy was used to observe the dynamic behavior which occurred when water containing pure nonionic surfactant was carefully contacted with equal volumes of polar oils such as oleyl alcohol and oleic acid at various temperatures. A key component of the system is a vertical-stage microscope which provides for stable interfaces by locating the oil above the denser aqueous phase. This arrangement allowed intermediate phases formed at the surface of contact to be clearly observed, as well as any spontaneous emulsification which developed. Contacting experiments with $C_{12}E_5$ as the surfactant and with pure oleyl alcohol and oleic acid soils showed little activity below the cloud point but vigorous activity at higher temperatures including formation of an intermediate lamellar liquid crystalline phase. Diffusion path theory, which allows prediction of spontaneous emulsification resulting from diffusion and of intermediate phase formation during contacting processes, was used to understand the dynamic behavior seen during contacting experiments. Tentative diffusion paths for the contacting experiments with pure oleyl alcohol were presented with the aid of a partial phase diagram of the oleyl alcohol-water-$C_{12}E_5$ system.