• Fire Science and Engineering
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• v.20 no.1 s.61
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• pp.1-5
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• 2006

The spontaneous ignition of a flammable matter is a crucial factor for the prevention of a fire. The minimum ignition temperatures of Gasoline and Cenox in $1000{\mu}l$ of a sample were determined to be $340.5^{\circ}C\;and\;368.5^{\circ}C$ respectively. In addition when the time taken for ignition was 1.0 sec, the instantaneous ignition temperatures were $416^{\circ}C\;and\;427^{\circ}C$ respectively. Moreover, the changes in the minimum ignition temperature were small when less than 60 v/v% of Cenox was added, but the changes were great when 80 v/v% or more was added. Therefore, it is hypothesized that, when used as a fuel in the Gasoline engine, the ratio of the mixture of Cenox and Gasoline will be a very important factor.

• Journal of the Korean Institute of Gas
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• v.20 no.2
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• pp.16-22
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• 2016

Auto ignition characteristic is an important factor for handling combustible substance and fire prevention. This research studied about auto ignition characteristic and activation energy of Ethylene Glycol (EG) and Diethylene Glycol (DEG) by using ASTM D2155 type ignition temperature measuring apparatus. As the auto ignition temperatures, it was possible to get $434^{\circ}C$ for EG within sample amount range of $75{\sim}160{\mu}l$ and $387^{\circ}C$ for DEG within sample amount range of $130{\sim}150{\mu}l$. Also, it was possible to get $579^{\circ}C$ and $569^{\circ}C$ as instantaneous ignition temperatures with sample amount of $140{\mu}l$ for EG and DEG respectively. By using least square method from Semenov equation on measured ignition temperature and ignition delay time from this study, it was possible to calculate activation energy of EG as 25.41 Kcal/mol and DEG as 14.07 Kcal/mol. Therefore, it was possible to claim that DEG has more risk of auto ignition since the auto ignition temperature, instantaneous ignition temperature and activation energy of DEG is lower than EG.

• Journal of the Korean Society of Safety
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• v.33 no.2
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• pp.45-51
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• 2018

This study was conducted to assess the hazards of gasoline in relevance to the changes in octane numbers, and gasoline's spontaneous ignition temperature and instantaneous ignition temperature were measured. Spontaneous ignition temperature of regular gasoline was $301^{\circ}C$ for sample quantity of $100{\sim}125{\mu}{\ell}$. Spontaneous ignition temperature of middle gasoline was $380^{\circ}C$ for sample quantity of $125{\mu}{\ell}$ and that of premium gasoline was $400^{\circ}C$. As gasoline's octane numbers increased, their spontaneous ignition temperatures increased, and their instantaneous ignition temperature were almost identically $499^{\circ}C$ for sample quantity of $125{\mu}{\ell}$. In addition, activation energies of regular gasoline, middle gasoline, and premium gasoline were 10.48 Kcal/mol, 16.89 Kcal/mol, and 24.55 Kcal/mol respectively.

• Journal of the Korean Solar Energy Society
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• v.36 no.2
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• pp.73-78
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• 2016

This study investigates the main factors of fire prevention, such as spontaneous ignition and flash point, while using Diehylene Glycol (DEG) as the antifreeze for automobile and industrial machines. Our results show the flash point of $142^{\circ}C$ and the minimum ignition temperature of $388^{\circ}C$ in the range of $130{\mu}{\ell}{\sim}150{\mu}{\ell}$. By increasing temperature to ignite in 1 second, an instantaneous ignition temperature of the sample is $569^{\circ}C$ in the sample amount of $140{\mu}{\ell}$.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.21 no.11
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• pp.1466-1474
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• 1997

In order to design and develop a spark ignition engine, many studies must be preceded about the characteristics of thermal flow. For measurement of transient wall temperature thin film thermocouples of Bendersky type were manufactured and these probes were fixed into the wall of combustion chamber. Surface wall temperatures were measured in experiments of various engine speeds. Transient heat fluxes were calculated from the wall temperature measurements. Pressure was measured from combustion chamber using pressure transducer and gas temperatures were calculated using the state equation of ideal gas. And instantaneous heat transfer coefficients were obtained. It will be the basic data for the formulae of instantaneous heat transfer coefficients.

• Fire Science and Engineering
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• v.30 no.1
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• pp.24-30
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• 2016

Autoignition characteristic is an important factor of all combustible substances, and a critical determinant in assessing the effectiveness of fire hazard prevention. This study investigated the autoignition characteristic of mixtures of Ethylene Glycol and water using an ASTM D2155 type ignition temperature measuring apparatus. It was possible to get the minimum temperature as $434^{\circ}C$ from 100% Ethylene Glycol within range of $75{\sim}160{\mu}l$. A volume of $100{\sim}125{\mu}l$ of a mixed sample of Ethylene Glycol and water (80 : 20) was ignited at the same temperature ($434^{\circ}C$). Also it was possible to get the auto ignition temperature as $437^{\circ}C$ from a mixed sample of Ethylene Glycol and water (60 : 40) within range of $120{\sim}160{\mu}l$. The instantaneous ignition temperatures determined for $125{\mu}l$ of each of the three samples were $579^{\circ}C$, $595^{\circ}C$ and $611^{\circ}C$, respectively. Both auto ignition temperatures and instantaneous ignition temperatures were increased through the addition of water to the samples.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.4
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• pp.103-111
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• 2001

In the present study, the internal combustion engine tends to high performance, fuel economy, small-sized. Therefore, it is necessary to solve the problems on thermal load, abnormal combustion, etc in the engine. Thin film instantaneous temperature probe was made, and the measuring system was established. The instantaneous surface temperatures in the constant volume combustion chamber were measured with this system and the heat flux was obtained by Fourier analysis. Maximum instantaneous temperatures were obtained after 55∼60ms from ignition and they increased as equivalence ratio and varied differently as the position of probe. Total heat loss during combustion time was affected by the equivalence ratio and differed widely as the position of probe.

• Journal of the Korean Society of Safety
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• v.5 no.2
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• pp.17-23
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• 1990

This study was performed by experiments with ASTM's apparatus for determination of autoignition temperature to obtain autoignition characteristics of 1-Heptene, 2-Heptene and 3-Heptene, respectively. As results, minimum autoignition temperatures (MAIT) of 1-Heptene, 2-Heptene and 3-Heptene were 246$^{\circ}C$, 248$^{\circ}C$ and 254$^{\circ}C$, respectively and each dropping volume of these temperatures was 0.25$m\ell$, 0.20$m\ell$ and 0.20$m\ell$. Instantaneous ignition temperatures measured at each dropping volume of Heptene were 371$^{\circ}C$, 357$^{\circ}C$ and 342$^{\circ}C$, respectively. Relation ignition delay time with ignition temperature at minimum autoignition temperature agreed well with Semenov's equation, and the values of apparent activation energy from this equation were 47Kca1/mo1 for 1-Heptene, 35Kca1/mo1 for 2-Heptene and 29Kca1/mo1 for 3-Heptene. It was found that the values of apparent activation energy decreased as the position of double bond changed from end to center in C-C chain.

• Journal of Advanced Marine Engineering and Technology
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• v.27 no.5
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• pp.624-632
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• 2003

In the gasoline engine industry. there has been a trend towards the development of high performance engines with improved fuel efficiency, reduced weight and smaller sizes. These trends help to solved engine problems related to thermal load and abnormal combustion. In order to investigate these Problems, a thin film-type probe for instantaneously measuring temperatures has been suggested. A method for manufacturing such a probe was established in this study. The instantaneous surface temperature of a constant volume combustion chamber was measured by this probe and the heat flux was obtained through Fourier analysis. A peak instantaneous temperature was obtained after 55∼60 ms from ignition and the temperature increased according to an equivalence ratio and varied differently according to the position of the probe. Total heat loss during combustion period was affected by the equivalence ratio and differed widely in accordance to the position of the probe.