• Journal of fish pathology
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• v.14 no.2
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• pp.65-70
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• 2001

The purpose of this study is to find out the effects of various bis(tri-n-butyltin)oxide (TBTO) on changes of inorganic matter and enzyme activity in the hemolymph of Pacific Oyster, Crassostrea gigas. Oyster were exposed to 5, 10, 20, 50, 80and $100{\mu}g$/L of TBTO for 20 days. Survival rate of the oyster wass significantly affected by $\geq80{\mu}g$/L TBTO concentration at 10 days, while the diminution of survival was found at 20 days with a lower concentration of $\geq50{\mu}g$/L TBTO. Calcium concentration in the hemolymph increased significantly after 20 days at the TBTO concentration $20{\mu}g$/L. However no change of magnesium and inorganic phosphate in the hemolymph was showed. A significant increment of GOT activities in the hemolymph was observed after 20 days at more than $20{\mu}g$/L TBTO concentraion, without typical changes of GPT activities. These results indicate that oysters can be affected by TBTO in terms of calcium concentration and GOT activity in the hemolymph when they were exposed to the TBTO concentration $20{\mu}g$/L.

• Journal of Soil and Groundwater Environment
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• v.27 no.5
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• pp.10-17
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• 2022

Inorganic acids such as HCl, HNO₃, and H₂SO₄ have been commonly applied to soil washing of heavy metals-contaminated soil due to their cost-effectiveness. However, implementing the 'Chemical Substance Control Act' requires off-site risk assessment of the chemicals used in the soil washing. Therefore, in this study, organic acids or Fe(III)-based washing agents were evaluated to replace commonly used inorganic acids. Ferric removed heavy metals via H⁺ generated by hydrolysis, which is similar to the HCl used in the control group. Oxalic acid and citric acid were effective to remove Cu, Zn, and Cd from soil. Organic acids could not remove Pb because they could form Pb-organic acid complexes with low solubility. Furthermore, Pb could be adsorbed onto the iron-organic acid complex on the soil surface. Ferric could remove exchangeable-carbonate, Fe-Mn hydroxide, and organic matter and sulfides bound heavy metals (F1, F2, and F3). Organic acids could remove the exchangeable-carbonate and Fe-Mn hydroxide bound metals (F1&F2). Therefore, this research shows that the fractionation of heavy metals in the soil and the properties of washing agents should be considered in the selection of agents in the process design.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.10 no.1
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• pp.47-55
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• 2005

Seasonal variations of remineralization and inorganic nitrogen removal capacity were measured from Dec. 2001 to Apr. 2004 in a tidal flat located in south-western pan of Gwanghwa island, Korea by measuring the sediment oxygen demand (SOD) and denitrification. SOD was higher in muddy sediment (Dong-Mak; three year average=$683;m^{-2}d^{-1}$) than sandy sediment(Yeocha; three year average=$457;m^{-2}d^{-1}$). The SOD was high in summer and tended to be lower in winter. During the sediment incubation in Apr. 2002, production of oxygen from sediment was observed implying active benthic photosynthesis. Denitrification was also higher in muddy sediment (Dong-Mak: $5.4;m^{-2}d^{-1}$) than sandy sediment (Yeocha; $3.4;m^{-2}d^{-1}$). The denitrification rate corresponds to the carbon remineralization rate of 9.3 and $5.9\;mg-C\;m^{-2}d^{-1}$ in Dong-Mak and Yeocha, respectively. The denitrification rates were lower compared to rates observed in other coastal area $(0{\sim}200\;{\mu}mole\;m^{-2}h^{-1})$. Although Kwanghwa tidal flat sediments are replete in organic matter, remineralization activity seems to be limited by the availability of labile organic matter. The Kwangwha tidal flat may have potential to effectively remove large load of organic matter. Net remineralization rates were 196 and $132\;mg-C\;m^{-2}d^{-1}$ in Dong-Mak and Yeocha, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.28 no.2
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• pp.145-153
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• 1995

Effects of lime application levels(0, 10, 50, 100, and 300kg/10a) on three alfalfa cultivars(Dekalb brand 120, Pike, Pioneer brand 5929) were analyaed with respect to the growth, dry matter yield, and inorganic composition of the plants at three cutting periods. Major chemical properties of the soils were also analyzed. Response of the plant height to the lime application level was variable among the cultivars, showing the order of 50>100>300>10>0kg/10a in Dekalb brand 120, 50>100>10>300>0kg/10a in Pike, and 10>50>300>0>100kg/10a in Pioneer brand 5929. The order of dry matter yield response to the lime application level was 50>300>100>10>0kg/10a in Dekalb brand 120, 50>10>300>100>0kg/10a in Pike, and 50>100>10>0>300kg/10a in Pioneer brand 5929. Total dry matter yields at 50kg/10a lime application level were higher than those at any other levels in all the cultivars. Neither a specific pattern nor a significant change in inorganic composition of the plant was found for the lime application levels and cutting times, Soil chemical properties and composition remained with little change after the experiment except the soil pH, which was increased with the lime application level.

• Journal of Environmental Science International
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• v.6 no.6
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• pp.595-604
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• 1997

To investigate characteristics of biogeochemical environment of the Korea Deep Ocean Study(KODOSI area in the northeast Pacific Ocean, we preferentially measured Inorganic nutrients and fluorescent organic matters. Typically. the permanent thermocline was well developed at the depth of 200~1000m In the study area. Nitrate. phosphate and silicate were low In the surface mixed layer and Increased with depth. N/P and N/Si showed 15 and 0.2 respectively In the deeper layer. Two fluorophores, biomacromolecule(protein-like) and geomacromolecule (humid-like) , were observed by three dimensional fluorescence excltatlon/ emission spectra matrix. Biomacromolecule(maximum fluorescence at $Ex_{280m}/Em_{330nm}$) ranged from 41.9 to 147.0 TU with its maximum In the surface mixed layer and minimum in deeper water, This is a same trend that has been reported for DOC in the equatorial Pacific. This suggests that biomacromolecule might be labile and converted to refractory humic substance after bacterial degradation In the deeper layer. On the contrary, geomacromolecule(maximum fluorescence at $Ex_{330m}/Em_{430m}$), ranged from 7.6 to 46.5 QSU, showed minimum in the surface nixed layer(euphotic zone) Implying photodegradation and then increased with depth at all stations. In the characteristics of vertical profiles, the relationship between biomacromolecule and geomacromolecule showed negative correlation. Such trend can be attributed to biochemical regeneration or formation of fluorescent materials accompanying oxidation and rennnerallzation of settling organic matter.

• Korean Journal of Microbiology
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• v.24 no.3
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• pp.308-316
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• 1986

Vertical distribution of heterotrophic bacteria and physico-chemical characteristics were measuted in Kum River estuarine sediments. And interrelationship between heterotrophic bacterka and environmental factors was also studied. The type of sediment of Site 1 was silty clay, and sand at Site 2. Annual pH ranges were between 7.1 and 7.7 in the clay type sediment (Site 1) and 6.9-7.2 in the sand type sediment (Site 2). It was shown that organic matter contents were higher in the clay type sediment than those of sand type sediment. Redox potential values of sediments were decreased rapidly with depth at Site 1, but those of Sete 2 showed vertical fluctuation. Nitrogens(ammonia+amino acid-N, nitrate-N, nitrite-N) and phosphate in the clay type sediment showed higher values than those of sand type sediment. Annual distribution of heterotrophic bacteria were ranged $6.71{\times}10^4$ cells/g dry wt. $-2.50{\times}10^6$ cells/g dry wt. In the clay type sediment and $2.67{\times}10^3$ cells/g dry wt. $-1.94{\times}10^6$ cells/g dry wt. in the sand type sediment. Distribution of proteolytic, lipolytic, and amylolytic bacteria were decreased with the depth and the highest density was found in April and the lowest in January. Bacterial populations in sediments were closely correlated with such environmental factors as pH, redox potential, moisture content, organic matter contents, and inorganic nutrients such as nitrite-N and phosphate-P.

• The Korean Journal of Ecology
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• v.6 no.3
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• pp.198-207
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• 1983

The dry-matter production, the litter decomposition and the nutrient cycle were studied on Quercus serrata and Carpinus laxiflora forests at Piagol in Mt. Jiri. With the growth curves of the annual ring, the time schedules for the maximum productivities and maximum yields were measured. In Q.serrata forest, the maximum productivity was 11.36 tons $ha^-1 yr^-1$ at the 49th year and the maximum yield was 115.78 tons $ ha^-1$ at the 73th year, and in C. laxiflora 7.24 tons $ha^-1 yr^-1$at the 35th year and 82.5 tons $$ha^-1 $$at the 53th year, respectively. The maximum productivities and the maximum yields of the leaves, stems and roots of the trees were calculated. The contents of nitrogen, phosphorus, potassium and organic carbon were measured.. While inorganic materials were the most abundant in the leaves, organic materials in stems. The maximumproductivities and the maximum yields of the constituents of the trees were calculated, assuming that the constituents of the trees increase allometrically. The decomposition rates were as follows: k = 0.301 for Q.serrata forest, and k = 0.364 for C. laxiflora forest. The litter of the former was decayed more slowly than that of the latter. The halftimes for decomposition were 3.2 and 1.9 years, respectively.

• Korean Journal of Soil Science and Fertilizer
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• v.33 no.6
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• pp.393-397
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• 2000

This study was conducted to find out the effect of long-term compost application on the chemical properties of the orchard soils and apple quality. The contents of P and cations in soils were increased by the application of compost, while there are no difference in that of organic matter. The increase in application rates of compost resulted to the increase in apple yields, however, firmness and Brix of apple were as not differentiated by the compost application. The application of lower chemical fertilizer and higher compost resulted to the increase in the contents of organic matter and Ca in soils. The compost application resulted to the increase in inorganic material contents in soil but was not effective on the quality of apple fruits.

• Asian Journal of Turfgrass Science
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• v.9 no.4
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• pp.275-284
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• 1995

In this investigation, the accumulation mineralization and annual cycle of organic P has been studied in grassland ecosysterns of a Z japonica grassland and a M sinensis grassland on Mt. Kwanak. The basic models of the accumulation and mineralization for ash components of a grass-litter have been presented as the equations (1), (2), and (3). The equations (7)~(10) for organic P are derived from these basic concepts. There was a highty significant relationship between organic matter and organic P. The estimates between organic matter and organic P correlated very high significance. The parameter factors k or k' of mineralization of organic P for the Z. japonica and M sinensis asslands were k=0.412 or k'=0.292 and k=0.224 or k'=0.183, respectively. The time required for a cycle to be completed from organic P to inorganic P of 50, 95 and 99 % are 3.9, 16.7 and 27.8 years in the Z. japonica grassland and 4.1, 17.7 and 29.4 years in the M sinensis grassland. The annual P cycle formulae for mineralization were based on the equations (5), (11) and (12). Annual yields of mineralization for organic P in the steady state grasslands of Z. japonica and M sinensis were 0.407 and 0.504g /$m^2$, respectively.

• Korean Journal of Organic Agriculture
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• v.14 no.1
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• pp.69-83
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• 2006

This experiment was conducted to investigate effects of application of diluted and undiluted cattle slurry with water on seasonal and annual dry matter yields and feed values of tall fescue in the uncultivated rice paddy and it was compared with chemical fertilizer. Annual dry matter yields for diluted (average 6.43 ton DM/ha) and undiluted (average 6.56 ton DM/ha) cattle slurry were significantly higher (p<0.05) than those of no fertilizer (3.82 ton DM/ha). This trend was much more conspicuous in treatments applied in spring. In chemical fertilizer treatments, fertilizers with P and K (6.12 ton DM/ha), and P, K and N (10.13 ton DM/ha) had significantly (p<0.05) higher dry matter yields compared with no fertilizer. However, annual dry matter yields for treatments of P and K mixture tended to be lower than those of cattle slurry applications. The efficiency of DM production for inorganic nitrogen in chemical fertilizers annually averaged 26.7kg DM/kg N. In terms of cutting frequencies, it was highest in 2nd growth followed by 1st and 3rd growth. On the other hand, efficiencies of annual DM production of nitrogen for diluted and undiluted cattle slurry were 18.3 and 17.4 kg DM/kg N, respectively, especially, highest in 2nd growth. While, efficiencies of DM production for cattle slurry versus for inorganic nitrogen were 68.5 (undiluted) and 65.2% (diluted), respectively. For annual crude protein contents of tall fescue, no fertilization (11.5%) was significantly higher than chemical fertilizer, but that was lower than cattle slurry ($12.4{\sim}12.6%$) diluted with water. on the contrary, no fertilizers had significantly lower NDF (64.1%) and ADF (37.2%) contents than those of any other treatments, but their RFV (87.0) was significantly higher (p<0.05) than other treatments. The application of cattle slurry and their dilution significantly increased yields of crude protein and total digestible nutrients compared with no and/or P and K fertilizers (p<0.05). This trend was more conspicuous in cattle slurry applied in the early spring.