• Title/Summary/Keyword: inorganic materials

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Characteristics in the Deposition of Mn-Zn Ferrite Thin Films by Ion Beam Sputtering Using a Single Ion Source (단일 이온원을 사용하는 이온빔 스퍼터링법에 의한 Mn-Zn 페라이트 박막의 증착 기구)

  • Jo, Hae-Seok;Ha, Sang-Gi;Lee, Dae-Hyeong;Hong, Seok-Gyeong;Yang, Gi-Deok;Kim, Hyeong-Jun;Kim, Gyeong-Yong;Yu, Byeong-Du
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.239-245
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    • 1995
  • Mn-Zn ferrite thin films were deposited on $SiO_2(1000 \AA)/Si(100)$ by ion beam sputtering using a single ion source. A mosaic target consisting of a single crystal(ll0) Mn-Zn ferrite with a Fe metal strip on it was used. As-deposited films without oxygen gas flow have a wiistite structure due to oxygen deficiencies, which originated from the extra metal atoms sputtered from the metal strips during deposition. The as-deposited films with oxygen gas flow, however, have a spinel structure with (111) preferred orientation. The crystallization of thin films was maximized at the ion beam extraction voltage of 2.lkV, at which the deposited films are bombarded appropriately by the energetic secondary ions reflected from the target. As the extraction voltage increased or decreased from the optimum value, the crystallinity of thin films becomes poor owing to a weak and severe bombardment of the secondary ions, respectively. Crystallization due to the bombardment of the secondary ions was also maximized at the beam incidence angle of $55^{\circ}$. The as-deposited ferrite thin films with a spinel structure showed ferrimagnetism and had an in-plane magnetization easy axis.

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Fabrication of Flexible Inorganic/Organic Hybrid Thin-Film Transistors by All Ink-Jet Printed Components on Plastic Substrate

  • Kim, Dong-Jo;Lee, Seong-Hui;Moon, Joo-Ho
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1463-1465
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    • 2008
  • We report all-ink-jet printed inorganic/organic hybrid TFTs on plastic substrates. We have investigated the optimal printing conditions to make uniform patterned layers of gate electrode, dielectrics, source/drain electrodes, and semiconductor as a coplanar type TFT in a successive manner. All ink-jet printed devices have good mechanical flexibility and current modulation characteristic even when bent.

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Synthesis and characterization of orange-yellow phosphor for inorganic EL device

  • Chang, Mi-Youn;Lee, You-Hui;Han, Sang-Do;Khatkar, S.P.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1334-1337
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    • 2005
  • Orange-yellow phosphor has been synthesized by solid-state method for inorganic EL devices. Zinc sulfide is used as host material for the phosphor and the phosphor consists of copper and manganese as activators. The dependence of the photoluminescence (PL) and electroluminescence(EL) properties on the copper and manganese concentrations has been investigated.

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The Effect of Synthesis Conditions on the Electrochemical Properties of LiFePO4 for Cathode Material of Secondary Lithium Ion Batteries (리듐 2차 전지용 약극활물질 LiFePO4의 합성 조건에 다른 전기화학적 특성)

  • Kim, Do-Gyun;Park, Hyun-Min;Jeong, Yeon-Uk;Lee, Joon-Hyung;Kim, Jeong-Joo
    • Journal of the Korean Ceramic Society
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    • v.43 no.2 s.285
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    • pp.121-125
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    • 2006
  • [ $LiFePO_4$ ] is one of the promising materials for cathode material of secondary lithium batteries due to its high energy density, low cost, environmental friendliness and safety. $LiFePO_4$ was synthesized by the solid-state reaction method at 500 - 800°C. The crystal structure of $LiFePO_4$ was analyzed by X-ray powder diffraction. The samples synthesized at 600 and $700^{\circ}C$ showed a single phase of a olivine structure. The particle sizes were increased and the specific surface areas were decreased with heating temperatures. The electrochemical performance was investigated by coin cell test. The discharge capacities at 0.1 C-rate were 118 mAh/g and 112 mAh/g at $600^{\circ}C,\;700^{\circ}C$, respectively. In an attempt to improve the electrical conductivity of cathode materials, $LiFePO_4/graphite$ composite was prepared with various graphite contents. The electrical conductivity and discharge capacity were increased with increasing the graphite contents in composite samples. The rate capabilities at high current densities were also improved.

Preparation of $\textrm{TiO}_2$ Thin Film by Electrochemical Method (전기화학법을 이용한 $\textrm{TiO}_2$ 박막의 제조)

  • Gong, Pil-Gu;Lee, Jong-Kook;Kwak, Heo-Seop;Park, Soon-Ja;Kim, Hwan
    • Korean Journal of Materials Research
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    • v.6 no.10
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    • pp.999-1006
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    • 1996
  • 전기화학법 중 음극환원법을 이용하여 0.005M TiCI4수용액으로부터 수화물 형태의 TiO2박막을 제조하였다. TiCI4수용액에 첨가제로 에탄올을 50vol% 첨가하여 균일한 박막을 얻을 수가 있었으며, 전류밀도와 시간에 따라서 박막의 두께와 미세구조가 변화하였다. 성장속도가 큰 조건에서 얻은 박막은 균질성의 감소로 인하여 건조과정이나 열처리 중 다량의 균열이 발생하였다. 일정한 전류밀도ㅇ에서 반응시간의 증가에 따라 박막의 두께가 직선적으로 증가하였으며, 10mA/$\textrm{cm}^2$의 전류밀도에서 3분 동안 반응시켜 약 0.7$\mu\textrm{m}$ 두께의 우수한 TiO2박막을 얻을수 있었다. 이러한 박막은 80$0^{\circ}C$에서 한 시간 열처리 한 결과, rutile 단일상으로 결정화되었다.

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Synthesis of Inorganic-Organic Composite Electrolyte Membranes for DMFCs (DMFC용 무기-유기 복합 전해질 막의 합성)

  • Kim, Eun-Hyung;Yoon, Gug-Ho;Park, Sung-Bum;Oh, Myung-Hoon;Kim, Sung-Jin;Park, Yong-Il
    • Journal of the Korean Ceramic Society
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    • v.45 no.2
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    • pp.119-125
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    • 2008
  • The FAS(Fluoroalkylsilane)/Nafion inorganic-organic composite electrolyte membrane was successfully fabricated through sol-gel method. The FAS having hydrophobic functional group and silanol ligands is impregnated in $Nafion^{(R)}$ membrane to reduce methanol crossover. The prepared FAS/Nafion inorganic-organic composite electrolyte membrane consist of the hydrophobic FAS-derived silicate nano-particles and $Nafion^{(R)}$ matrix showed decrease of methanol crossover and reduction of humidity dependence without large sacrifice of proton conductivity. The microstructural analysis of the composite membranes was performed using FESEM and FTIR. And the effect of the incorporation of the hydrophobic FAS-derived silicate nano-particles into $Nafion^{(R)}$ membrane was investigated via solvent uptake, membrane expansion rate, humidity dependency of proton conductivity and contact angle measurement.

Formation of the precipitates in the Bi-2223/Ag superconducting tapes by post-heat treatment (Bi-2223 초전도 선재의 후열처리 과정에 의한 석출물의 형성)

  • Lee, Sang-Hee;Kim, Cheol-Jin;Chung, Jun-Ki;Yoo, Jae-Moo;Ko, Jae-Woong
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.262-267
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    • 2000
  • To tap the possibility of exploiting the precipitates as flux-pinning center in the Bi-2223 superconducting system, as-received Bi-2223/Ag tapes with the starting composition of Bi$_{1.8}$Pb$_{0.4}$Sr$_2$Ca$_{2.2}$Cu$_3$O$_8$ were post-annealed at various temperature, oxygen partial pressure, and annealing time. The 2$^{nd}$ phases in the annealed specimen were analysed with XRD, SEM, TEM, and EDS. The size and the distribution of the precipitates such as (Ca,Sr)$_2$(Pb,Bi)O$_4$ and Bi$_{0.5}$Pb$_3$Sr$_2$Ca$_2$CuO$_{12+{\delta}}$ (3221) in the Bi-2223 matrix was controllable by varying heat-treatment condition without breaking the connectivity of the 2223 grains. The nano-size precipitates within the 2223 grains are conjectured as working as flux-pinning sites, resulting in increased J$_c$ value.

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The Synthesis and Pore Property of Hydrogen Membranes Derived from Polysilazane as Inorganic Polymer (무기 고분자인 폴리실라잔을 이용한 수소 분리막의 합성 및 기공특성)

  • Kwon, Il-Min;Song, In-Hyuck;Park, Young-Jo;Lee, Jae-Wook;Yun, Hui-Suk;Kim, Hai-Doo
    • Journal of the Korean Ceramic Society
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    • v.46 no.5
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    • pp.462-466
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    • 2009
  • We investigated the pore properties of inorganic membranes applied for hydrogen separation industry. Inorganic membranes were derived from polysilazanes. The thermal reactions involved were studied using thermogravimetry(TG) and IR spectroscopy(FTIR) of the solids. To determine the thermal effect of pore properties, polysilazanes were pyrolysed in inert atmosphere. Pore volume and BET surface area showed the maximum value at a pyrolysis temperature of $500^{\circ}C$. For amorphous SiCN membrane derived from polysilazanes, selectivity of $H_2/N_2$ was 4.81 at $600^{\circ}C$.

Change in the Functional Properties of Mulching Paper by the Addition of Inorganic Materials (무기소재 첨가에 따른 멀칭용지의 기능성 변화)

  • Sung, Yong Joo;Jung, Woong-Gi;Lee, Ji-Young
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.6
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    • pp.64-71
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    • 2013
  • The biodegradable mulching paper could be applied for the environmental friendly agriculture as an alternative to the current vinyl mulching. In order to increase the usability of the mulching paper, the effects of the addition of various inorganic materials on the functionality of the mulching paper were evaluated in terms of practical benefits. The blend of carbonized rice husk powder and perlite resulted in the higher value in the air permeability of the mulching paper, which would be important for the health of plant root. The heat conservative of the mulching paper could be improved by adding the bottom ash or the fly ash because of the pore structure of the ashes. The pH of acidic soil could be neutralized by using the mulching paper containing paper-mill sludge ash or fly ash. The various results showed the addition of the inorganic materials could improve the functional properties of the mulching paper.