• Title/Summary/Keyword: inorganic materials

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Effects of the Contaminants in Papermaking Process Water on Physical Properties of Paper (공정수 내의 오염물질이 종이의 물성에 미치는 영향)

  • 이학래;함충현;이지영
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.36 no.1
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    • pp.16-23
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    • 2004
  • Recently the increased concerns about the cost reduction and environmental protection make the paper industry increase the closure level of papermaking system, which results in the buildup of organic and inorganic materials in the papermaking process water. Increase of the system closure causes deterioration of additive performance and provokes diverse problems in papermaking process and product quality. To investigate the effects of process water quality on the physical properties of fine papers handsheets were prepared with process water containing various amounts of inorganic and organic contaminants including calcium or sodium ions and oxidized or cationic starches. Inorgainc and organic materials did not show any significant effect on the physical properties of handsheets. Recycled GCC showed the same trends as inorganic and organic materials. The performance of cationic starch was deteriorated, however, in the recycled white water, which resulted in the reduction of tensile index of handsheets.

Physical Properties of Inorganic Foam Material for Exterior Fire Resistance Material (무기발포체의 화재확산 방지용 외장재 적용을 위한 물성평가)

  • Shin, Hyeon-Uk;Kim, Ji-hyeon;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2016.05a
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    • pp.124-125
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    • 2016
  • This study is to development of inorganic insulation material using by-product materials. The organic material is due to toxic gas emission, when a fire occurs. And it has lower water resistance. The inorganic material is heavy and worse thermal performance than organic materials.In this study, cullet and fly ash were used as basic materials in order to secure a recycling technology of by-products which was mostly discarded and reclimed, and measure of physical properties of light-weight ceramic insulator.

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Synthesis and Characterization of Co-Surfactant Templated Mesoporous Materials with Enhanced Hydrothermal Stability

  • Kim Geon-Joong;Kim Hyun-Seok;Ko Yoon Soo;Kwon Yong Ku
    • Macromolecular Research
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    • v.13 no.6
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    • pp.499-505
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    • 2005
  • Ordered mesoporous materials with a hydrothermally-stable, protozeolitic framework were prepared by exploring the direct conversion of inorganic species based on co-surfactant templating systems. To confer hydrothermal stability on the mesoporous aterials, the organic-inorganic hybrids were heat-treated in strongly basic media. Co-surfactant templating systems of cetyltrimethylammonium bromide [$C_{16}H_{13}(CH_{3})_{3}$NBr, CTAB] with 1,3,5-trim­ethylbenzene (TMB) or a nonionic block copolymer of poly(ethylene oxide )-b-poly(propylene oxide )-b-poly(ethyl­ene oxide) ($EO_{20}PO_{70}EO_{20}$) were employed to improve the hydrothermal stability of the organic-inorganic self-assembly during the solid rearrangement process of the inorganic species. The mesoscopic ordering of the pore structure and geometry was identified by X-ray diffraction, small angle neutron scattering and electron microscopy.

Materials Aspects for fast switchable NLC/FLC Devices

  • Haase, Wolfgang;Bezborodov, Vladimir;Lapanik, Valery;Podgornov, Fedor
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.986-989
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    • 2007
  • In this review, several aspects for improving the quality of materials parameters of Nematic Liquid Crystals (NLCs) and Ferroelectric Liquid Crystals (FLCs) will be discussed. In particular the decrease of the response time is a need. It will be demonstrated that the materials parameters of NLCs and FLCs can be improved among other ways due to optimization of chemical structures of the NLCs and /or FLCs mixtures, due to doping them with nanomaterials and by using fast elastic relaxation processes.

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Preparation of Transparent Organic-Inorganic Hybrid Hard Coating Films and Physical Properties by the Content of SiO2 or ZrO2 in Their Films (투명 유-무기 하이브리드 하드코팅 필름 제조 및 SiO2 또는 ZrO2함량에 따른 필름의 물성)

  • Seol, Hyun Tae;Na, Ho Seong;Kwon, Dong Joo;Kim, Jung Sup;Kim, Dae Sung
    • Korean Journal of Materials Research
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    • v.27 no.1
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    • pp.12-18
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    • 2017
  • Transparent organic-inorganic hybrid hard coating films were prepared by the addition of $SiO_2$ or $ZrO_2$, as an inorganic filler to improve the hardness property, filler was highly dispersed in the acrylic resin. To improve the compatibility in the acrylic resin, $SiO_2$ or $ZrO_2$ is surface-modified using various silanes with variation of the modification time and silane content. Depending on the content and kind of the modified inorganic oxide, transparent modified inorganic sols were formulated in acryl resin. Then, the sols were bar coated and cured on PET films to investigate the optical and mechanical properties. The optimized film, which has a modified $ZrO_2$ content of 4 wt% markedly improved in terms of the hardness, haze, and transparency as compared to neat acrylate resin and acrylate resin containing modified $SiO_2$ content of 8 wt%. Meanwhile, the low transparency and high haze of these films slowly appeared at $SiO_2$ content above 10 wt% and $ZrO_2$ content of 5 wt%, but the hardness values were maintained at 2H and 3H, respectively, in comparison with the HB of neat acrylate resin.

Effect of Electrode Materials and Applied Potential in Electrocatalytic Reduction of Carbon Dioxide by Carbon Monoxide Dehydrogenase (일산화탄소탈수소화효소를 이용한 이산화탄소의 전기화학적 환원에 미치는 전극재료와 전위의 영향)

  • Shin, Jun Won;Kim, You-Sung;Song, Ji-Eun;Lee, Sang-Hee;Lee, Sang-Phil;Lee, Ho-Jun;Lim, Mi-Ran;Shin, Woon-Sup
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.165-169
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    • 2008
  • The effect of reduction of carbon dioxide by CODH(Carbon Monoxide Dehydrogenase) was compared on glassy carbon and gold working electrodes. In case of gold electrode, the choice of the optimum applied potential is very important since $H_2$ evolution can be mixed with $CO_2$ reduction. On the other hand, efficient $CO_2$ reduction was observed up to -650 mV vs. NHE on glassy carbon in neutral solution due to the larger overpotential for $H_2$ evolution on glassy carbon surface than that on gold surface. The optimum potential for $CO_2$ reduction was found to be $-570{\sim}600\;mV$ vs. NHE. The current efficiency of $CO_2$ to CO decreased dramatically at more negative potential according to the activity of enzyme decrease and the hydrogen evolution.

Effects of Sintering Additives on the Microwave Dielectric and Sintering Characteristics of (1-x)CaT$iO_{3}$-xLa($Zn_{1}$2/$Ti_{1}$2/)$O_{3}$ (소결조제가 (1-x)CaT$iO_{3}$-xLa($Zn_{1}$2/$Ti_{1}$2/)$O_{3}$계의 소결 및 마이크로파 유전특성에 미치는 영향)

  • Kim, Jin-Seok;Yun, Cheol-Ho;Choe, Ju-Hyeon;Lee, Gyeong-Tae;Sin, Jong-Yun;Park, Hyeon-Su;Mun, Jong-Ha
    • Korean Journal of Materials Research
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    • v.7 no.10
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    • pp.872-876
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    • 1997
  • (1-x)CaTi $O_{3}$-xLa(Z $n_{1}$2/ $Ti_{1}$2/) $O_{3}$의 마이크로 유전특성을 조사하였다. x가 증가함에 따라 비유전율과 공진주파수의 온도계수는 감소하였으며, Qㆍ $f_{0}$는 증가하였다. 그 결과 x=0.5인 (C $a_{0.5}$L $a_{0.5}$)( $Ti_{0.75}$Z $n_{0.25}$) $O_{3}$의 조성에서 $\varepsilon$$_{r}$=51, Qㆍ $f_{0}$=38,000 (at 7 GHz), $\tau$$_{f}$=+5ppm/$^{\circ}C$의 유전특성이 나타났다. (C $a_{0.5}$L $a_{0.5}$)( $Ti_{0.75}$Z $n_{0.25}$) $O_{3}$조성의 소결온도를 저하시키기 위하여 B $i_{2}$ $O_{3}$를 주조성으로한 소결체를 첨가하여 소결 및 유전특성을 조사하였다. 1wt% 0.76B $i_{2}$ $O_{3}$-0.24NiO가 첨가된 경우 소결온도는 15$0^{\circ}C$ 낮아졌으며, 비유전율 ($\varepsilon$$_{r}$), 공진주파수의 온도계수($\tau$$_{f}$), Qㆍ $f_{0}$가 각각 50+5ppm/$^{\circ}C$, 35,000인 마이크로파 유전특성이 얻어졌다. 또한 3wt%의 0.76B $i_{2}$ $O_{3}$-0.24NiO가 첨가된 경우 소결온도는 20$0^{\circ}C$ 저하되었고, 비유전율 ($\varepsilon$$_{r}$)과 공진주파수의 온도계수 ($\tau$$_{f}$)는 변하기 않았으나, Qㆍ $f_{0}$값이 38,000에서 25,000으로 저하되었다. 25,000으로 저하되었다.되었다.되었다.되었다.

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Characteristics of Polyimide-silica Hybrid Materials Prepared from Alkoxide Precursor Using Sol-gel Process (졸-겔법을 이용하여 알콕사이드 전구체로부터 합성된 Polyimide-silica 혼성체의 특성)

  • Kim, Byoung-Woo;Lee, Sung-Hwan;Kim, Sung-Wan;Park, Jae-Hyun;Kim, Jun-Ho;Park, Seong-Soo;Park, Hee-Chan
    • Journal of the Korean Ceramic Society
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    • v.39 no.11
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    • pp.1063-1068
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    • 2002
  • Polyimide/silica(PI/silica) hybrid materials having physical or chemical bonds between the PI and silica network were prepared using sol-gel process through hydrolysis and polycondensation of tetraethoxysilane with the polyamic Acid(PAA) or end-capped PAA solution. PAA solution was synthesized by ring opening reaction of pyromellitic dianhydride and oxydianiline monomers in dimethyl acetamide solution. End-capped PAA solution was synthesized by the addition of 3-aminopropyltriethoxysilane in PAA solution. PI/silica hybrid samples were characterized by infrared spectroscopy, differential thermogravimetry, X-ray diffractometry, scanning electron microscopy, and tensile tester. It has been demonstrated that the properties of hybrid samples were affected by the silica content and the bond type between PI and silica.

Study on Magnetic Property Enhancement of Metal Powders for Magnetic Tape by Using Ultrasonic Dispersion (자기테이프용 Metal Powder의 초음파 분산에 의한 자기적 특성 향상에 관한 연구)

  • Kim, Chang-Gon;Choe, Hyeon-Seung;Jang, Hak-Jin;Yun, Seok-Yeong;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.972-977
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    • 2001
  • It was investigated the effect of ultrasonic treatment on magnetic property of ultra fine magnetic Fe powders ($\alpha$-Fe) for magnetic tape. The properties were characterized with vibrating sample magnetometer (VSM), particle size analyzer (PSA) and scanning electron microscope (SEM). At 4hours ultrasonic treatment of 70 kHz, magnetic properties such as squareness ratio (S.Q. : 0.8868), orientation ratio (O.R. : 2.45) and switching field distribution (S.F. D. : 0.394) before taping were relatively enhanced. Cumulative particle size distribution of less than 5$\mu\textrm{m}$ fine powder was above 90% below 1 hour leaving time after ultrasonic treatment and it was supposed that ultrasonic treatment prevent aggregation. The magnetic values of S.Q. and S.F.D. of tape manufactured at 70 kHz and 4hour ultrasonic treatment were improved from 0.7747, 0.3818 to 0.8037, 0.3706, respectively. Electro-magnetic property used as in-output signal characteristic was improved, which showed that ultrasonic treatment developed the magnetic properties.

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Low-Loss Multimode Waveguides Using Organic-Inorganic Hybrid Materials

  • Yoon, Keun-Byoung
    • Macromolecular Research
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    • v.12 no.3
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    • pp.290-292
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    • 2004
  • Multimode channel waveguides were fabricated using a direct UV patterning technology from thick films deposited by the one-step dip-coating of an organic/inorganic hybrid material (ORMOCER(equation omitted). The core size of the covered ridge waveguide was 43${\times}$51 $\mu\textrm{m}$$^2$; the waveguides can be readily prepared for multimode applications by direct UV patterning. The waveguides exhibited smooth surface profiles and a low optical loss of 0.07 ㏈/cm at the most important wavelength (850nm) used for optical interconnects.