• Title/Summary/Keyword: inorganic content

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Liquid Uptake and Methanol Transport Behaviour of PVDF/SPEEK/TiO2 Hybrid Membrane for DMFC (DMFC용 PVDF/SPEEK/TiO2 하이브리드 막의 수분함량과 메탄올 전이현상)

  • You, Sun-Kyung;Kim, Han-Joo;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.8 no.4
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    • pp.177-180
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    • 2005
  • A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nano particles content. Their liquid uptake, methanol permeability and proton conductivity as a function of inorganic oxide content were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and liquid uptake. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of the morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with the standard nafion membrane.

Performance Evaluation of Carbon-Reducing Soil Pavement using Inorganic Binder (무기계 바인더를 이용한 탄소저감형 흙포장의 성능평가)

  • Yoo, Ji Hyeung;Kawk, Gi Bong;Kim, Dae Sung
    • International Journal of Highway Engineering
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    • v.17 no.6
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    • pp.19-26
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    • 2015
  • PURPOSES : This study intends to develop an inorganic soil pavement material using industrial by-products and to evaluate its applicability as a road pavement material. METHODS : In this study, a compressive strength experiment was conducted based on the NaOH solution molarity and water glass content to understand the strength properties of the soil pavement material according to the mixing ratio of alkali activator. In addition, the strength characteristic of the inorganic soil pavement material was analyzed based on the binder content. The performance of the soil pavement was evaluated by conducing an accelerated pavement test and a falling weight deflectometer (FWD) test. RESULTS : As a result of the soil pavement material test based on the mixture ratio of alkali activator, it was identified that the activator that mixed a 10 M NaOH solution to water glass in a 5:5 ratio is appropriate. As a result of the inorganic soil pavement materials test based on the binder content, the strength development increased sharply when the amount of added binder was over 300 kg; this level of binder content satisfied 28 days of 18 MPa of compression strength, which is the standard for existing soil pavement design. According to the measured results of the FWD test, the dynamic k-value did not show a significant difference before or after the accelerated pavement testing. Furthermore, the effective modulus decreased by approximately 50%, compared with the initial effective modulus for pedestrian pavement. CONCLUSIONS : Based on these results, inorganic soil pavement can be applied by changing the mixture proportions according to the use of the pavement, and can be utilized as road pavement from light load roads to access roads.

Effects of inorganic salts on biomass production, cell wall components, and bioethanol production in Nicotiana tabacum

  • Sim, Seon Jeong;Yong, Seong Hyeon;Kim, Hak Gon;Choi, Myung Suk;Choi, Pil Son
    • Journal of Plant Biotechnology
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    • v.48 no.4
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    • pp.278-288
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    • 2021
  • The development of bioenergy through biomass has gained importance due to the increasing rates of fossil fuel depletion. Biomass is important to increase the productivity of bioethanol, and production of biomass with high biomass productivity, low lignin content, and high cellulose content is also important in this regard. Inorganic salts are important in the cultivation of biomass crops for the production of biomass with desirable characteristics. In this study, the roles of various inorganic salts in biomass and bioethanol production were investigated using an in vitro tobacco culture system. The inorganic salts evaluated in this study showed dramatic effects on tobacco plant growth. For example, H2PO4 substantially improved plant growth and the root/shoot (R/S) ratio. The chemical compositions of tobacco plants grown in media after removal of various inorganic salts also showed significant differences; for example, lignin content was high after Mg2+ removal treatment and low after K+ treatment and H2PO4 removal treatment. On the other hand, NO3- and H2PO4 treatments yielded the highest cellulose content, while enzymatic hydrolysis yielded the highest glucose concentration ratio 24 h after NH4+ removal treatment. The ethanol productivity after H2PO4 removal treatment was 3.95% (w/v) 24 h after fermentation and 3.75% (w/v) after 36 h. These results can be used as the basis for producing high-quality biomass for future bioethanol production.

The Properties of ORMOSIL with Adding Organic Silane in TEOS System(I) (고분자 Silane을 첨가한 TEOS계의 ORMOSIL 특성(I))

  • 이동아;김구대;김현민
    • Journal of the Korean Ceramic Society
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    • v.29 no.8
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    • pp.593-600
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    • 1992
  • Through sol-gel processing, Inorganic-organic composite was obtained. The influence of water content used in hydrolysis on the bonding state, microstructure, strength, and elongation into IR, NMR, Tg, etc. As the water content was increased, the bonds between inorganic Si-(OH) and organic Si-(OH) increased, and relatively denser microstructure was formed. Tensile strength and elongation decreased with amount of water content.

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Antibacterial Activity and Mechanical Properties of Poly(Lactic-Acid) Composites Containing Zeolite-type Inorganic Bacteriocide

  • Park, Yuri;Park, Tae-Hee;Lee, Rami;Baek, Jong-sung;Jhee, Kwang-Hwan;Bang, Daesuk
    • Elastomers and Composites
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    • v.52 no.3
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    • pp.201-210
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    • 2017
  • We studied the antibacterial effect and mechanical properties of PLA composites with in organic porous zeolite-type bacteriocides. The specimens were prepared by an intermeshing co-rotating twin screw extruder using different contents of inorganic bacteriocide. The degree of dispersion of the in organic bacteriocide in the PLA composite was confirmed by FE-SEM. The contents of Ag and Zn in the composite were also investigated by energy dispersive spectroscopy at different concentrations of the inorganic bacteriocide. The antibacterial effects were analyzed by turbidity analysis, shaking culture, and drop-test. The mechanical properties, such as the tensile and flexural properties, impact strength, and physical properties, were also investigated. As the content of inorganic bacteriocide increased, the antibacterial activity was increased, especially against Staphylococcus aureus. Mechanical properties, namely, tensile strength, elongation, flexural strength, and impact strength, tended to decrease with an increase in inorganic bacteriocide content, but the tensile and flexural modulus increased.

Luminescent Properties of Europium-Doped Lanthanum Silicon Nitride Phosphor

  • Lences, Zoltan;Hrabalova, Monika;Czimerova, Adriana;Sajgalik, Pavol;Zhou, You;Hirao, Kiyoshi
    • Journal of the Korean Ceramic Society
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    • v.49 no.4
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    • pp.325-327
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    • 2012
  • Europium-doped $LaSi_3N_5$ phosphor was synthesized from LaSi/Si/$Si_3N_4/Eu_2O_3$ mixture by nitridation at $1390^{\circ}C$ and additional annealing at $1650^{\circ}C$ for 4 h. The phosphor shows emissions in the green light region with a maximum at 560 nm. With increasing europium content in the general formula $La_{1-z}Eu_zSi_3N_{5-z}O_{1.5z}$ from z = 0.01 to 0.06 there was a maximum emission for z = 0.04 followed by concentration quenching for the highest europium content (z = 0.06).

The Thickness Change of the Phosphor Ink Layer and the Dielectric Ink Layer of a Inorganic Powder EL Lamp That was produced by Screen Printing Technique (스크린 인쇄 기법에 의해 제작된 분산형 무기 EL 램프의 형광층 및 유전층의 두께 변화)

  • Moon, Kil-Hwan;Kang, Young-Reep
    • Journal of the Korean Graphic Arts Communication Society
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    • v.29 no.2
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    • pp.83-92
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    • 2011
  • A inorganic powder EL lamp was made by screen printing technique with phosphor ink and dielectric ink. The thickness change of a phosphor ink layer and a dielectric ink layer were not influenced on dielectric content, but rely on phosphor size and vehicle. Once finishing screen printing technique with phosphor ink and dielectric ink, and its surface has been printed again before not drying of phosphor ink and dielectric ink. Then phosphor ink and dielectric ink were not transferred. The electric capacity of inorganic powder EL lamp was more influenced on dielectric content than the thickness of dielectric ink layer, and it was more dependent on the thickness of phosphor ink layer than the thickness of dielectric ink layer.

Electrical AC Insulation Breakdown Characteristics of Various Epoxy / Heterogeneous Inorganic Mixed Composite (여러 종류의 에폭시/이종무기물 혼합 콤포지트의 전기적 교류 절연파괴 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.11
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    • pp.1463-1470
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    • 2018
  • In this study, 20 types of samples were prepared by mixing different kinds of inorganic materials to develop insulation materials for epoxy - based GIS substation equipment used under high voltage environmentally friendly insulation gas. One of the electrical characteristics, AC insulation breakdown experiment was performed. As mixing ratio of mixed heterogeneous inorganic materials, the dielectric breakdown strength was increased with increasing filler ratio of micro silica, micro silica : micro Alumina, 1:9, 3:7, 5:5, 7:3, 9:1, and decreased as the filling amount of micro alumina increased. The AC insulation breakdown characteristics were the best when the composition ratio was 9:1. The higher the content of silica, the better the interfacial properties, and the larger the alumina content ratio, the worse the interfacial properties.

Titanium Dioxide Nanoparticles filled Sulfonated Poly(ether ether ketone) Proton Conducting Nanocomposites Membranes for Fuel Cell

  • Kalappa, Prashantha;Hong, Chang-Eui;Kim, Sung-Kwan;Lee, Joong-Hee
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.87-90
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    • 2005
  • This paper presents an evaluation of the effect of titanium dioxide nanoparticles in sulfonated poly(ether ether ketone) (SPEEK) with sulfonation degree of 57%. A series of inorganic-organic hybrid membranes were prepared with a systematic variation of titanium dioxide nanoparticles content. Their water uptake, methanol permeability and proton conductivity as a function of temperature were investigated. The results obtained show that the inorganic oxide network decreases the proton conductivity and water swelling. It is also found that increase in inorganic oxide content leads to decrease of methanol permeability. In terms of morphology, membranes are homogeneous and exhibit a good adhesion between inorganic domains and the polymer matrix. The properties of the composite membranes are compared with standard nafion membrane.

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