• 한국염색가공학회지
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• 제17권4호
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• pp.1-6
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• 2005

We studied the degree of variety of indigo for the electrochemical redox reaction in addition of reducing agent and the electrokinetic parameters. The electrokinetic parameters such asthe number of electron and the exchange rate constant were obtained by cyclic voltammetry. With increasing scan rate, the reduction currents of indigo were increased and the reduction potentials were shifted to the negative direction. As the results, the reduction processes of the indigo were proceeding to totally irreversible and diffusion controlled reaction. Also, exchange rate constant ($k^0$) and diffusion coefficient ($D_0$) of indigo were decreased by increasing concentration of reducing agent. We found that the less concentration, the more easily diffused and electron transferred and the product was more stable.

• 한국염색가공학회지
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• 제21권2호
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• pp.29-39
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• 2009

The color mixture, obtained from Indigo and Japanese pagoda tree, was applied to cellulose fibers such as cotton, linen and rayon to diversify color gamut of natural dyes. The color mixture was tried with two different methods. The first process was that cellulose fibers were dyed with $5{\sim}25%$ owf Japanese pagoda tree solution, and then dyed 1 to 4 times with Indigo. The second process was dyeing 1 to 7 times with Indigo, followed by dyeing with $5{\sim}25%$ owf Japanese pagoda tree solution. K/S value of the dyed fibers with one colorant and color mixture increased in the order of linen, cotton, rayon. It was also found that the first process could give higher K/S values than the second process.

• 한국염색가공학회지
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• 제20권3호
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• pp.18-24
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• 2008

The purpose of this study is to develop the dyeing method with dry leaves of indigo plant. Coloring matter was extracted from dry leaves of indigo plant with hot sodium hydroxide solution. The extract was reduced with sodium dithionite, and it was used for dyeing cotton fabrics under various conditions. UV-visible absorption spectra of extract, reduction rate of extracts by reducing agent, and the surface color of dyed cotton, lightfastness were examined. For the initial 20 minutes, the absorbance of indigo solution rapidly decreased. However, several hours later, the decreasing rate retarded. By repeating the dyeing process, the shade looked deeper and deeper. At $30-40^{\circ}C$, the value of K/S reached the highest point. The concentration of indigo solution in dye bath seemed to playa critical role for the reaction of the reducing agent. It was observed that the surface color of cotton fabrics was getting bluish and its degree of value and chroma seemed slightly decreased as the K/S value was increasing. The lightfastness was clearly enhanced by increasing the K/S value.

• 한국의류학회지
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• 제26권2호
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• pp.325-336
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• 2002

This study investigated color change of combination dyeing silk fabrics dyed with Turmeric extracts and Gardenia extracts after dyeing of Indian indigo. Experimental variables include the condition of dyeing time and concentration of Turmeric extracts, Gardenia extracts, arid dyeing cycle of Indian indigo. Surface color of silk fabrics dyed with Turmeric 77tracts after one cycle dyeing, two cycles dyeing, four cycles dyeing of Indian indigo was changed from 5.1GY to 0.3GY, 1.5G to 3.5GY and 6.5G to 5.8GY by increase of concentration of Turmeric extracts. On the other hand, Surface color of silk fabrics dyed with Gardenia extracts after one cycle dyeing, two cycles dyeing, four cycles dyeing of Indian indigo was changed from 7.5Y to 3.9Y, 1.2GY to 6.7Y and 4.0GY to 8.6GY by increase of concentration of Gardenia extracts. Its range of surface color was changed to green and yellowish green by increase of dyeing time with concentration of Turmeric extracts. On the other hand, its range of surface color was changed to yellowish and yellow by increase of dyeing time with concentration of Gardenia extracts.

• 한국의류학회지
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• 제41권2호
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• pp.212-223
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• 2017

This research investigated the screen printing method for natural indigo dye on cotton fabric. We examined four types of thickening agents (arabic gum, guar gum, indalca, and CMC) based on their ability to retard the oxidation of natural indigo print paste while the paste remained on the screen frame. The results indicated that the retardation of arabic gum towards oxidation was the greatest among the four types of thickening agents. The highest K/S value of the printed cotton was observed with a dye concentration of 50g/L fermented indigo powder. The best printing results were obtained when the duration of dye efficiency was tested for the 10 minutes of the dye paste remaining on the screen with a thickening agent concentration of 26.56% that represented 530 cps viscosity. The test of colorfastness to washing and rubbing of the printed cotton resulted in grade 5, and the colorfastness to sunlight resulted in grade 4. Chinese traditional Naminwhapo printing was reproduced on cotton fabric using the natural indigo printing method derived from this study.

• 한국의류학회지
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• 제32권12호
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• pp.1963-1970
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• 2008

전통적인 니남쪽염료 제조법을 기준으로 굴껍질가루 대신 칼슘하이드록사이드를 사용하여 천연인디고분말염료를 만들었다. 제조한 인디고분말염료에 대한 텐셀의 염색성을 몇 가지 실험조건에서 조사하였으며 염색견뢰도를 측정하였다. 제조한 인디고분말염료는 약 15.5%의 인디고 성분과 0.757%의 인디루빈 성분을 함유하는 것으로 분석되었다. 환원과 염색을 자동염색기로 one-step으로 하였으며 환원제로 소디움하이드로설파이트를 사용하였다. 최대염착량은 $60^{\circ}C$에서 얻었으며 초기 20분 동안에 염착이 거의 이루어졌다. 본 연구의 실험조건 범위에서는 염료농도 4g/L까지는 2g/L의 환원제 농도에서, 염료농도 8g/L에서는 3g/L의 환원제 농도에서 최대염착량을 보였다. 텐셀은 염욕에 가성 소다를 넣지 않고 pH 5.75에서 염색할 때 훨씬 높은 염착량을 나타냈다. 염색견뢰도는 4/5-5등급으로 대체로 우수하였으며, 염착량이 낮을수록 더 높은 광퇴색을 보였다.

• 복식문화연구
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• 제20권4호
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• pp.463-474
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• 2012

The purpose of this research was to find the suitable dyeing method for dyeing cotton fabric into indigo blue color using the raw indigo powder dyes sold in the Korean market. The research focused primarily on the comparison of the non-reduced dyeing method and the reduced dyeing method. The dyeing effects using different dyeing temperatures ($2{\sim}80^{\circ}C$) and different concentrations of reducing agent and alkali were also investigated. It was found that the reduced dyeing method must be used for dyeing cotton into indigo blue color using the commercial raw indigo powder dyes. The best result was obtained by $20^{\circ}C$ dyeing with the $40^{\circ}C$ dyeing giving a comparable result. The intensity of the blue color could be enhanced by increasing the alkali concentration. The non-reduced dyeing could not dye cotton fabric into indigo blue color at any given dyeing temperatures ($2{\sim}80^{\circ}C$). The reduce-dyed cotton fabrics showed a gradual color change upon repeated washing and extended sunlight exposure, the most color change occurring after the first two washing cycles and the first 5 hours of sunlight exposure. The standard tests of colorfastness showed that the reduce-dyed cotton fabrics had good to excellent colorfastness whereas the colorfastness of the non-reduce-dyed cotton fabrics were mostly poor.

• 복식문화연구
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• 제19권2호
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• pp.376-388
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• 2011

The purpose of this study is to examine the types and characteristics of Chinese indigo dyed designs performed until today in private houses of Chinese minority races and to examine the modern value of traditional dyeing crafts of minority races by investigating the cases of utilizing modern private Chinese indigo dyed designs. As the research methodology for theoretical study about the history of Chinese traditional pattern dyeing, the origin, types and characteristics of Chinese indigo dyed designs, the preceding research data, photo data, and Internet data were utilized, and for the empirical research on Chinese traditional dyeing techniques and the cases of utilizing today Chinese indigo dyed designs, the on-site survey on Guizhou and Yunnan was conducted during February and March 2008 and the data were collected and analyzed. Based on the results of this research, it was found that Chinese indigo dyed designs represented Chinese traditional pattern dyeing, which was inherited and developed mainly in Chinese minority races and Chinese. It could be seen that according to geographical distribution and characteristics of each race, the types and characteristics of dyeing techniques were formed, which are classified into the batik of the Miao of Guizhou in the Chinese southwestern region, the tie-dyeing of Bai of Yunnan, and Chinese blue calico(resist printing) of Chinese private houses in the Hunan and Huseo regions, and these represent the three typical Chinese dyeing techniques today. Based on the results of empirical research on the utilizing cases, focusing on the traditional living handicrafts of Chinese minority races, traditional cultural articles, and artworks, the modern values such as practical, cultural, and artistic values of Chinese indigo dyed designs could be rediscovered.

• 감성과학
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• 제20권3호
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• pp.3-12
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• 2017

본 연구에서는 인체 친화적이고 환경 친화적인 패션제품 소재기획을 위한 기초 자료를 제시하고자 수행되었다. 이를 위해서 4종의 섬유소 소재를 대상으로 염색조건을 달리하여 천연 쪽 염색을 실시하여 색채특성과 색채감성을 평가하였으며, 이러한 특성이 선호도에 미치는 영향을 분석하였다. 쪽 염색된 직물은 모두 중, 저명도와 저채도의 남색(PB)을 구현하였다. 이들 직물의 색채특성은 섬유종류와 염색조건에 따라 유의한 차이를 보였다. 쪽 염색된 직물에 대한 색채감성은 스포티 감성, 클래식 감성, 내추럴 감성 등 3가지 요인으로 분류되었다. 이러한 색채감성은 섬유종류와 염색조건에 따라 부분적으로 유의한 차이를 나타내었다. 또한 쪽 염색 직물의 색채특성과 색채감성 요인 간에는 부분적으로 유의한 상관관계를 보였다. 쪽 염색 직물의 색채 선호도에 영향을 주는 요인으로는 색채감성 요인 중에서 클래식 감성과 스포티 감성, 색채특성에서는 $L^*$값인 것으로 나타났다.

• 한국염색가공학회지
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• 제32권4호
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• pp.193-198
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• 2020

In this study, the validity of extracts from food waste as biocatalyst for indigo reduction was examined. Dried food wastes such as apple peel and corn waste were water-extracted and freeze-dried. The reducing power of extracts for indigo was evaluated by the oxidation-reduction potential(ORP) measurement of reduction bath and color strength(K/S value) of the fabrics dyed in the indigo reduction bath. Total sugar contents of the apple peel and corn waste extracts were 60.56% and 62.36%, respectively. Antioxidant activity was 64.78% for the extract of apple peel and 7.96% for the extract of corn waste. Indigo reduction took place quickly with both extracts, and maximum color strength was obtained up to 15.91 and 12.11 within 1-3 days, respectively. The oxidation-reduction potential of reduction bath was stabilized in the range of -500 ~ -620 mV according to the kinds of food waste and the extract concentration. At higher concentration of the extracts, reduction power was maintained for longer time and stronger color strength was obtained. Compared to sodium dithionite, the reducing power of the studied extracts was lower, but the reduction stability was superior to it. The studied extracts were effective biocatalyst as biodegradable and safe alternatives to sodium dithionite for indigo reduction.