• Title/Summary/Keyword: in situ process

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Study of Polycarbonate/MWNT Electrospun Nanofiber and Its Multi-Filament Application (전기방사에 의한 카본나노튜브/폴리카보네이트 나노섬유와 복합필라멘트 특성에 관한 연구)

  • Choi, Jae-Won;Lee, Kwang-Hoon;Hwang, Seok-Ho;Kim, Jeong-Yeol;Lee, Sang-Won;Huh, Wansoo
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.413-420
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    • 2008
  • Over the past decade, there have been significant advancement in the field of electrospinning area. This study has focused on preparing yarn using polycarbonate (PC) nanofibers including modified multi-walled carbon nanotube (mMWNT) by solution electrospinning process using the mixture of solvents consisting of tretrahydronfuran (THF) and N,N-dimethylformamide (DMF). In order to enhance the dispersion, MWNT was chemically modified. TEM analysis for the prepared PC/mMWNT nanofibers reveals that mMWNT was well-dispersed into the PC nanofiber matrix. Also with increasing contents of mMWNT, thermal stability of PC/mMWNT nanofibers was improved than that of PC nanofibers. Moreover when 3 to 5 wt% of mMWNT was added, the nanofibers showed good electrical properties expecting antistatic effect, ranging 109.1~109.5 ${\Omega}$. It was confirmed that the multi-filament fibers using PC/mMWNT had $60{\sim}100{\mu}m$ in diameter and 4~5 cm in length.

Behavior of Bearing Capacity for Shallow Foundation on a Sand overlying Clay Depending on Bearing Capacity Ratio (점토층 위 모래지반의 지지력비에 따른 얕은 기초의 지지력 거동)

  • Jung, Min Hyung;Shin, Hyo Hee;Lee, Song
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.15 no.1
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    • pp.198-208
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    • 2011
  • When a structure which has relatively low load constructs on soft clay, the bearing capacity of the ground will be improved by sand overlying clay. In this condition, verifying the bearing capacity is difficult from the P.B.T etcetera in the in-situ. So, it is needed to estimate precise bearing capacity in the design process. In this study, 2-dimensional chamber tests and FEM analyses are conducted to evaluate behavior of bearing capacity for shallow foundations on a sand overlying clay. Because depth ratio H/B and bearing capacity ratio $q_c/q_s$ are selected as main factors, height of a sand, undrained shear strength of a clay and width of a loading are designated as variables. Results from chamber tests are very similar with those of FEM analyses. And it shows that punching shear mechanism is more suitable than the equation of Okamura et al.(1998). To make continual application of load spread mechanism, the equivalent load spread angle is proposed for H/B and $q_c/q_s$. Also, the linear regression equation of critical depth ratio Hf is suggested for $q_c/q_s$.

Delamination Prediction of Semiconductor Packages through Finite Element Analysis Reflecting Moisture Absorption and Desorption according to the Temperature and Relative Humidity (유한요소 해석을 통해 온도와 상대습도에 따른 수분 흡습 및 탈습을 반영한 반도체 패키지 구조의 박리 예측)

  • Um, Hui-Jin;Hwang, Yeon-Taek;Kim, Hak-sung
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.3
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    • pp.37-42
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    • 2022
  • Recently, the semiconductor package structures are becoming thinner and more complex. As the thickness decrease, interfacial delamination due to material mismatch can be further maximized, so the reliability of interface is a critical issue in industry field. Especially, the polymers, which are widely used in semiconductor packaging, are significantly affected by the temperature and moisture. Therefore, in this study, the delamination prediction at the interface of package structure was performed through finite element analysis considering the moisture absorption and desorption under the various temperature conditions. The material properties such as diffusivity and saturated moisture content were obtained from moisture absorption test. The hygro-swelling coefficients of each material were analyzed through TMA and TGA after the moisture absorption. The micro-shear test was conducted to evaluate the adhesion strength of each interface at various temperatures considering the moisture effect. The finite element analysis of interfacial delamination was performed that considers both deformation due to temperature and moisture absorption. Consequently, the interfacial delamination was successfully predicted in consideration of the in-situ moisture desorption and temperature behavior during the reflow process.

Fracture Behaviors of Jointed Rock Model Containing an Opening Under Biaxial Compression Condition (이축압축 조건에서 공동이 존재하는 유사 절리암반 모델의 파괴 거동)

  • SaGong, Myung;Yoo, Jea-Ho;Park, Du-Hee;Lee, J.S.
    • Journal of the Korean Geotechnical Society
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    • v.25 no.10
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    • pp.17-30
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    • 2009
  • Underground construction such as tunneling can induce damages on the surrounding rock mass, due to the stress concentration of in situ stresses and excessive energy input during construction sequence, such as blasting. The developed damage on the rock mass can have substantial influence on the mechanical and hydraulic behaviors of the rock masses around a tunnel. In this study, investigation on the generation of damage around an opening in a jointed rock model under biaxial compression condition was conducted. The joint dip angles employed are 30, 45, and 60 degrees to the horizontal, and the synthetic rock mass was made using early strength cement and water. From the biaxial compression test, initiation and propagation of tensile cracks at norm to the joint angle were found. The propagated tensile cracks eventually developed rock blocks, which were dislodged from the rock mass. Furthermore, the propagation process of the tensile cracks varies with joint angle: lower joint angle model shows more stable and progressive tensile crack propagation. The development of the tensile crack can be explained under the hypothesis that the rock segment encompassed by the joint set is subjected to the developing moment, which can be induced by the geometric irregularity around the opening in the rock model. The experiment results were simulated by using discrete element method PFC 2D. From the simulation, as has been observed from the test, a rock mass with lower joint angle produces wider damage region and rock block by tensile cracks. In addition, a rock model with lower joint angle shows progressive tensile cracks generation around the opening from the investigation of the interacted tensile cracks.

The Effect of Rainfall on the Stability of Mudstone Slope in Consideration of Collapse Record (이암 절취사면의 붕괴이력을 고려한 강우침투에 따른 안정성 분석)

  • Jeon, Byeong-Chu;Lee, Su-Gon;Kim, Young-Muk;Chung, Sung-Rae
    • Journal of the Korean Geotechnical Society
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    • v.25 no.2
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    • pp.55-66
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    • 2009
  • At the mudstone slope located on the roadside of the Seokri area in Donghae-myeon, Pohang, Gyeongsangbuk-do, this study was performed to analyze the effects of rainfall on the stability of slope through seepage analysis according to the precipitation type of the mudstone slope, referring to the actual case of slope failure. For this, precise geological survey, geophysical exploration and drilling survey for the slope where the failure occurred were performed and followed by analysis of detailed soil layer. For the section where failure surface located, the durability reduction of rocks was measured through slaking/swelling tests and the permeability was measured through in-situ permeability tests for each soil layer. In addition, the change of strength parameter and process of instability were analyzed by back analysis, using Talren 97 and Slope/W programs, in the slope. By applying different precipitation conditions to the geographical conditions of the slope that had actual failure records, the slope stability was analyzed by seepage analysis according to duration of rainfall and rise of groundwater level resulting from the flow of rainfall caused by development of geological structures and the slope surface condition.

Reliability-Based Design Optimization for a Vertical-Type Breakwater with an Emphasis on Sliding, Overturn, and Collapse Failure (직립식 방파제 신뢰성 기반 최적 설계: 활동, 전도, 지반 훼손으로 인한 붕괴 파괴를 중심으로)

  • Yong Jun Cho
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.36 no.2
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    • pp.50-60
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    • 2024
  • To promote the application of reliability-based design within the Korean coastal engineering community, the author conducted reliability analyses and optimized the design of a vertical-type breakwater, considering multiple limit states in the seas off of Pusan and Gunsan - two representative ports in Korea. In this process, rather than relying on design waves of a specific return period, the author intentionally avoided such constraints. Instead, the author characterized the uncertainties associated with wave force, lift force, and overturning moment - key factors significantly influencing the integrity of a vertical-type breakwater. This characterization was achieved by employing a probabilistic model derived from the frequency analysis results of long-term in-situ wave data. The limit state of the vertical-type breakwater encompassed sliding, overturning, and collapse failure, with the close interrelation between wave force, lift force, and moment described using the Nataf joint probability distribution. Simulation results indicate, as expected, that considering only sliding failure underestimates the failure probability. Furthermore, it was shown that the failure probability of vertical-type breakwaters cannot be consistently secured using design waves with a specific return period. In contrast, breakwaters optimally designed to meet the reliability index requirement of 𝛽-3.5 to 4 consistently achieve a consistent failure probability across all sea areas.

Laboratory and Field Performance Evaluation of Acryl Resin Based Solar Radiation Reflective Pavement (아크릴 수지를 이용한 차열성 포장의 실내 및 현장 공용성 평가)

  • So, Kyung-Rock;Lee, Hyun-Jong;Baek, Jong-Eun;Lee, Sang-Yum
    • International Journal of Highway Engineering
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    • v.13 no.4
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    • pp.19-28
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    • 2011
  • This study developed a solar radiation reflection pavement, so called a cool pavement, to lessen the urban heat island effect by coating a pavement surface with acrylic resins mixed with light-colored pigments. From a laboratory test, simulating solar heating process in pavements, the cool pavement reduced more than $12^{\circ}C$ of pavement temperature at $60^{\circ}C$ compared to a control porous pavement. With the increase of the mixing ratio of the pigments to acrylic resins, the temperature reduction effect increased, but its workability became worse due to higher viscosity. As a result, an appropriate mixing ratio was determined as 15%. The cool pavement had better durability than the control pavement: One quarter of Catabro loss and twofold dynamic stability. Its adhesion was also higher enough not to be debonded under traffic loading. In-situ noise and friction tests conducted in two field sites showed that the cool pavement reduced its noise level by 3.7dB in average and increased its friction level by 30% compared to the control pavement. The permeability of the cool pavement was little lower than the control pavement, but higher enough to satisfy the minimum requirement for porous pavements.

Stabilization of cubic-BN/hexagonal-BN Mixed Films by Post-Annealing (후 열처리에 의한 cubic-BN 상과 hexagonal-BN상 혼합 막의 안정성 향상)

  • 박영준;최제형;이정용;백영준
    • Journal of the Korean Vacuum Society
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    • v.9 no.2
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    • pp.155-161
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    • 2000
  • BN films composed of c-BN(70%) and h-BN(30%) phases have been synthesized by the ion beam assisted deposition (IBAD) process and stabilized by post-annealing. Boron was e-beam evaporated at 1.2 $\AA$/sec and nitrogen was ionized and accelerated at about 100 eV by the end-hall type ion gun. Substrates were negatively biased by DC 400 and 500 V, respectively, and heated at $700^{\circ}C$. Synthesized BN films were in-situ post-annealed at 700 or $800^{\circ}C$, respectively, for 1 hr without breaking vacuum. BN films without post-annealing were peeled off from substrates immediately when they were exposed to the air while those with post-annealing at $800^{\circ}C$ were stabilized. Post annealing reduced the film stress from 4.9 GPa to 3.4 GPa, but no considerable stress release in the c-BN phase was observed, contrary to previous reports that the stress relaxation in the c-BN phase is the main mechanism for the stabilization. Structural and chemical relaxation of non c-BN phase is supposed to be responsible for the film stress reduction and, in turn, stabilization, especially when the c-Bn content of the film is not high.

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Environmental Ecological Status of Suncheon Bay and Its Application to the Criteria of UNESCO World Nature Heritage (순천만 연안의 환경생태현황 및 세계자연유산 등재기준 적용 분석)

  • Kim, Kyungwon;Lee, Kyong-Jae;Han, Bong-Ho
    • Korean Journal of Environment and Ecology
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    • v.27 no.5
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    • pp.625-641
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    • 2013
  • This study is analyzed the environmental ecological status of Suncheon Bay and its applicable possibility to the selection criteria of UNESCO World Natural Heritage (hereafter Criteria). The study shows that the formation process of the tidal-flats in Suncheon bay could apply to the Criteria VIII, "to be outstanding examples representing major stages of earth's history." The landscape pattern of Suncheon Bay is deduced various patterns based on 5 biotope types: tidal-flat, rice-paddy, field area, coniferous natural forest, and broadleaf natural forest. Its landscape characteristic is a harmonized composition of various landscape including mountains, rivers, fields, and tidal-flats. It is judged that the unique landscape of Suncheon Bay falls under the criteria VII, "areas of exceptional natural beauty and aesthetic importance." In addition, Suncheon Bay, the habitat of the Hooded Crane as internationally endangered species, comes under the criteria X, "the most important and significant natural habitats for in-situ conservation of threatened species." The study shows, however, that any other designation for protected area including national park or biosphere reserve is a prerequisite for designation of World Nature Heritage. In particular, it could evaluate whether it is qualified of the Criteria after the integrated conservation and management to the Sucheon bay as well as the southwestern tidal-flat is preceded.

Refractive index change of nonlinear polymer thin films induced by corona poling and quantitative evaluation of poling effect (코로나 극성배향이 비선형 고분자박막의 복소굴절율에 미치는 영향 및 배향효과의 정량화)

  • 길현옥;김상준;방현용;김상열
    • Korean Journal of Optics and Photonics
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    • v.10 no.3
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    • pp.181-187
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    • 1999
  • We prepared the side-chain type nonlinear optical NPP(N-(6-nitrophenyl)-(L)-prolinol) polymer films by spin coating method. Ellipsometric spectra were in situ collected by using spectroscopic phase modulated ellipsometer while the NPP polymer films were being corona poled at the temperature above glass transition. We calculated film thickness and the refractive index dispersion by modeling the spectro-ellipsometry data in transparent region. We also calculated the refractive index and the extinction coefficient of the polymer films by numerically inverting the spectro-ellipsometry data in absorbing region, while the previously determined film thickness was used. The independently determined extinction coefficient spectra from the analysis of transmission spectra were compared with those by spectro-ellipsometry and they showed an excellent agreement with each other. From the analysis of the complex refractive index change of the NPP polymer thin films induced by the corona poling, we could determine the vertical complex refractive index and the horizontal complex refractive index separately. Using the volume fraction of the vertical component f⊥, the degree of poling of poled NPP polymer films was quantitatively addressed. It is suggested that the present method can be used to quantitatively address the degree of poling in an absolute manner and to depth profile the poled fraction of thick polymer films. It will be useful to understand the structural change of polymer films and hence the poling mechanism during the poling process.

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