• 제목/요약/키워드: in situ physical properties

검색결과 131건 처리시간 0.039초

탄산칼슘 in-situ precipitation 처리된 신문고지의 형태와 물성변화 (Morphological and Physical Properties of ONP Treated by CaCO3 In-situ Precipitation Method)

  • 이영호;정재권;이기승;서영범
    • 펄프종이기술
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    • 제45권6호
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    • pp.44-54
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    • 2013
  • Replacing OMG (old magazine) to ONP (old newspaper) by raising optical property through $CaCO_3$ in-situ precipitation method in white duplex board presents cost reduction and possible drying energy saving. The strength property impairment by the presence of $CaCO_3$ could be supplemented by the fiber furnish treatment or strength polymer addition. In $CaCO_3$ in-situ precipitation of ONP, it was found from morphological study using FlowCAM, an image analyzer, that most of calcium carbonate were formed on the fines, and made the size of the fines larger. For the case of forming calcium carbonate only on the fractionated fines, the size of the fines were the biggest, and there were more clean surface areas available for bonding for the fractionated long fibers when fractionated fibers and fines were regrouped to make paper.

폴리피롤을 이용한 전도성 아크릴 직물의 제조 및 물성 (Preparation and Physical Properties of Conductive Poly(acrylonitrile) Fabrics Containing Polypyrrole)

  • 이영관;조재춘
    • 폴리머
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    • 제24권2호
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    • pp.276-280
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    • 2000
  • 폴리아크릴로니트릴 (PAN) 직물을 매트릭스로 하여 전도성고분자인 폴리피롤(PPy)과 전도성 복합재료 직물을 제조하였다. 복합재료의 제조는 PAN 직물을 피롤과 산화제를 포함하는 용액에 일정 시간동안 함침하여 직물상에서 전도성 고분자의 중합을 in-situ로 유도하는 방법을 이용하였다. 복합재료의 물성을 최적화 하기 위한 반응 조건을 설정하였으며, 이때 arylsulfonate 계통의 도판트를 부가적으로 첨가하여 이들이 복합재료의 물성에 미치는 영향을 검토하였다. 본 연구에서 실험한 다양한 종류의 도판트 중에서 antraquinonesulfonate (AQSA)가 부가적으로 첨가된 전도성 PAN 직물이 가장 우수한 전기전도도와 열적 안정성 및 세탁 견뢰도를 나타내었다.

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중심코아형 록필댐 제체의 물리적 및 역학적 특성 조사 (Investigation of Physical and Mechanical Properties for a Central Core Rockfill Dam)

  • 신동훈
    • 한국지반공학회:학술대회논문집
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    • 한국지반공학회 1999년도 가을 학술발표회 논문집
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    • pp.345-350
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    • 1999
  • In this study the results of investigation on the physical and mechanical properties of a rockfill dam body were provided. On the crest of the old Namgang dam to be excavated partially, various in-situ tests(boring with SPT, sampling of undisturbed sample, field density test, field permeability test) and geophysical investigation works were performed Rock materials, i.e., shale and sandstone, were collected, and their slake durability was evaluated using slaking durability testing method which is suggested by ISRM.

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Rheological characterization of nanoparticle filled polymeric systems

  • Kim, Byoung-Chul;Chae, Dong-Wook
    • 한국고분자학회:학술대회논문집
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    • 한국고분자학회 2006년도 IUPAC International Symposium on Advanced Polymers for Emerging Technologies
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    • pp.219-219
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    • 2006
  • This study focuses on the effects of dispersion method of a nanoparticle in a polymer matrix such as melt mixing, solution blending, and in-situ polymerization on the physical properties of the nanocomposites. Introduction of a nanoparticle to a polymer resulted in some unusual physical properties. In some cases the nanoparticle played a role of a nucleating agent, leading to decreasing induction time to crystallization. In addition, the dispersion state of the nanoparticle in the polymer matrix also had a significant influence on the physical properties of the nanocomposites. Hence the method of introducing the nanoparticle to the polymer made contribution to the rheological properties of the nanocomposite systems.

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국내 화강암의 지반공학적 특성 및 암반분류법과의 상관성에 관한 연구 (Study on the Geotechnical Characteristics of Granite in Korea and their Correlation with Rock Classification Method)

  • 선우춘;류동우;김형목;김기석
    • 터널과지하공간
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    • 제21권3호
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    • pp.205-215
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    • 2011
  • 본 논문은 국내 여러 지역에서 수행된 도로, 철도 및 기타 토목공사를 위한 설계과정에서 이루어진 현지조사 및 시추공을 이용한 현장시험과 실내시험 및 암반평가가 이루어진 화강암의 자료들을 대상으로 물성 및 암반분류방법간의 상관관계에 대해 분석을 실시하였다. 실험실과 현지에서 측정된 화강암의 물성 중에 단위중량, 압축강도, 인장강도, 탄성파속도, 점착력 및 마찰각 그리고 탄성계수 및 변형계수에 대해 분석을 실시하였다. 이들 물성 중에서 압축강도와 각 요소들 사이의 상관관계에 대해서도 검토하였다. 국내 화강암을 대상으로 조사된 RQD, RMR 과 Q 시스템의 암반분류법간의 상관관계에 대해서도 분석을 실시하였고, 기존의 암반분류법간의 상관관계를 보다 간편화하여 상관관계식을 유도하였다. 그리고 현장에서 시추코어를 대상으로 측정된 RQD와 압축강도 값으로부터 RMR 값을 유도하였으며 또한 RMR값을 이용하여 현지암반 탄성계수를 유추하였다.

Physical Property Change of the Gapless Semiconductor $PbPdO_2$ Thin Film by Ex-situ Annealing

  • Choo, S.M.;Park, S.M.;Lee, K.J.;Jo, Y.H.;Park, G.S.;Jung, M.H.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.371-372
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    • 2012
  • We have studied lead-based gapless semiconductors, $PbPdO_2$, which is very sensitive to external parameters such as temperature, pressure, electric field, etc[1]. We have fabricated pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films using the pulsed laser deposition. Because of the volatile element of Pb, it is very difficult to grow the films. Note that in case of $MgB_2$, Mg is also volatile element. So in order to enhance the quality of $MgB_2$, some experiments are carried out in annealing with Mg-rich atmosphere [2]. This annealing process with volatile element plays an important role in making smooth surface. Thus, we applied such process to our studies of $PbPdO_2$ thin films. As a result, we found the optimal condition of ex-situ annealing temperature ${\sim}650^{\circ}C$ and time ~12 hrs. The ex-situ annealing brought the extreme change of surface morphology of thin films. After ex-situ annealing with PbO-rich atmosphere, the grain size of thin film was almost 100 times enlarged for all the thin films and also the PbO impurity phase was smeared out. And from X-ray diffraction measurements, we determined highly crystallized phases after annealing. So, we measured electrical and magnetic properties. Because of reduced grain boundary, the resistivity of ex-situ annealed samples changed smaller than no ex-situ sample. And the carrier densities of thin films were decreased with ex-situ annealing time. In this case, oxygen vacancies were removed by ex-situ annealing. Furthermore, we will discuss the transport and magnetic properties in pure $PbPdO_2$, Co- and Mn-doped $PbPdO_2$ thin films in detail.

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Structures and Physical Properties of in situ composite based on Liquid Crystalline Polymer and Poly(ethylene 2,6-naphthalate) Blends

  • Yoo, Hyun-Oh;Kim, Seong-Hun;Hong, Soon-Man;Hwang, Seung-Sang
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 1998년도 가을 학술발표회논문집
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    • pp.236-239
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    • 1998
  • The in situ composites based on poly(ethylene 2,6-naphthalate) and thermotropic liquid crystalline polymer (LCP) have been an area of increasing interest and study, since LCP exhibits high chemical stabilities and excellent thermo mechanical properties such as high strength and modulus. In a binary, however, poor compatibility and interfacial adhesions between two phases frequently results in deteriorated mechanical properties. (omitted)

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연직배수재에 의한 토양오염물질 추출에 미치는 영향인자 분석 - 토양 및 오염유체의 물성치를 중심으로 (Analysis of Effecting Parameters on Extraction of Soil Contaminants using Vertical Drains - Focusing on Soil and Contaminants Physical Properties)

  • 이행우;장병욱;강병윤;김현태
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2005년도 학술발표논문집
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    • pp.355-360
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    • 2005
  • The properties of contaminants, contaminated soil, and the elapsed time are important factors to in-situ soil remediation. Gabr et. al. (1996) derived the solution equation of contaminant concentration ratio as initial one $(C/C_0)$ with time and spatial changes in contaminated area with vertical drains. The contaminant concentration ratio $(C/C_0)$ is analyzed with time and spatial changes as varying the effective diameter, porosity, shape factor, density of contaminated soil and temperature in ground and unit weight, viscosity of contaminants by using FLUSH1 model. Results from numerical analysis indicate that the most important factor to the in-situ soil remediation using vertical drains is the effective diameter of contaminated soil. It also shows that the viscosity of contaminants, porosity of soil, shape of soil, temperature in ground, unit weight of contaminants are, in order, affected to the soil remediation but density of soil is insignificant to the soil remediation.

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In-situ 중합을 통한 그래핀/수분산 폴리우레탄 나노 복합체 제조 (Preparation of Graphene/Waterborne Polyurethane Nanocomposite through in-situ Polymerization)

  • 차지정;임진형
    • 폴리머
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    • 제37권4호
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    • pp.507-512
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    • 2013
  • 수분산 폴리우레탄(waterborne polyurethane; WPU)의 물리화학적/전기적 특성을 개선하기 위하여 그래핀에 이소시아네이트기를 도입하고 in-situ 방법으로 폴리우레탄을 중합하여 그래핀/WPU 나노 복합체를 제조하였다. 본 연구의 접근 방법으로 그래핀을 2 wt%까지 그래핀/WPU 나노 복합체에 도입하면 기존 WPU에 비해 인장강도가 57%, 전기전도도는 약 $10^2$배 정도 향상되는 결과를 얻었다. 또한 단순 블렌드 방법으로 만든 그래핀/WPU 복합체와 비교하였을 때, in-situ 중합 방법으로 제조된 복합체가 상대적으로 우수한 기계적 물성과 전기 전도도를 가졌다. 이것은 전자현미경을 이용한 복합체 단면의 형태학적 분석으로부터 이소시아네이트기가 개질된 그래핀(iGO)이 in-situ 중합 방법에 기인한 WPU 매트릭스와의 공유결합과 수소결합을 통하여 균일하게 분산되었기 때문이다.

페놀 화학사고 발생으로 오염된 퇴적물에서 페놀의 거동 기작이 원위치 피복의 정화 효율에 미치는 영향 (Effect of the Fate Mechanisms of Phenol on the Remediation Efficiency of In-Situ Capping Applied to Sediment Contaminated by Phenol Chemical Spills)

  • 이아름;최용주
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제27권1호
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    • pp.60-70
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    • 2022
  • We evaluated the performance of in-situ capping to prevent the release of phenol, one of hazardous chemicals of concern for their impact on sediment. Sediment near the estuary of Hyeongsan River, Korea, and commercially-available sand were collected to evaluate their physical properties and phenol sorption characteristics. Biodegradation kinetics of phenol spiked into the sediment was evaluated under freshwater and estuarine salinity conditions. These experimental measurements were parameterized and used as input parameters for executing CapSim, a software predicting the performance of in-situ capping. The CapSim simulation demonstrated that capping with 50-cm sand reduced the phenol release by several orders of magnitude over 0.25- and 1-year duration for almost all simulation scenarios. The variables tested, i.e., cap thickness, pore-water movement, and biodegradation rate, showed high correlation to each other to influence the extent of phenol release from sediment to the water column. The findings and the framework employed to evaluate the performance of in-situ capping in this study can be adopted to determine whether in-situ capping is appropriate remedial approach at sediment sites impacted by hazardous chemicals due to accidental spills.