• Title/Summary/Keyword: improvement of durability

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Effect of Operation Temperature on the Durability of Membrane and Electrodes in PEM Water Electrolysis (PEM 수전해에서 막과 전극의 내구성에 미치는 구동 온도의 영향)

  • Donggeun Yoo;Seongmin Kim;Byungchan Hwang;Sohyeong Oh;Kwonpil Park
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.19-25
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    • 2023
  • Although a lot of research and development has been conducted on the performance improvement of PEM (Proton Exchange Membrane) water electrolysis, the research on durability is still in early stage. This study investigated effect of temperature on the water electrolysis durability when driving temperature of the PEM water electrolysis was increased to improve performance. Voltage change, I-V, CV (Cyclic Voltammetry), LSV (Linear Sweep Voltammetry), Impedance, and FER (Fluoride Emission Rate) were measured while driving under a constant current condition in a temperature range of 50~80 ℃. As the operating temperature increased, the degradation rate increased. At 50~65 ℃, the degradation of the IrO2 electrocatalyst mainly affected the durability of the PEM water electrolysis cell. At 80 ℃, the polymer membrane and electrode degradation proceeded similarly, and the short resistance decreased to 1.0 kΩ·cm2 or less, and the performance decreased to about 1/3 of the initial stage after 144 hours of operation due to the shorting phenomenon.

Durability and Characteristics of Ag-Pd Rod Heater for Bidet Fabricated by Screen Printing Process (스크린 프린팅 공정에 의해 제조된 비데용 Ag-Pd 봉형 발열체의 내구성 및 물성 평가 )

  • Tae-Ung Park;Da-Eun Hyun;Ik-Soo Kim;Sung-Chul Lee;Yeon-Sook Lee;Yong-Nam Kim;Dong-Won Lee;Jong-Min Oh
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.36 no.1
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    • pp.81-87
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    • 2023
  • Heaters using the resistance heating principle are used in various industrial fields that require heat and are also essentially used in bidet among small home appliances. A planar heater and a coil-inserted heater mounted on a conventional commercially used bidet have disadvantages and limitations of complicated manufacturing process and local heating. In this study, silver-palladium (Ag-Pd) powder material was used for a screen-printing process that is more advantageous in achieving simplification than the existing process, and a rod-type heater for bidet was manufactured. The on-off cycle test under actual conditions was conducted to confirm the durability and the capability of the fabricated heater, and the fabricated heater operated more than 2,600 on-off cycles, which means it could be applied for a commercial product. In addition, through the on-off cycles under harsh conditions, the cause of failure was identified after the test that the durability limit temperature of the heater was 850℃. Through Ag-Pd rod heater in this study, it is expected to contribute to the efficient development of electrode materials for heaters and the improvement of the durability of heaters in the future.

Durability Evaluation of Air-Cooled Proton Exchange Membrane Fuel Cells Stacks by Repeated Start-Up/Shut-Down (시동/정지반복에 의한 공랭식 고분자연료전지 스택 내구성 평가)

  • YOO, DONGGEUN;KIM, HYEONSUCK;OH, SOHYEONG;PARK, KWON-PIL
    • Transactions of the Korean hydrogen and new energy society
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    • v.32 no.5
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    • pp.315-323
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    • 2021
  • The air-cooled proton exchange membrane fuel cells (PEMFC) stacks, which is widely used in small-sized PEMFC, have a problem in that durability is weaker than that of the water-cooled type. Because the cathode is open to the atmosphere and the structural problem of the air-cooled stack, which is difficult to maintain airtightness, is highly likely to form a hydrogen/air boundary during start-up/shut-down (SU/SD). Through the accelerated durability evaluation of the 20 W air-cooled PEMFC stack, the purpose of this study was to find out the cause of the degradation of the stack and to contribute to the improvement of the durability of the air-cooled PEMFC stack. In this study, it was possible to evaluate durability in a relatively short time by reducing 20-30% of initial performance by repeating SU/SD 1,000 to 1,200 times on an air-cooled PEMFC stack. After disassembling the stack, each cell was divided into two and the performance analysis showed that the electrode degradation was more severe in the anode outlet membrane electrode assembly (MEA), which facilitates air inflow as a whole, than in the inlet MEA. It was shown that the cathode Pt was dissolved/precipitated to deteriorate the polymer ionomer inside the membrane.

A Study on the Concrete Durability by Fly Ash Replacement Ratio (플라이애쉬 치환율을 고려한 콘크리트의 내구성에 관한 연구)

  • Kim, Dongbaek;Lee, Kwangjae
    • Journal of the Society of Disaster Information
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    • v.10 no.4
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    • pp.566-571
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    • 2014
  • Recently, with concentrated social and engineering interests on durability, diversified subsequent researches have been progressed. The Chloride-induced corrosion, carbonation, freeze-thaw etc, deterioration factors of concrete act to concrete not privately but complexly, Fly ash is most frequently used admixture which is using a reduction method of deterioration. And the fly ash effects on improvement of durability with enhancement of fluidity, decrease of crack with reduction of hydration heat, promotion of long-age strength and have a economic advantage which replaces cement as a binding material. But, fly ash have different qualities and occasionally reduce the durability and strength by adhesion of AE admixture with unburned carbon powder etc. In this study, the experiments will take about various replacement ratio of fly ash concrete, and will analyze, consider the results, after these will verify applicability and validity as admixture and binding material.

Development of Laser Processing Technology and Life Evaluation Method for Lifespan Improvement of Titanium Superhydrophobic Surface (티타늄 초소수성 표면의 수명 향상을 위한 레이저 처리 기법 개발 및 내수명성 평가법 개발)

  • Kyungeun Jeong;Kyeongryeol Park;Yong Seok Choi;Seongmin Kang;Unseong Kim;Song Yi Jung;Kyungjun Lee
    • Tribology and Lubricants
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    • v.40 no.3
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    • pp.91-96
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    • 2024
  • Recently, extensive studies have been carried out to enhance various performance aspects such as the durability, lifespan, and hardness by combining diverse materials or developing novel materials. The utilization of superhydrophobic surfaces, particularly in the automotive, textile, and medical device industries, has gained momentum to achieve improved performance and efficiency. Superhydrophobicity refers to a surface state where the contact angle when water droplets fall is above 150°, while the contact angle during sliding motion is smaller than 10°. Superhydrophobic surfaces offer the advantage of water droplets not easily sliding off, maintaining a cleaner state as the droplets leave the surface. Surface modification involves two fundamental steps to achieve superhydrophobicity: surface roughness increase and surface energy reduction. However, existing methods, such as time-consuming processes and toxic organic precursors, still face challenges. In this study, we propose a method for superhydrophobic surface modification using lasers, aiming to create roughness in micro/nanostructures, ensuring durability while improving the production time and ease of fabrication. The mechanical durability of superhydrophobic samples treated with lasers is comparatively evaluated against chemical etching samples. The experimental results demonstrate superior mechanical durability through the laser treatment. Therefore, this research provides an effective and practical approach to superhydrophobic surface modification, highlighting the utility of laser treatment.