• Journal of the Korean earth science society
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• v.22 no.4
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• pp.278-291
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• 2001

Mesothermal gold vein minerals of the Seolhwa mine were deposited in a single stage of massive quartz veins which filled the mainly NE-trending fault shear zones exclusively in the granitoid of the Gyeonggi Massif. The Seolhwa mesothermal gold mineralization is spatially associated with the Jurassic granitoid of 161 Ma. The vein quartz contains three main types of fluid inclusions at 25$^{\circ}$C: 1) low-salinity (< 5 wt.% NaCl), liquid CO$_{2}$-bearing, type IV inclusion; 2) gas-rich (> 70 vol.%), aqueous type II inclusions; 3) aqueous type I inclusions (0${\sim}$15 wt.% NaCl) containing small amounts of CO$_{2}$. The H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl inclusions represent immiscible fluids trapped earlier along the solvurs curve at temperatures from 430$^{\circ}$ to 250$^{\circ}$C and pressures of 1 kbars. Detailed fluid inclusion chronologies may suggest a progressive decrease in pressure during the auriferous mineralization. The aqueous inclusion fluids represent either later fluids evelved through extensive fluid unmixing (CO$_{2}-CH$_{4}$ effervescence) from a homogeneous H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl fluid due to decreases in temperature and pressure, or the influence of deep circulated meteoric waters possibly related to uplift and unloading of the mineralizing suites. The initial fluids were homogeneous containing H$_{2}$O-CO$_{2}-CH$_{4}$-N$_{2}$-NaCl components and the following properties: the initital temperature of >250$^{\circ}$ to 430$^{\circ}$C, X$_{CO}\;_{2}$ of 0.16 to 0.62, 5 to 14 mole% CH$_{4}$, 0.06 to 0.3 mole% N$_{2}$ and salinities of 0.4 to 4.9 wt.% NaCl. The T-X data for the Seolhwa gold mine may suggest that the Seolhwa auriferous hydrothermal system has been probably originated from adjacent granitic melt which facilitated the CH$_{4}$ formation and resulted in a reduced fluid state evidenced by the predominance of pyrrhotite. The dominance of negative ${\delta}\;^{34}$S values of sulfides (-0.6 to 1.4$%_o$o) are consistent with their deep igneous source.

• Journal of the Korean Institute of Gas
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• v.27 no.3
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• pp.59-71
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• 2023

Carbon capture, and storage (CCS) is important for the reduction of greenhouse gases and achieving carbon neutrality. CCS focuses on storing captured CO₂ permanently in underground reservoirs. CO₂-enhanced oil recovery (CO₂-EOR) is one form of CCS, where CO₂ is injected into the underground to enhance oil recovery. CO₂-EOR not only aids in the extraction of residual oil but also contributes to carbon neutrality by storing CO₂ underground continuously. CO₂-EOR can be classified into miscible and immiscible methods, with the CO₂-water alternating gas (CO₂-WAG) technique being a representative approach within the miscible method. In CO₂-WAG, water and CO₂ are alternately injected into the reservoir, enabling oil production and CO₂ storage. The WAG method allows for controlling the breakthrough of injection fluids, providing advantages in oil recovery. It also induces hysteresis in relative permeability during the injection and production process, expanding the amount of trapped CO₂. In this study, the effects of enhancing oil recovery and storing CO₂ underground during CO₂-EOR were presented. Additionally, cases of CO₂-EOR application in relation to CCS were introduced.