• Title/Summary/Keyword: illite clay

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The Morphology, Physical and Chemical Characteristics of the Red-Yellow Soils in Korea (우리나라 전토양(田土壤)의 특성(特性) (저구릉(低丘陵), 산록(山麓) 및 대지(臺地)에 분포(分布)된 적황색토(赤黃色土)를 중심(中心)으로))

  • Shin, Yong Hwa
    • Korean Journal of Soil Science and Fertilizer
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    • v.6 no.1
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    • pp.35-52
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    • 1973
  • Red Yellow Soils occur very commonly in Korea and constitute the important upland soils of the country which are either presently being cultivated or are suitable for reclaiming and cultivating. These soils are distributed on rolling, moutain foot slopes, and terraces in the southern and western parts of the central districts of Korea, and are derived from granite, granite gneiss, old alluvium and locally from limestone and shale. This report is a summary of the morphology, physical and chemical characteristics of Red Yellow Soils. The data obtained from detailed soil surveys since 1964 are summarized as follows. 1. Red-Yellows Soils have an A, Bt, C profile. The A horizon is dark colored coarse loamy or fine loamy with the thin layer of organic matter. The B horizon is dominantly strong brown, reddish brown or yellowish red, clayey or fine loamy with clay cutans on the soil peds. The C horizon varies with parent materials, and is coarser texture and has a less developed structure than the Bt horizon. Soil depth, varied with relief and parent materials, is predominantly around 100cm. 2. In the physical characteristics, the clay content of surface soil is 18 to 35 percent, and of subsoil is 30 to 90 percent nearly two times higher than the surface soil. Bulk density is 1.2 to 1.3 in the surface soil and 1.3 to 1.5 in the subsoil. The range of 3-phase is mostly narrow with 45 to 50 percent in solid phase, 30 to 45 percent in liquid one, and 5 to 25 percent in gaseous state in the surface soil; and 50 to 60 solid, 35 to 45 percent liquid and less than 15 percent gaseous in the subsoil. Available soil moisture capacity ranges from 10 to 23 percent in the surface soil, and 5 to 16 percent in the subsoil. 3. Chemically, soil reaction is neutral to alkaline in soils derived from limestone or old fluviomarine deposits, and acid to strong acid in other ones. The organic matter content of surface soil varying considerably with vegetation, erosion and cultivation, ranges from 1.0 to 5.0 percent. The cation exchange capacity is 5 to 40 me/100gr soil and closely related to the content of organic matter, clay and silt. Base saturation is low, on the whole, due to the leaching of extractable cations, but is high in soils derived from limestone with high content of lime and magnesium. 4. Most of these soils mainly contain halloysite (a part of kaolin minerals), vermiculite (weathered mica), and illite, including small amount of chlorite, gibbsite, hematite, quartz and feldspar. 5. Characteristically they are similar to Red Yellow Podzolic Soils and a part of Reddish Brown Lateritic Soils of the United States, and Red Yellow Soils of Japan. According to USDA 7th Approximation, they can be classified as Udu Its or Udalfs, and in FAO classification system to Acrisols, Luvisols, and Nitosols.

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Changes in Provenance and Transport Process of Fine Sediments in Central South Sea Mud (남해중앙니질대 세립질 퇴적물의 기원지 및 이동과정 변화)

  • Lee, Hong Geum;Park, Won Young;Koo, Hyo Jin;Choi, Jae Yeong;Jang, Jeong Kyu;Cho, Hyen Goo
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.4
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    • pp.235-247
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    • 2019
  • The Central South Sea Mud (CSSM), developed in the Seomjin River estuary, is known to be supplied with sediments from Heuksan Mud Belt (HMB) and Seomjin River. However, in order to form a mud belt, more sediments must be supplied than supplied in the above areas. Therefore, research on additional sources should be conducted. In this study, clay minerals, major elements analyzes were performed on cores 16PCT-GC01 and 16PCT-GC03 in order to investigate the transition in the provenance and transport pathway of sediments in CSSM. The Huanghe sediments are characterized by higher smectite and the Changjiang sediments are characterized by higher illite. Korean river sediments contain more kaolinite and chlorite than those of chinese rivers. Korean river sediments have higher Al, Fe, K concentraion than Chinese river sediments and Chinese rivers have higher Ca, Mg, Na than those of Korean rivers. Therefore, clay minerals and major elements can be a useful indicator for provenance. Based on our results, CSSM can be divided into three sediment units. Unit 3, which corresponds to the lowstand stage, is interpreted that sediments from Huanghe were supplied to the study area by coastal or tidal currents. Unit 2, which corresponds to the transgressive stage, is interpreted to have a weaker Huanghe effect and a stronger Changjiang and Korean rivers effect. Unit 1, which corresponds to the highstand stage when the sea level is the same as present and current circulation system is formed, is interpreted that sediments from Changjiang and Korean rivers are supplied to the research area through the current.

The Uptake of $Sr^{90}$ by Paddy Rice from Soil and its Distribution in the Plant (답토양(畓土壤)에서 수도(水稻)의 Strontium-90 흡수(吸收)와 수도체내(水稻體內) 분포(分布))

  • Lim, Soo-Kil;Kim, Jae-Sung;Lee, Young-Il
    • Korean Journal of Environmental Agriculture
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    • v.5 no.1
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    • pp.48-54
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    • 1986
  • Because of the drastic development of nuclear industries, the contamination of natural environments by the disposal of radioactive materials which are released from nuclear facilities have aroused a considerable concern in relation to agricultural practices. Therefore the present investigation, through pot experiment, was performed to find out the aspect of the uptake of $Sr^{90}$ by rice plants and its distribution in them in five different types(physicochemical and minerallogical properties) of paddy soils. The results obtained were as follows; 1) Visual toxic symptoms on the growth of rice plant due to treatment of $Sr^{90}$ up to $40{\mu}Ci/10㎏$ in a pot were not observed even though uptake of $Sr^{90}$ by rice plant was proportionally increased with the $Sr^{90}$ treatment. 2) Distribution of $Sr^{90}$ in the rice plant was the highest in the leaves (84.5%) followed in the order by stems (13.5%) and rough grain (2.0%). The ratio of $Sr^{90}$ to Ca was higher in the leaves (872) and stems (667) than in the rice grain (89). 3) $Sr^{90}$ absorption in the rice plant ranged $0.15{\sim}0.30%$ at harvesting time. Uptake of $Sr^{90}$ by rice plants decreased by the increase of soil pH and exchangeable canons in the soils, but $Sr^{90}$ uptake increased when nitrogen, organic matter and clay content in soil was high, and uptake of this nuclide in the rice plant was higher with low Illite and Vermiculite content in the soils.

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A Scientific Study of Roof Tiles in Joseon Dynasty from Dongdaemoon Stadium (동대문운동장유적 출토 조선시대 기와의 특성 연구)

  • Chung, Kwang-Yong
    • Korean Journal of Heritage: History & Science
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    • v.45 no.3
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    • pp.160-173
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    • 2012
  • Roofing tile research conducted in Korea so far is mostly related to studies on roofing tile patterns excavation report on the roof tile klin site in the aspects of archeology architecture and history of art. There have been continuous studies on kiln ground and manufacture techniques of roofing tiles. However it is difficult to find roofing tiles research based on scientific experiments. The research on this paper performs physical and chemical experimental study to understand order, manufacturing techniques and other characteristics of Chosun Dynasty roofing tiles excavated in Dongdaemun stadium. As for physical experimental study water absorption, specific gravity, whole-rock Magnetic susceptibility rate and Differential Thermal Analysis are conducted. As for chemical experimental study, neutron activation analysis(NAA), microstructure observation, X-ray diffractometry(XRD) analysis are conducted. Result of neutron activation analysis and statistical analysis on piece of roof tile 22 samples clearly show that the roofing tile samples are from different time line and places. It also shows different composition when compare average value of rare earth resources per findspots. It means roofing tiles were manufactured from clay mineral from several places. Close inspection using XRD and polarization microscope reveals that main components of roofing tiles are quartz and felspar. Mica and Illite are found partially. XRD analysis shows mullite mineral composition which occurs when roofing tile is calcined around $1000^{\circ}C$. Differential thermal analysis shows gradual exothermic peak near $900^{\circ}C$. Based on these results, it is assumed that roofing tile is made at $900{\sim}1000^{\circ}C$. result of XRD analysis shows mullite were made near $1000^{\circ}C$. in Differential Thermal Analysis shows gradual exothermic peak near $900^{\circ}C$. this results shows that roof tiles were made near 900~1000 near $1000^{\circ}C$ mean value of whole-rock Magnetic susceptibility rate. When performed comparative analysis using whole-rock Magnetic susceptibility rate average value, findspots provided no certain classification to arrange. Nonetheless low whole-rock Magnetic susceptibility rate 0.2~0.78(${\times}103$ SI unit) is found when roofing tile patterns are Pasangmun, Taesangmun, Eosangmun, Kyukjamun, Heongsunmun. Overall absorptivity is 14~21%. It is similar to 14~18% of roofing tile from Chosun Dynasty. There is only 1.4~2.5g/cm3 of roof tile sample specific gravity. The analysis finds no difference in specific gravity by findspots.

Hydrogeochemistry and Contamination of Meteoric Water at the Narim Mine Creek, Korea (나림광산 수계에 분포하는 순환수의 수문지구화학 및 오염)

  • 이찬희
    • Economic and Environmental Geology
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    • v.32 no.4
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    • pp.385-398
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    • 1999
  • The Narim gold mine is located approimately 200km southeast of Seoul within the Muju mineralized district of the Sobaegsan gneiss complex, Korea. Environmental geochemistry were undertaken for various kinds of water (surface, ground and mine water) collected of April, September and November in 1998 from the narim mine creek. Hydrogeochemical compositions of water samples are characterized by the relatively significant enrichment of Na+K, alkali ions, $HCO_{3}$, $NO_{3}$, Cl and F in groundwater, wheras the mine and surface waters are relatively enriched in Ca+Mg, hea표 metals and $SO_{4}$. Therefore, the groundwaters belong to the (Na+Ca)-( $HCO_{3}+SO_{4}$) type, respectively. The pH and EC values of the non-mining creek surfers are relatively lower compared with those of the surface water of the mine and ore dump area. The d values ($\delta$D-8$\delta^{18}$O) of all kinds of water from the Narim mine creek are 5.8 to 13.1 The range of $\delta$D and $\delta^{18}$O values (relative to SMOW) are shown in distinct two groups as follows: for the April waters of -64.8 to -67.8$\textperthousand$ and -9.6 to -10.0$\textperthousand$(d value=10.1 to 13.1), and for the November waters of -65.9 to -70.2$\textperthousand$ and -9.3 to -9.6$\textperthousand$ (d value=5.8 to 7.9), respectively. This range variation indicates that two group water were composed of distinct waters with seasonal difference. Geochemical modeling showed that mostly toxic metals (As, Fe, Mn, Ni, Pb, Zn) may exist largery in the from of metal $(M2^+)$ and metal-sulfate $(MSO_4\;^{2-$\mid$),\; and \;SO_4^{2-$\mid$}$ concentration influenced the speciation of heavy metals in the meteoric water. These metals in the groundwater could be formed of $CO_3 \;and \;(OH)_3$ complex ions. Using computer program, saturation index of albite, calcite, dolomite in meteoric water show undersaturated and progreddively evolved toward the saturation state, however, ground and mine water are nearly saturated. The gibbsited water-mineral reaction and stabilities suggest that the weathering of silicate minerals may be stable kaolinite, illite and Nasmectite. The clay minerals will be transformed to more stable kaolinite owing to the contiunous reaction.

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A Study on the sedimentological Environments in KODOS91-1 Area, Northeast Pacific (북동 태평양 KODOS91-1지역퇴적환경 연구)

  • 박정기;김기현
    • 한국해양학회지
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    • v.29 no.1
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    • pp.17-27
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    • 1994
  • The sediment collected from KODOS91-1 were studied using X-ray diffraction(SRD) analysis to clarify the composition and vertical distribution of clay minerals. Micropaleontological data(Radiolarians) was applied to identify the changes in post-depositional environment and chemical mechanism leading to the formation of authigenic minerals. The result show that the highest concentration of smectite is occurred in the lower part(Unit II, III) of sediment column and the lowest concentration in the upper part(Unit I) whereas terrestrial minerals, such as illite, kaolinite and quartz, indicate the opposite trends. Radiolarians in the upper part are composed entirely of Quaternary/Tertiary mixtures, whereas in lower sediment units generally revealed the middle Miocene to the Eocene. This may imply that the Quaternary and Tertiary sedimentary processes were continuously affected by reworking of older sediments and subsequent resegmentation. The changes of the sediment color, peak pattern of minerals and presence of reworked microfossils at the unit boundaries have been interpreted as evidence of authigenic formation. Mineralogical characteristics of the sediments in study area strongly indicates changes in paleoenvironments through geologic time, including changes in post-depositional conditions by physical processes and chemical mechanisms.

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Petrological Characteristics and Deterioration Aspect of the Pohang Chilpori and Shinheungri Petroglyphs (포항 칠포리 I지구와 신흥리 암각화의 암석학적 특징과 훼손양상 분석)

  • Lee, Sang-Hun;Choi, Gi-Ju
    • Journal of Conservation Science
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    • v.25 no.4
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    • pp.347-361
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    • 2009
  • The Pohang Chilpori is the area with abundant petroglyphs in Korea. The form of the shield, female sex organs, and yut board on the outcrops or float rocks which are composed of the rhyolitic rock are engraved on Chilpori and Shinheungri Petroglyphs. The rhyolitic rock is composed of the phenocryst and groundmass with quartz and feldspar. The rock surface shows mostly yellowish brown color and the rock surface is very irregular by serious weathering, and illite and kaolinite, a kind of the clay minerals, are produced. Deterioration aspects are mainly of surface exfoliation, grain peel-off, damages, scribbling. Chilpori Petroglyph (1) plane has been eroded by running water, in (2) plane has been abrased is on the rock surface, in (3) plane shows surface exfoliation and the various part of the rock surface in plane (4) has become the soil. The corrasion and black phenomenon of the Shinheungri Petroglyph (1) plane was formed by running water, and surface exfoliation and scribbling in plane (2) is serious. Deterioration factors are geomorphologic states, plants, rock of weak to weathering, and artificial influence such as a scribbling and a forest fire. For conservation of the these petroglyphs, study for rock surface conservation and the arrangement of around petroglyphs and construction of water wall are necessary.

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Mineral Composition of the Tamna Formation, Jeju Island (제주도 탐라층의 구성광물)

  • Hyun, Weonhak;Hwang, Jinyeon;Lee, Jinhyun;Son, Byeongseo;Oh, Jiho;Yang, Kyounghee;Kim, Kwanghee
    • The Journal of the Petrological Society of Korea
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    • v.25 no.4
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    • pp.335-348
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    • 2016
  • The fluvial Tamna Formation, consisting of conglomerate, sandstone and mudstone layers, is widely distributed in Jeiu Island. Various sizes of quartz crystals were identified from most of the Tamna Formation, including the mudstone layer. XRD analysis also shows that the mudstone layer is composed of various minerals, quartz, plagioclase, K-feldspar, mica, magnetite, hematite, olivine, amphibole, gibbsite, calcite, analcime and clay minerals such as illite, kaolinite, vermiculite, smectite, chlorite, $10{\AA}$-halloysite. There is a tendency showing that the more amount of kaolinite, vermiculite, and chlorite is present where the more amount of quartz crystals is present. It is likely that the main source materials contributing to the Tamna Formation were from the parental rocks containing abundant quartz grains, suggesting that the Tamna Formation could not be related to Jeju volcanic rocks, but possibly to pre-existing basement rocks. Thus, we propose that the Tamna Formation was formed from the materials derived from both pre-existing basement rocks and Jeju volcanic rocks, which were subsequently affected by diagenesis, hydrothermal alteration and weathering process.

Spectral Characteristics associated with Heavy Metal Concentration and Mineral Composition in Cropland and Rice Field Soils from Downstream of an Abandoned Coal Mine (폐석탄광 하류 밭토양 및 논토양의 중금속 함량과 광물조성에 따른 분광학적 특성)

  • Seo, Jihee;Yu, Jaehyung;Koh, Sang-Mo;Lee, Bum Han
    • Economic and Environmental Geology
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    • v.53 no.6
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    • pp.743-753
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    • 2020
  • This study analyzed heavy metal concentration, mineral composition, and spectral characteristics of heavy metal contaminated soil samples of cropland and rice field located in downstream of abandoned Okdong coal mine. X-ray fluorescence analysis detected heavy metal elements including cadmium, copper, arsenic, lead, zinc and nickel in the soils. Both cropland and rice field samples were severely contaminated with arsenic showing higher concentration over the concerned standard. The pollution index of cropland samples was higher than that of rice field samples. X-ray powder diffraction analysis identified that the mineral composition of cropland and rice field samples is similar with quartz, calcite, kaolinite, illite, smectite, magnetite and hematite. The range of organic matter content were more widely distributed in cropland samples. The spectral analysis showed that the reflectance spectra and the absorption features of cropland and rice field samples were alike. The absorption features that appeared near 490nm and 900nm were attributed to the ferric iron, and clay minerals such as kaolinite and smectite caused the absorption features at 1410nm, 1910nm and 2200nm. The reflectance of the soil spectral decreased with an increase in organic content. The absorption depths of both types of soil samples decreased with higher organic matter content at 490nm and 1916nm as well as higher heavy metal concentration.

Mineralogy and Geochemistry of Shale Deposits in the Lower Anambra Basin, Nigeria: Implication for Provenance, Tectonic Setting and Depositional Environment

  • Olugbenga Okunlola;Agonsi Udodirim Lydia;Aliyu Ohiani Umaru;Raymond Webrah Kazapoe;Olusegun G. Olisa
    • Economic and Environmental Geology
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    • v.56 no.6
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    • pp.799-816
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    • 2023
  • Mineralogical and geochemical studies of shales within the Lower Anambra Basin was conducted to unravel the depositional environment, provenance, maturity, paleo-weathering conditions, and tectonic settings. Mineralogical studies conducted using X-ray diffraction analysis revealed that the samples were composed of kaolinite, montmorillonite, chlorite, and illite. KaolinIite is the dominant mineral, constituting approximately 41.5% of the bulk composition, whereas the non-clay minerals are quartz, ilmenite, and sillimanite. Geochemical analysis showed a predominance of SiO2, Al2O3, and Fe2O3 contents of the shale samples with mean values of 52.29%, 14.09%, and 6.15% for Imo Shale (IS); 52.31%, 16.70%, and 7.39% for Mamu Shale (MS); 43.21%, 21.33%, and 10.36% for Enugu Shale (ES); 53.35%, 15.64%, and 7.17% for Nkporo Shale (NS); and 51.24%, 17.25%, and 7.78% for Agwu Shale (AS). However, the shales were depleted in Na2O, MgO, K2O, MnO, TiO2, CaO, and P2O5. The trace element ratios of Ni/Co and Cu/Zn of the shale suggest an oxic depositional environment. The average SiO2 vs. Al2O3 ratio of the shales indicated textural maturity. Compared to the PAAS standard, the shales plot below the PAAS value of 0.85, suggesting a high degree of maturity and intensive chemical weathering, further confirmed on a CIA vs. PIA plot. On log (K2O/Na2O) against SiO2 and tectonic setting discriminant function diagrams, the shales plot mostly in the field of passive continental margin tectonic setting. The discriminant function diagrams as well as Al2O3/TiO2 ratio of the shales showed that they were derived from a mixed source (mafic and intermediate igneous rocks).