• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.386-386
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• 2011

sol-gel 및 hydrothermal growth method를 이용한 zinc oxide nanorod는 제작 시 고가의 장비가 필요치 않기에 저비용 대면적 박막을 제작하는데 적합하지만 rod들의 array 및 density 조절에서 어려움을 가지고 있다. 본 연구에서는 이러한 nanorod array 형상 조절을 위하여 zinc oxide seed layer 형성 과정 중 precursor solution에 이종 나노 입자를 첨가하였다. 첨가한 seed precursor solution을 spin coating한 이후에 후처리 하여 hydrothermal method를 이용해 성장시켰다. 합성한 rod들을 optic과 FE-SEM으로 측정해 rod들의 density 변화를 확인할 수 있었다.

• Journal of the Korean Ceramic Society
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• v.18 no.3
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• pp.147-151
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• 1981

On the calcium silicate hydrothermal reaction, the effect of NaOH and KOH Studied. Forincreasing the yield of fibers and to promote crystal growth, Rotary autoclae has been used. By addition NaOH solution, approximately 150${\mu}{\textrm}{m}$ of pectolite was grown. By addition KOH solution, approximately 30${\mu}{\textrm}{m}$ of 11$\AA$-Tobermorite was grown under the conditon of 21$0^{\circ}C$ 10 days reaction. These results indicate that 11$\AA$-Tobermorite was stabilized by KOH over a wide Temperature and composition range.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2006.09a
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• pp.167-168
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• 2006

A hyrdrothermal synthesis has been developd to prepare rod-like crystals of copper oxide using copper nitrate trihydrate as a function of synthesis temperature, stirring speed and solution pH value. The properties of the fabricated crystals were studied using scanning electron microscopy, X-ray diffraction and particle size analysis. The morphology of the synthesized CuO was dependent on both the pH value of the solution and the morphology of the seed materials. Synthesized particles have regular morphologies and a uniform size distribution.

• Journal of Environmental Health Sciences
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• v.33 no.4
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• pp.317-324
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• 2007

The sewage treatment sludge disposal has become a serious environmental problem because of restricted direct land-filling and oceandumping in spite of their large amounts discharged. So the recycling of sewage treatment sludge is very useful alternative for waste management. Here, we studied the feasibility of zeolite synthesis in open system from the sewage treatment sludge incinerator fly ash by means of hydrothermal synthesis. We considered the concentration of NaOH, reaction time, reaction temperature and reaction step as synthesis variables. The phase of zeolite products was identified by X-ray diffractometer(XRD) and ammonium ion exchange test was performed for the raw fly ash and two zeolite products(Z-3 and Z-5). In leaching test of the raw fly ash, hazard metal is detected very low level compared with regulatory leaching test standard. But in total recoverable test, the total contents of the fly ash were very high in terms of the standard for waste-derived fertilizer. Through hydrothermal reaction, small amount of zeolite P was synthesied in 1 N of NaOH solution and relatively large amount of hydroxysodalite was synthesied in 3 N and 5 N of NaOH solution with similar peak intensity. Addition of an aging step in the synthesis didn't increase the amount of zeolite phase. Maximum $NE_4^+-N$ exchange capacity is 1.49 mg $NH_4^+-N/g$ in Z-3 and 1.38 mg $NH_4^+-N/g$ in Z-5. Most of the ammonium ion is exchanged in 30 minutes and disorption did not occur until 5 hours.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.2
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• pp.129-140
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• 1996

In this study, we have prepared corundum ($\alpha$-Al_{2}O_{3}$) single crystals from aluminum hydroxides by hydrothermal growing process and have investigated the reaction conditions. The hydrothermal conditions were mainly affected by reaction temperature, seed crystal and reaction time. Especially, seed crystal has strong effects on the particle size and crystallity of products. By adding seed crystal in Japanese gibbsite solution as the nutrient, hydrothermal reaction was performed for 2 hours at the reaction temperature of $460^{\circ}C$, to produce corundum powders which had weight mean particle diameter of $11\;\mu\textrm{m}$ with hexagonal crystal, Without adding seed crystal in Russian gibbstite solution, corundum powders that have weight mean particle diameter of $6\;\mu\textrm{m}$ with hexagonal crystals were also formed after 2 hours operation at the reaction temperature of $420^{\circ}C$.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.3
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• pp.126-132
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• 2002

The nanocrystalline zirconia powder with anisotropic shapes was synthesized by hydrothermal treatment of the tetragonal zirconia prepared by aging the zirconium hydroxide precipitate, which was obtained from the reaction between $ZrOCl_2{\cdot}8H_2O$ and KOH solutions under the fixed pH of 13.5, at $100^{\circ}C$ for 24 h. With increasing the hydrothermal reaction temperature and time, the fraction of tetragonal phase with spherical zirconia decreased, whereas, relatively the fraction of monoclinic phase with spindle-like and rod shape zirconia increased. As increased concentration of the NaOH solution it promoted the particle size to become larger and the crystalline phase to transform tetragonal to monoclinic. However, the specific surface area at the early stage of the reaction increased and subsequently decreased because of grain growth in powder with longer reaction time.

• Korean Journal of Materials Research
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• v.26 no.7
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• pp.393-399
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• 2016

Flower-like nickel oxide (NiO) catalysts were coated on NiCrAl alloy foam using a hydrothermal method. The structural, morphological, and chemical bonding properties of the NiO catalysts coated on the NiCrAl alloy foam were investigated by field-emission scanning electron microscopy, scanning electron microscopy-energy dispersive spectroscopy, X-ray diffraction, and X-ray photoelectron spectroscopy, respectively. To obtain flower-like morphology of NiO catalysts on the NiCrAl alloy foam, we prepared three different levels of pH of the hydrothermal solution: pH-7.0, pH-10.0, and pH-11.5. The NiO morphology of the pH-7.0 and pH-10.0 samples exhibited a large size plate owing to the slow reaction of the hydroxide ($OH^-$) and nickel ions ($Ni^+$) in lower pH than pH-11.5. Flower-like NiO catalysts (${\sim}4.7{\mu}m-6.6{\mu}m$) were formed owing to the fast reaction of $OH^-$ and $Ni^{2+}$ by increased $OH^-$ concentration at high pH. Thus, the flower-like morphology of NiO catalysts on NiCrAl alloy foam depends strongly on the pH of the hydrothermal solution.

• Structural Engineering and Mechanics
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• v.24 no.4
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• pp.395-410
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• 2006

This paper reports the result of an investigation into wave propagation in orthotropic laminated piezoelectric cylindrical shells in hydrothermal environment. A dynamic model of laminated piezoelectric cylindrical shell is derived based on Cooper-Naghdi shell theory considering the effects of transverse shear and rotary inertia. The wave characteristics curves are obtained by solving an eigenvalue problem. The effects of layer numbers, thickness of piezoelectric layers, thermal loads and humid loads on the wave characteristics curves are discussed through numerical results. The solving method presented in the paper is validated by the solution of a classical elastic shell non-containing the effects of transverse shear and rotary inertia. The new features of the wave propagation in laminated piezoelectric cylindrical shells with various laminated material, layer numbers and thickness in hydrothermal environment and some meaningful and interesting results in this paper are helpful for the application and the design of the ultrasonic inspection techniques and structural health monitoring.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.2
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• pp.254-262
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• 1996

$Pb(Zr_{0.52}Ti_{0.48})O_{3}$ (PZT) ceramics were prepared with uniform particle size of $1~3\;\mu\textrm{m}$ by hydrothermal synthesis at various conditions, such as hydrothermal reaction temperature, concentration of mineralizer and reaction time. PZT ceramics were formed above $180^{\circ}C$ for 2 hrs reaction using 10 M KOH solution as a mineralizer, but reaction condition was slightly different by starting materials. Morphology and characterization of PZT powders were investigated by XRD and SEM. By increasing the reaction temperature, KOH concentration and reaction time, the composition of the PZT phase tended to be homogeneous phase.

• Journal of the Korean Ceramic Society
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• v.42 no.11 s.282
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• pp.743-748
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• 2005

The effect of reaction parameters in the characteristic of $Pb(Zr_{0.52} Ti_{0.48})O_3$ powders by hydrothermal process was investigated in this study. In the preparation of PZT, the types of starting material and concentration of mineralizer on phase fraction and morphology was investigated respectively. Regardless the types of Pb precursor, PZT was able to synthesize ranging from 7 to 20 on KOH concentration and from 13.01 to 13.55 on pH of solution. The particle size of the PZT powders can be controlled by the mineralizer concentration and various types of precursor.