• Title/Summary/Keyword: hydrothermal reduction

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Electrochemical hydrothermal treatment on Pure Titanium by the method of Cathodic reduction (음극환원법에 의한 Pure Ti의 전기화학적 열수처리)

  • Song, Jae-Joo;Kim, Kyeong-Seon
    • Journal of Korean society of Dental Hygiene
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    • v.7 no.4
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    • pp.471-479
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    • 2007
  • The purpose of this study was to examine the optimum condition of impulse during the anodic spark oxidation applying pulse current as well as to find the excellent condition for HA precipitation the after electrochemical hydrothermal treatment by cathode reduction method. After anodic spark oxidation, the anodized specimen and the Pt plate connected cathode and anode, respectively. Hydrothermal treatment performed at 90, 120, $150^{\circ}C$ for 2 hours in the electrolyte containing $K_2HPO_4$, $CaCl_2{\cdot}2H_2O$, Tris(Hydroxymethyl)-$(CH_2OH)_3\;CNH_2$(Aminomethane), and NaCl. The optimum impulse voltage for anodic spark oxidation was 350V. The optimum pulse cycle measured at 10 mS. The HA crystals precipitated excellently by cathode reduction at $150^{\circ}C$ for 2 hours. The phases of anatase, rutile, and HA coating on the surface of modified titanium surface immersed in Hanks' solution for 3weeks were detected by XRD measurement and the intensity of HA crystal phase has increased by temperature and time of hydrothermal treatment. According to the our experiments, we found that Pure Ti will be good materials of bioactivity and biocompatibility.

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Comparison of CTD Cast and CTD Tow-yo Methods for Detecting Hydrothermal Plume (열수 플룸 검출을 위한 CTD Cast와 CTD Tow-yo 방법 비교)

  • Son, Juwon;Joo, Jongmin;Ham, Dong Jin;Yang, Seungjin;Kim, Jonguk
    • Ocean and Polar Research
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    • v.36 no.2
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    • pp.179-187
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    • 2014
  • Directly searching for undiscovered hydrothermal vent sites is inefficient due to the practical difficulty of comprehensively imaging vent fields. Thus, most searches for hydrothermal vent sites rely on the detection of hydrothermal plumes from water column observation. Detecting and measuring the hydrothermal plumes are the most efficient way to infer the presence and distribution of hydrothermal vents. Both the array of vertical casting and lateral towing are the most common methods to discover hydrothermal plumes. In this study, we compared results of cast and tow-yo operations along the same section of a spreading center with a distance of 20.5 km in the North Fiji Basin for mapping hydrothermal plumes. Operation of CTD tow-yo provides a detailed pattern of plumes which enable us to locate the hydrothermal vents. On the other hand, identification of hydrothermal activity can be determined effectively by CTD cast with additional analysis of geochemical tracers. Reduction in the operating time is another advantage of CTD cast operation, especially for regional-scale survey. Our results show that the combination of CTD cast and tow-yo would improve the efficiency of the hydrothermal plume survey to locate new hydrothermal vent sites.

A Study on Analysis of Domestic Energy Consumption and Reduction Greenhouse Gas in Building (에너지 소비분석과 건축분야에서의 온실가스 저감 방안)

  • Park, Jong-Il;Park, Ryul
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.8 no.1
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    • pp.1-6
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    • 2012
  • This study aims to analysis domestic energy consumption in Korea and reduction greenhouse gas by building mechanical system. At this point be tormented the energy depletion and climate change of earth are big problems on the eatrh. In this paper we will find out best methods to reduction greenhouse gas and energy consumption by practical building mechanical system. Enlargement of greenhome and building adopt, greenhouse gas exhaust reduction in building, publication of energy consumption rate, publish building energy management manual, etc.

Conversion of organic residue from solid-state anaerobic digestion of livestock waste to produce the solid fuel through hydrothermal carbonization

  • Yang, Seung Kyu;Kim, Daegi;Han, Seong Kuk;Kim, Ho;Park, Seyong
    • Environmental Engineering Research
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    • v.23 no.4
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    • pp.456-461
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    • 2018
  • The solid-state anaerobic digestion (SS-AD) has promoted the development and application for biogas production from biomass which operate a high solid content feedstock, as higher than 15% of total solids. However, the digested byproduct of SS-AD can be used as a fertilizer or as solid fuel, but it has serious problems: high moisture content and poor dewaterability. The organic residue from SS-AD has to be improved to address these problems and to make it a useful alternative energy source. Hydrothermal carbonization was investigated for conversion of the organic residue from the SS-AD of livestock waste to solid fuels. The effects of hydrothermal carbonization were evaluated by varying the reaction temperatures within the range of $180-240^{\circ}C$. Hydrothermal carbonization increased the calorific value through the reduction of the hydrogen and oxygen contents of the solid fuel, in addition to its drying performance. Therefore, after the hydrothermal carbonization, the H/C and O/C atomic ratios decreased through the chemical conversion. Thermogravimatric analysis provided the changed combustion characteristics due to the improvement of the fuel properties. As a result, the hydrothermal carbonization process can be said to be an advantageous technology in terms of improving the properties of organic waste as a solid-recovered fuel product.

A study on the synthesis of tin oxide crystalline by the liquid reduction precipitation method and hydrothermal process (액상환원침전법 및 수열반응법을 이용한 주석산화물 결정 합성에 관한 연구)

  • Park, Il-Jeong;Kim, Geon-Hong;Kim, Dae-Weon;Choi, Hee-Lack;Jung, Hang-Chul
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.26 no.3
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    • pp.95-100
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    • 2016
  • In this work, tin oxides were obtained by the liquid reduction precipitation method and hydrothermal process using $SnCl_2{\cdot}2H_2O$, $N_2H_4$, and NaOH. Tin oxide crystals having different sizes and morphologies could be achieved. The powders were characterized by X-ray diffraction (XRD) and Field Emission Scanning Electron Microscopy (FE-SEM). Depending on the molar ratio of the raw materials, tin oxide crystalline with the spherical and rectangular plate-like shape could be obtained, the crystal phase was SnO and $Sn_6O_4(OH)_4$. And the obtained SnO crystals by a hydrothermal reaction showed various shapes, such as, spherical, plate-like and flower-like architectures depending on the temperature conditions.

An Experimental Study on the Ground Source Heat Pump System for Heating Economic Efficiency and Reduction Amount of $CO_2$ (지열 시스템의 난방 경제성 및 $CO_2$ 절감 실증 연구)

  • Nam, Leem-Woo;Paek, Gi-Dong
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.3 no.2
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    • pp.25-30
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    • 2007
  • The final energy consumption in the building sector in Korea represents almost 20% of the total energy consumption. Besides, Space heating and hot water generation in Korea are based on fossil fuels, with a serious environmental impact. This study describes thermal performance of heating demonstration system using close-loop ground source heat pump installed at Korean minjok leadership academy. The results of the experimental study, it retrieve the investment cost for 3years 8months and reduction amount of $CO_2$are 293,900 $kgCO_2$.

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Preparation of Fine Co Powder from Co(OH)2 Slurry by Hydrothermal Reduction with Hydrogen

  • Kening Yu;Kim, Dong J.;Hun S. Chung
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06b
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    • pp.87-107
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    • 1996
  • The fine Co powder with an average particle sie of less than 1$\mu\textrm{m}$ was prepared by hydrothermal reduction with hydrogen from Co(OH)2 slurry obtained by mixing the solutons of CoSO4$.$7H2O and NaOH. A method to control pH of the end solution around neutrality was proposed. The reduction rate was found to be a function of pH, temperature, hydrogen pressure and the amount of catalyst.

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Photo-catalytic Properties of Nanotubes Synthesized using TiO2 Nanoparticles

  • Kim, Hyun;Kim, Dong Yun;Yang, Bee Lyong
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.239-243
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    • 2018
  • Up to now, microstructure changes of photocatalysts have been studied to improve photocatalytic activity. Especially, to improve the adsorption of reactants and reactive sites, porous and fine crystal structures have received much attention because of their large specific surface area. In this study, $TiO_2$ nanotubes were synthesized by hydrothermal method using $TiO_2$ nanoparticles; nanotubes were evaluated by oxidized methylene blue reduction test. Using synthesized $TiO_2$ nanotubes, results of TEM showed that the $TiO_2$ nanoparticles were changed into folding sheets and nanotubes. XRD results showed that the peaks of the nanoparticles almost disappeared and only the rutile (110) and anatase (200) peaks were observed. Comparison of photocatalytic properties of nanoparticles and nanotube structures was performed by measuring the UV-vis absorbance with reducing oxidized methylene blue. As a result, the reduction rate of nanotubes was found to be $0.24{\mu}mol/s$, which was 2.6 times higher than the rate of reduction of nanoparticles.

Hydrothermal Reduction of $\Co(OH)_2$ to Cobalt Powder Preparation ($Co(OH)_2$로부터 수열법에 의한 코발트 분말제조)

  • Kim, Dong-Jin;Chung, Hun-Saeng;Yu Kening
    • Korean Journal of Materials Research
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    • v.9 no.7
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    • pp.675-679
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    • 1999
  • An investigation was performed to prepare spherical cobalt powder with about particle size of 400nm from aqueous cobalt hydroxide slurry under hydrothermal reduction conditions using palladium chloride as a catalyst. The reduction kinetics was in good agreement with a surface reaction core model equation. and the activation energy obtained from Arrhenius plots was 55.6 KJ/mol at the temperature range of $145~195^{\circ}C$. Additionally, the study showed that the cobalt reduction rate is proportional to the initial hydrogen pressure with a reaction order of n=0.63. which corresponds to the gas chemisorption reaction type.

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