• Title/Summary/Keyword: hydrophilic surface

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A Study on the Fabrication of Fe-Co Magnetic Fluid from the Waste Pickling Liquor of Steel

  • Kim, Young-Sam;Lee, Jong-Heon
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.149-153
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    • 2001
  • This paper describes on the fabrication of Fe-Co hydrophilic magnetic fluids from the waste pickling liquor of steel. By adding with HNO$_3$in the waste liquor oxidation is proceeded from Fe$^{3+}$ion at 6$0^{\circ}C$ with air blowing. Ultra-fine Co-ferrite particles with the mean particle size of 50 $\AA$ were produced at pH 12 after adjusting the ratio of Fe$^{3+}$Co$^{2+}$=7/3(wt%) and Fe-Co particles with the mean particle size of 94 $\AA$ were produced by reducing the Co-ferrite particle with H$_2$at the temperature of 50$0^{\circ}C$. After triple adsorption of oleic acid dodecyl benzene sulfonate(D.B.S.) and tetra methyl ammonium(T.M.A.) ions on the surface of Fe-Co particles Fe-Co hydrophilic magnetic fluid was produced by dispersing the Fe-Co particles in ethylene glycol solution. The magnetization of the Fe-Co hydrophilic magnetic fluid increased with increasing the Fe-Co concentration. The magnetic fluid containing 70% (g/cc) Fe-Co showed 73 emu/g in magnetization at the magnetic intensity of 10 kOe.kOe.e.

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Comparative Study on Ejection Phenomena of Droplets from EHD Jet by Hydrophobic Coating of Nozzle (노즐의 소수성 코팅에 의한 EHD 제트의 액적 토출 현상 비교 연구)

  • Kim, Yong-Jae;Choi, Jae-Yong;Son, Sang-Uk;Ahn, Ki-Cheol;Keum, Hyun-Joon;Lee, Suk-Han;Byun, Do-Young;Ko, Han-Seo
    • Proceedings of the KSME Conference
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    • 2008.11a
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    • pp.1742-1746
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    • 2008
  • An EHD (Electro-Hydro-Dynamic) jet for electrostatic inkjet head shows advantages to print micro-size patterns using various inks because it can generate sub-micron droplets and can use highly viscous inks. Thus, many researchers in industrial fields are concerned about the EHD jet in these days. Since the basic principle of the EHD jet is to form a droplet from an apex of meniscus at the end of the nozzle, the ejection mechanism can be changed by the shape of the meniscus. The stable ejection of the droplet is greatly affected by the shape of the meniscus which is also influenced by surface characteristics of the nozzle, electric potential and ink properties. Experiments have been performed using the nozzles with hydrophilic and hydrophobic coatings in this study. The hydrophobic nozzle forms the stable droplets in wider range of the electric potential than the hydrophilic nozzle does.

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Carbonation and Cl Penetration Resistance of Alkali Silicate Impregnant of Concrete (Silicate계 콘크리트 침투성 함침제의 탄산화 및 염해 저항성)

  • Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Journal of the Korean Ceramic Society
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    • v.45 no.11
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    • pp.719-724
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    • 2008
  • Every concrete structure should continue to perform its intended functions such as to maintain the required strength and durability during its lifetime. Deterioration of the concrete structure, however, occurs more progressively from the outside of the concrete exposed to severe conditions. Main deteriorations in concrete structures result from carbonation, chloride ion attack and frost attack. Concrete can therefore be more durable by applying surface protection to increase its durability using impregnants, which are normally classified into two large groups in polymeric and silicate materials. Concrete impregnants are composed of silanes and alkali silicates (sodium, potassium and lithium silicate). Thus, this study is concerned with elevating the carbonation and Cl- penetration resistance of concrete structures by applying alkali silicate hydrophilic impregnants including lithium and potassium silicates. From the experimental test results, lithium and potassium silicates produced a good improvement in carbonation resistance and are expected to be used as hydrophilic impregnants of concrete structures.

Semi-Permanent Hydrophilization of Polyester Textile by Polymerization and Oxidation Using Atmospheric Pressure Dielectric Barrier Discharge (APDBD)

  • Se Hoon Shin;Yoon Kee Kim
    • Korean Journal of Materials Research
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    • v.33 no.4
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    • pp.115-123
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    • 2023
  • In this paper, we report and discuss the semi-permanently hydrophilic (SPH) treatment of polyester fabric using plasma polymerization and oxidation based on atmospheric pressure dielectric barrier discharge (APDBD) technology. SiOxCy(-H) was coated on polyester fabric using Hexamethylcyclotrisiloxane (HMCTSO) as a precursor, and then plasma oxidation was performed to change the upper layer of the thin film to SiO2-like. The degradation of hydrophilicity of the SPH polyester fabrics was evaluated by water contact angle (WCA) and wicking time after repeated washing. The surface morphology of the coated yarns was observed with scanning electron microscopy, and the presence of the coating layer was confirmed by measuring the Si peak using energy dispersive x-ray spectroscopy. The WCA of the SPH polyester fabric increased to 50 degrees after 30 washes, but it was still hydrophilic compared to the untreated fabric. The decrease in hydrophilicity of the SPH fabric was due to peeling of the SiOxCy(-H) thin film coated on polyester yarns.

Properties Characterization of the Hydrophilic Inorganic Film as Function of Coating Thickness (코팅 두께에 따른 친수성 무기 필름의 특성 분석)

  • Joung, Yeunho;Choi, Won Seok;Shin, Yongtak;Lee, Minji;Kim, Heekon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.425-428
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    • 2013
  • In this paper, we present a novel hydrophilic coating material (Wellture Finetech, Korea) which can be utilized as a coating layer for anti-contamination for electrical and electronic system. The coating material was deposited on 4 inch silicon wafer with several different film thickness. The film thickness was controlled by spin coating speed. After curing of the film, we have scratched by permanent marker to check self-cleaning property of the film. Also we have executed several mechanical tests of the films. As the spin coating speed is increased, the film thickness was thinned from 230 nm to 125 nm. Contact angle of the film was lowered from $30^{\circ}$ to $12^{\circ}$ as the spin coating speed is increased from 700 to 2,500 rpm. On permanent marker scratched film surface coated at 1,000 rpm, we have poured regular city water to investigate self cleaning property of the film. The scratches were gradually separated from the film surface due to super-hydrophilicity of the film. Hardness of spin coated film was 9H measured by ASTM D3363 method. and adhesion of all film was 5B tested by ASTM D3359 method. Also, to get exact hardness value of the film, we have utilized a nano-indenter. As spin speed is increased, the hardness of film was increased from 3 GPa to 5 GPa.

A Study on the Wettability by Surfactant of Hydrophobic-Hydrophilic Powders (Hydrophobic-Hydrophilic 분체의 계면활성제에 의한 Wettability 연구)

  • Rho, Seung-Baik;Lim, Mi Ae
    • Applied Chemistry for Engineering
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    • v.9 no.2
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    • pp.177-184
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    • 1998
  • The contact angle on powder hydrophobic polymer PMMA(polymethylmethacrylate), PVC(poly vinyl chloride) and hydrophilic metal aluminium was measured by wicking method on the base of Washburn equation for water, glycerol, formamide, diiodomethane, 1,1,2,2-tetrabromoethane, 1-bromonaphthalene, acetone, chloroform, benzene, ethanol, methanol, and for anionic surfactant SDS(sodium dodecyl sulfate) and cationic surfactant CATB(cetyl trimethylamonium bromide) aqueous solution with concentrations. The values of ${\gamma}_c$ estimated by Zisman plot and adhesion tension plot for contact angle with organic liquids, SDS, and CTAB aqueous solutions were 43.5, 28.3, and $36.2mNm^{-1}$ for PMMA and 44.2, 25.0, and $34.8mNm^{-1}$ for PVC, respectively. From the results, it was considered that wettability and characteristics of solid surface were transformed by adding surfactant. The surface free energy, ${\gamma}_s$ and its components of PMMA, PVC, and aluminium were determined using harmonic equation.

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Prospective randomized clinical trial of hydrophilic tapered implant placement at maxillary posterior area: 6 weeks and 12 weeks loading

  • Kim, Seong-Beom;Yun, Pil-Young;Kim, Sang-Yun;Yi, Yang-Jin;Kim, Ji-Yun;Kim, Young-Kyun
    • The Journal of Advanced Prosthodontics
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    • v.8 no.5
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    • pp.396-403
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    • 2016
  • PURPOSE. Early loading of implant can be determined by excellent primary stability and characteristic of implant surface. The implant system with recently improved surface can have load application 4-6 weeks after installing in maxilla and mandible. This study evaluated the effect of healing period to the stability of hydrophilic tapered-type implant at maxillary posterior area. MATERIALS AND METHODS. This study included 30 patients treated by hydrophilic tapered-type implants (total 41 implants at maxilla) and classified by two groups depending on healing period. Group 1 (11 patients, 15 implants) was a control group and the healing period was 12 weeks, and Group 2 (19 patients, 26 implants) was test group and the healing period was 6 weeks. Immediately after implant placement, at the first impression taking, implant stability was measured using Osstell Mentor. The patients also took periapical radiographs after restoration delivery, 12 months after restoration and final followup period. The marginal bone loss around the implants was measured using the periapical radiographs. RESULTS. All implants were survived and success rate was 97.56%. The marginal bone loss was less than 1mm after 1 year postoperatively except the one implant. The stabilities of the implants were not correlated with age, healing period until loading, insertion torque (IT), the diameter of fixture and the location of implant. Only the quality of bone in group 2 (6 week) was correlated with the stability of implant. CONCLUSION. Healing period of 6 weeks can make the similar clinical prognosis of implants to that of healing period of 12 weeks if bone quality is carefully considered in case of early loading.

Evaluation of Porous PLLA Scaffold for Chondrogenic Differentiation of Stem Cells

  • Jung, Hyun-Jung;Park, Kwi-Deok;Ahn, Kwang-Duk;Ahn, Dong-June;Han, Dong-Keun
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.268-268
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    • 2006
  • Due to their multipotency, stem cells can differentiate into a variety of specialized cell types, such as chondrocytes, osteoblasts, myoblasts, and nerve cells. As an alternative to mature tissue cells, stem cells are of importance in tissue engineering and regenerative medicine. Since interactions between scaffold and cells play an important role in the tissue development in vitro, synthetic oligopeptides have been immobilized onto polymeric scaffolds to improve specific cell attachment and even to stimulate cell differentiation. In this study, chondrogenic differentiation of stem cells was evaluated using surface-modified PLLA scaffolds, i.e., either hydrophilic acrylic acid (AA)-grafted PLLA or RGD-immobilized one. Porous PLLA scaffolds were prepared using a gas foaming method, followed by plasma treatment and subsequent grafting of AA to introduce a hydrophilicity (PLLA-PAA). This was further processed to fix RGD peptide to make an RGD-immobilized scaffold (PLLA-PAA-RGD). Stem cells were seeded at $1{\times}10^{6}$ cells per scaffold and the cell-PLLA constructs were cultured for up to 4 weeks in the chondrogenic medium. Using these surface-modified scaffolds, adhesion, proliferation, and chondrogenic differentiation of stem cells were evaluated. The surface of PLLA scaffolds turned hydrophilic (water contact angle, 45 degrees) with both plasma treatment and AA grafting. The hydrophilicity of RGD-immobilized surface was not significantly altered. Cell proliferation rate on the either PLLA-PAA or PLLA-PAA-RGD surface was obviously improved, especially with the RGD-immobilized one as compared to the control PLLA one. Chondrogenic differentiation was clearly identified with Safranin O staining of GAG in the AA- or RGD-grafted PLLA substrates. This study demonstrated that modified polymer surfaces may provide better environment for chondrogenesis of stem cells.

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