• Title/Summary/Keyword: hydroperoxide

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A Study on the Antimicrobial Activity of Copper Alloy Metal Fiber on Water Soluble Metal Working Fluids (수용성 절삭유의 Copper Alloy Metal Fiber에 의한 항균 특성에 관한 연구)

  • Song, Ju-Yeong;Lee, Sang-Ho;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.3
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    • pp.233-237
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    • 2007
  • This study is focused on the possibility of copper alloy metal fiber for an antimicrobial activity in the water soluble metal working fluids. Electrochemical potential of Cu/Zn ion is -268mV, and easily makes radicals with molecular oxygen. Especially, hydroperoxide radical shows strong toxicity to the strains. Plasma membrane causes conformational change when hydroperoxide radical binds to plasma membrane. Elution of copper ion from copper alloy metal fiber is detected in metal working fluid. As a result antimicrobial activity of copper alloy metal fiber in metal working fluid is superior to that of copper fiber.

Oxidation of Dibenzothiophene Catalyzed by Surfactant-Hemoprotein Complexes in Anhydrous Nonpolar Organic Solvents

  • Ryu, Keun-Garp;Chae, Young-Rae;Kwon, O-Yul
    • Journal of Microbiology and Biotechnology
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    • v.13 no.5
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    • pp.647-650
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    • 2003
  • In anhydrous organic solvents, the complexes formed between AOT (dodecylbenzene sulfuric acid sodium salt) and hemoproteins, such as hemoglobin, myoglobin, or cytochrome c, displayed remarkably higher activity than the hemoprotein powders to oxidize dibenzothiophene, a model compound of organic sulfurs contained in fossil fuels. In slightly hydrophobic organic solvents, such as ethyl acetate and butyl acetate, dibenzothiophene was completely oxidized catalytically by the cytochrome c-AOT complex with cumene hydroperoxide (${\alpha},{\alpha}-dimethylbenzyl$ hydroperoxide) as an oxidant. In highly hydrophobic organic solvents, such as decane and hexadecane, however, the activity of the cytochrome c-AOT complex decreased, presumably due to the aggregation of the hemoprotein-AOT complex in these solvents.

Physiological Roles of Bacillus subtilis thiol peroxidase gene in response to oxidative stress (산화적 스트레스에 대한 Bacillus subtilis의 thiol peroxidase 유전자의 생리적인 기능)

  • Kim, Ha-Kun;Kim, Sung-Jin
    • The Journal of Natural Sciences
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    • v.15 no.1
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    • pp.57-67
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    • 2005
  • In Order to investigate the physiological role of thiol peroxidase in Bacillus subtilis, a thiol peroxidase (btpx) knock-out mutant was generated by homologous recombination. The growth of btpx knock-out mutant in aerobic condition showed a similar pattern with that of wild type of Bacillus subtilis 168/ But btpx knock-out mutant showed a retarded growht in response to oxidative stress such as $H_2O_2$, cumene hydroperoxide (CHP) treatments.

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Effect of Linoleate Hydroperoxide on Pepsin Activity (리놀레산 과산화물이 펩신 활성도에 미치는 영향)

  • Choi, Kap-Seong;Kim, Ze-Uook;Moon, Tae-Wha
    • Korean Journal of Food Science and Technology
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    • v.23 no.2
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    • pp.224-228
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    • 1991
  • The effect of linoleate hydroperoxides(LAHPO) on pepsin activity was investigated. The activity of pepsin was largely decreased by LAHPO at various temperatures and pH. The inactivation of pepsin seems to be the radicals in the system because ascorbate and metal ions enhanced the inactivation of enzyme by LAHPO. It was shown by SDS-PAGE that LAHPO caused scission of the enzyme in the model system.

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Effect of Ginseng Extracts on Photosensitized Peroxidation of Human Erythrocyte Ghosts (Erythrocyte Ghost의 광산화반응에 미치는 인삼추출물의 영향)

  • Baek, Tae-Hong;Cheon, Hyeon-Ja;Gang, Byeong-Su
    • Journal of Ginseng Research
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    • v.14 no.1
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    • pp.30-35
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    • 1990
  • The photooxidation of human erythrocyte ghosts has been studied and the effects of ginseng water extract on it have been investigated. In the presence of photosensitizer, rose bengal, human erythrocyte ghosts have caused photooxidation by lO2 and produced lip)id hydroperoxides. Ginseng water extract and d-${\alpha}$-tocofherol have inhibited photooxidation, ,whereas ascorbic acid has developed in low concentrations but inhibited in high concentrations. On the other hand, amounts of lipid hydroperoxide produced by photooxidation were decreased by addition of catalase after irradiation and according to sequential addition of ginseng water extract into it, the formation of lipid hydrolleroxide was decreased simultaneously.

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A case study of methanol explosion by metal hydroperoxid (유기 과산화물에 의한 메탄올 폭발 사례 연구)

  • Won You-Jon;Kang Kyong-Sik
    • Journal of the Korea Safety Management & Science
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    • v.7 no.5
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    • pp.119-133
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    • 2005
  • In the June, 1991, there was the explosion in which methanol rectified column as a part of the new surface active agent's manufacturing processes. The type of explosion was estimated as the 'detonation'. The methanol rectified column was ruined, and broken pieces of the column were scattered within 900m. Also, there were victims such as the two deads and thirteen wounded persons. The cause of the explosion was heat explosion by being concentrated locally from 0.1% to several tens% of supply fluid at Metal Hydroperoxide, which was produced by methanol and hydrogen peroxide used as the bleach of surface active agent, during the operation stoppage process of methanol rectified column.

Protective Effect of Stilbenes on Oxidative Damage

  • Na, Min-Kyun;Min, Byung-Sun;Bae, Ki-Hwan
    • Natural Product Sciences
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    • v.13 no.4
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    • pp.369-372
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    • 2007
  • Oxidative stress induced by reactive oxygen species (ROS) has been suggested to be the cause of various degenerative diseases as well as aging. To evaluate the antioxidant potential of stilbenes, we have investigated the cytoprotective effect of 10 stilbenes derived from plants on the oxidative stress induced by tertiary butyl hydroperoxide (t-BuOOH). Of the stilbenes tested, piceatannol (3) showed the most potent activity, which was further investigated using an animal model. When 3 (30 or 10 mg/kg) was topically administered prior to UVB irradiation, the amount of the thiobarbituric acid reactive substances (TBARS) was significantly reduced compared to that of the control (vehicle). Our findings suggest that piceatannol is capable of protecting cells and tissues from oxidative stress.

Isomeric Composition of Hydroperoxides Formed by Autoxidation of Adlay Lipid and Triglyceride (율무 지방빌의 자동산화에 의해서 형성된 Hydroperoxides 이성체 조성)

  • 한지숙;이숙희;최홍식
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.19 no.3
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    • pp.229-233
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    • 1990
  • The compositions of hydroperoxy fatty acid components of lipid in raw adlay powder(RAP) and processed adlay powder(PAP) stored at 35$^{\circ}C$ and PAP lipid and triglyceride(TG) autoxi야-zed 35$^{\circ}C$ were studied. During autoxidation the time taken to reach 100 of peroxide and 13-hydroperoxide isomers were the major hydroperoxy fatty acids found in oxidized adlay lipid. Lower levels of 8-. 10-, 11-, 12- and 16-hydroperoxide isomer were also observed. The composi-tions of hydroperoxy fatty acid componets obtained from sutoxidized RAP lipid and TG were similar to those of hydroperoxy fatty acid components is lipid extracted from stored RAP and PAP.

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