• 한국재료학회지
• /
• 제12권8호
• /
• pp.624-633
• /
• 2002

In order to improve the hydrogen storage capacity and the activation properties of the hydrogen storage alloys, the rare-earth metal alloy series, MmN $i_{4.5}$M $n_{0.5}$Z $r_{x}$(x=0, 0.025, 0.05, 0.1), are prepared by adding excess Zr in MmN $i_{4.5}$M $n_{0.5}$ alloy. The various parts in hydrogen storage vessel consisted of copper pipes reached the setting temperature within 4~5 minutes after heat addition, which indicated that storage vessel had a good heat conductivity required in application. The performance test on storage vessel filled with rare-earth metal alloys of 1000 gr was also conducted after hydrogen charging for 10 min at $18^{\circ}C$ under 10 atm. It showed that the average capacity of discharged hydrogen volume was found to be for $MmNi_{4.5}$ $Mn_{0.5}$ and $MmNi_{4.5}$ $Mn_{x}$ 0.5/$Zr_{samples}$ indicated that the released amount of hydrogen for this $AB_{5}$ type alloys was more than 92 % of theoretic value, and also it was found that the optimum discharging temperature for obtaining an appropriate pressure of 3 atm was determined to be $V^{\circ}C$ for $MmNi_{4.5}$ $Mn_{0.5}$$Zr_{x}$(x=0, 0.025, 0.05, 0.1) hydrogen storage alloys. The released amount of these hydrogen storage samples was 125 $\ell$ , 122.4 $\ell$ and 108.15 $\ell$/kg for $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{0.025}$ $MmNi_{4.5}$M $n_{0.5}$Z $r_{0.05}$, and MmN $i_{4.5}$ Mn_0.5$Zr_{0}$, at $70^{\circ}C$ respectively. Amount of the 2nd phases increase with increase on Zr contents in $MmNi_{4.5}$$Mn_{0.5}$ $Zr_{ 0.1}$/ alloy. This phenomenon indicates that$ ZrNi_3$ in $MmNi_{4.5}$ $Mn_{0.5}$ $Zr_{x}$ / phase, which shows the maximum storage capacity and the strong resistance to intrinsic degradation, is considered as a proper alloy for hydrogen storage. As the Zr contents increase, the activation time and the plateau pressure decreases and sloping of the plateau pressure increases.creases.eases.s.

• 한국수소및신에너지학회논문집
• /
• 제34권1호
• /
• pp.26-31
• /
• 2023

In this study, in order to propose a modular method for type IV high aspect ratio modular hydrogen storage vessel, a numerical analysis was conducted on the heat transfer behavior in series and parallel connection methods, and the differences according to each connection method were reviewed. Computational fluid dynamics software was used to check the internal temperature and pressure values of the hydrogen storage container under charging conditions. In terms of thermal safety when charging hydrogen gas, it was confirmed that the parallel modularization method was superior.

• Nuclear Engineering and Technology
• /
• 제54권1호
• /
• pp.177-185
• /
• 2022

Hydrogen risk in the containment filtered venting system (CFVS) vessel was analyzed, considering operation pressure and modes with the effect of PAR and accident scenarios. The CFVS is to depressurize the containment by venting the containment atmosphere through the filtering system. The CFVS could be subject to hydrogen risk due to the change of atmospheric conditions while the containment atmosphere passes through the CFVS. It was found that hydrogen risk increased as the CFVS opening pressure was set higher because more combustible gases generated by Molten Core Concrete Interaction flowed into the CFVS. Hydrogen risk was independent of operation modes and found only at the early phase of venting both for continuous and cyclic operation modes. With PAR, hydrogen risk appeared only at the 0.9 MPa opening pressure for Station Black-Out accidents. Without PAR, however, hydrogen risk appeared even with the CFVS opening set-point of 0.5 MPa. In a slow accident like SBO, hydrogen risk was more threatening than a fast accident like Large Break Loss-of-Coolant Accident. Through this study, it is recommended to set the CFVS opening pressure lower than 0.9 MPa and to operate it in the cyclic mode to keep the CFVS available as long as possible.

• Journal of Welding and Joining
• /
• 제1권2호
• /
• pp.45-52
• /
• 1983

Many pressure vessels for the hot H$\sub$2//H$\sub$2/S service are made of 2+1/4Cr-1Mo steel with austenitic stainless steel overlay to combat agressive corrosion due to hydrogen sulfide. Hydrogen dissolves in to materials during operation, and sometimes gives rise to unfore-seeable damages. Appropriate precautions must, therefore, be taken to avoid the hydrogen induced damages in the design, fabrication and operation stage of such reactor vessels. Recently, hydrogeninduced cracking (or Disbonding) was found at the interface between base metal and stainless weld overlay of a desulfurizing reactor. Since the stainless steel overlay weld metal is subjected to thermal and internal-pressure loads in reactor operation, it is desirable for the overlay weld metal to have high strength and ductility from the stand point of structural safety. In section III of ASME Boiler and Pressure Vessel Code, Post-Weld Heat Treatment(PWHT) of more than one hour per inch at over 1100.deg. F(593.deg. C) is required for the weld joints of low alloy pressure vessel steels. This heat treatment to relieve stresses in the welded joint during construction of the pressure vessel is considered to cause sensitization of the overlay weld metal. The present study was carried out to make clear the diffusion of carbon migration by PWHT in dissimilar metal welded joint. The main conclusion reached from this study are as follows: 1) The theoretical analysis for diffusion of carbon in stainless steel overlay weld metal does not agree with Fick's 2nd law but the general law of molecular diffusion phenomenon by thermodynamic chemical potential. 2) In the stainless steel overlay welded joint, the PWHT at 720.deg. C for 10 hours causes a diffusion of carbon atoms from ferritic steel into austenitic steel according to the theoretical analysis for carbon migration and its experiment. 3) In case of PWHT at 720.deg. C for 10 hours, the micro-hardness of stainless steel weld metal in bonded zone increase very highly in the carburized layer with remarkable hardening than that of weld metal.

• 한국압력기기공학회 논문집
• /
• 제4권2호
• /
• pp.1-6
• /
• 2008

Very High Temperature Gas Cooled Reactor (VHTR) has been selected as a high energy heat source for nuclear hydrogen generation. The VHTR can produce hydrogen from heat and water by using a thermo-chemical process or from heat, water, and natural gas by steam reformer technology. A co-axial double-tube primary hot gas duct (HGD) is a key component connecting the reactor pressure vessel and the intermediate heat exchanger (IHX) for the VHTR. In this study, a preliminary design analysis for the primary HGD of the nuclear hydrogen system was carried out. These preliminary design activities include a determination of the size, a strength evaluation and an appropriate material selection. The determination of the size was undertaken based on various engineering concepts, such as a constant flow velocity model, a constant flow rate model, a constant hydraulic head model, and finally a heat balanced model.

• 대한기계학회논문집A
• /
• 제26권6호
• /
• pp.1107-1113
• /
• 2002

This study presents the hydrogen emblittlement in the metal, which decreases the ductility and then induces the brittle fracture. The contribution deals with the effect of strain rate and notch geometry on hydrogen emblittlement of 1.25Cr-0.5Mo and 2.25Cr-1Mo steels, which are in use at high pressure vessel. Smooth and notched specimens were examined to obtain the elongation and tensile strength. For charging the hydrogen in the metal, the cathodic electrolytic method was used. In this process, current density is maintained constant. The amount of hydrogen penetrated in the specimen was detected by the hydrogen determenator(LECO RH404) with the various charging time. The distribution of hydrogen concentration penetrated in the specimen was obtained by finite element analysis. The amount of hydrogen is high in smooth specimen and tends to concentrate in the vicinity of surface. The elongation and tensile strength decreased with the passage of charging time in 1.25Cr-0.5Mo and 2.25Cr-1Mo steels. The elongation increased and tensile strength decreased as strain rate increased. As a result of this study, it is supposed that 1.25Cr-0.5Mo steel is more sensitive than 2.25Cr-lMo steel in hydrogen embrittlement. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• 한국안전학회지
• /
• 제33권2호
• /
• pp.1-7
• /
• 2018

The multi-scale analysis is more proper and precise for composite materials because of considering the individual microscopic structure and properties of each material for composite materials. The purpose of this study is to verify the validity of using palladium particles in carbon/fiber composites by multi-scale analysis. The palladium is a material for itself to detect leaking hydrogen by using the property of adsorbing hydrogen. The macroscopic model material properties used in this study are homogeneous material properties from microstructure. Homogenized material properties that are calculated from periodic boundary conditions in the microscopic representative volume element model of each macroscopic analysis model. In this study, three macroscopic models were used : carbon fiber/epoxy, carbon fiber/palladium, palladium/epoxy. As a result, adding palladium to carbon/epoxy composite is not a problem in terms of strength.

• 한국수소및신에너지학회논문집
• /
• 제29권6호
• /
• pp.570-577
• /
• 2018

Composite pressure vessels made through filament winding are widely used in various fields. Numerous studies regarding composite pressure vessels have been conducted in the automotive industry to improve the space efficiency of trunks as well as the fuel efficiency. Compared with steel liquefied petroleum gas (LPG) vessels used in the conventional LPG vehicles, the use of type 4 composite pressure vessels has advantages in terms of reduction of the weight of vehicles. This study focused on development of type 4 composite pressure vessels that can be installed in the spare tire well. Those type 4 composite pressure vessels are designed with torispherical dome shapes instead of geodecis dome shapes because of the space limitation. To reduce deformation due to the stresses in the axial direction of the vessels, thereby securing the safety of the container, the reinforcing bar concept was applied. A structural analysis software, ABAQUS, confirmed the effect of the reinforcing bar on the axial deformation through the type 4 composite pressure vessel. As a result, the final winding angle of the composite layer was analyzed by applying $26^{\circ}/28^{\circ}/26^{\circ}/28^{\circ}/26^{\circ}/88^{\circ}$ The tensile stress was 939.2 MPa and the compressive stress was 249.3 MPa.

• 연구논문집
• /
• 통권29호
• /
• pp.91-99
• /
• 1999

Fatigue crack growth behaviors of Cr-Mo steels developed recently for thick-wall pressure vessel were investigated. Experiments in accordance with ASTM E647 standard were performed for 1/2 inch CT specimens of $2^(1/4)$Cr-1Mo and 3Cr-IMo steels in gaseous environments, hydrogen gas of 10 atm, 1 atm and argon gas of 1 atm. Fatigue crack growth rates were observed and effects of gaseous hydrogen and argon on the crack growth behavior were discussed.

• Nuclear Engineering and Technology
• /
• 제54권6호
• /
• pp.2311-2320
• /
• 2022

The main outcomes of the experiments H2P6 performed in the thermal-hydraulics large-scale PANDA facility at PSI in the frame of the OECD/NEA HYMERES-2 project are presented in this article. The experiments of the H2P6 series consists of two PANDA tests characterized by the activation of three (H2P6_1) or one (H2P6_2) cooler(s) in an initially stratified and pressurized containment atmosphere. The initial stratification is defined by a helium-rich region located in the upper part of the vessel and a steam/air atmosphere in the lower part. The activation of the cooler(s) results i) in the condensation of the steam in the vicinity of the cooler(s), ii) the corresponding activation of large scale natural circulation currents in the vessel atmosphere, with the result of iii) the re-distribution and mixing of the Helium stratification initially located in the upper half of the vessel and iv) the continuous pressure decay. The initial helium layer represents hydrogen generated in a postulated severe accident. The main question to be answered by the experiments is whether or not the interaction of the different, localized cooler units would be important for the application of numerical methods. The paper describes the initial and boundary conditions and the experimental results of the H2P6 series with the suggestion of simple scaling laws for both experiments in terms of i) the temperature difference(s) across the cooler(s), ii) the transient steam and helium content and iii) the pressure decay in the vessel. The outcomes of this scaling indicate that the interaction between separate, closely localized units does not play a prominent role for the present experiments. It is therefore reasonable to model several units as one large component with equivalent heat transfer area and total water flow rate.