• 제목/요약/키워드: hydrogen generation

검색결과 805건 처리시간 0.024초

하수관내 침전물의 황화수소가스 발생에 관한 연구 (Production of Hydrogen Sulfide Gas from Sediments in Concrete Sewer)

  • 조선형;고영송;남상호
    • 상하수도학회지
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    • 제10권3호
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    • pp.83-91
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    • 1996
  • The pulverized wastes originated from kitchen garbage grinder cause an additional load in sewage treatment plant and water environment. Therefore, several problems occur in sewer, such as microbial corrosion, odor, psychoda and fly interrupting flow of sewage etc. by their precipitation with earth and sand. This study was conducted on two experiments: hydrogen sulfide gas generation from sediments in sewer and anaerobic batch test. In anaerobic batch test, gas generation was increased when organic compounds were increased in concentration. Sulfide was decreased upon decreasing in sulfate concentration. In $H_2S$ gas generation test along the depth of sediments there were two different sampling sites which are apart from about 50 cm each other in a menhole. The one has the thickness of 55 cm from the surface, the other, of 60 cm. The hydrogen sulfide gas production rates were measured based on ranges from 0 to 10 cm, 10 to 20 cm, 20 to 30 cm for two samples. The results obtained were 1.08, between 0 to 10 cm in depth for the sample thickness of 55 cm and 3.07, 5.36, $5.42{\mu}g/g-VS{\cdot}hr$ in order of depth for the sample thickness of 60 cm, respectively.

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골판지 재활용 공정수의 혐기성 분해에 따른 유해 기체의 생성과 부식 (Generation of Hazardous Gas and Corrosion Originated from Anaerobic Digestion of Process Water in OCC Recycling Mill)

  • 박대식;류정용;송봉근;서영범;성용주
    • 펄프종이기술
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    • 제37권3호
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    • pp.59-65
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    • 2005
  • There are accumulations of remained chemical additives and contaminants in the process water of semi-closed linerboard mill. High temperature of the process water aggravates the anaerobic digestion of contaminated process water and causes the generation of hazardous gases, which are from the biological reaction of varied additives and contaminants. The hydrogen sulfide in the gases easily combine with moisture in the air, and become sulfuric acid, which causes corrosion of paper machinery. This hydrogen sulfide is from the reduction of sulfate ions in the process water, and the sulfate ions are mostly from the alum. We changed the alum to PAC (Poly Aluminum Chloride). The results were preventing generation of hydrogen sulfide, and equivalent sizing effect by the use of PAC.

신경교세포주 C6 glial에서 Zinc의 Hydrogen Peroxide($H_2O_2$) 생성을 통한 세포고사 (Zinc-induced Apoptosis in C6 glial Cells via Generation of Hydrogen Peroxide($H_2O_2$))

  • 이지현;김명선;소흥섭;김남송;조광호;이향주;이기남;박길래
    • Toxicological Research
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    • 제16권3호
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    • pp.179-185
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    • 2000
  • Zinc is known to generate reactive oxygen species (ROS) including superoxide anion and hydrogen peroxide ($H_2O_2$), which eventually contribute to cytotoxicity in a variety of cell types. Here in, we demonstrated that zinc decreased the viability of C6 glial cells in a time and dose-dependent manner, which was revealed as apoptosis characterized by ladder-pattern fragmentation of genomic DNA. chromatin condensation and DNA fragmentation in Hoechst dye staining. Zinc-induced apoptosis of C6 glial cells was prevented by the addition of catalase and antioxidants including reduced glutathione (GSH), N-acetyl-L-cysteine (NAC) and pyrrolidinedithiocarbamate (PDTC). Wefurther confirmed that zinc decreased intrac-ellular levels of GSH and generated $H_2O_2$in C6 glial cells. Moreover, antioxidants also decreased the generation of zinc-induced $H_2O_2$ in C6 glial cells. These data indicated that zinc-induced the apoptotic death of C6 glial cells via generation of reactive oxygen species such as $H_2O_2$.

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동전기적 가스발생방식의 자동윤활주유기 개발 (Development of Automatic Grease Lubricator for Gas Generation Type of Galvanic Electricity)

  • 왕덕현
    • 한국기계가공학회지
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    • 제7권4호
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    • pp.121-127
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    • 2008
  • Automatic grease lubricator is an equipment that provides adequate amount of fresh grease constantly to the shaft and bearings of machines. It minimizes the friction heat and reduces the friction loss of machines to the least. This paper is developing an automatic grease lubricator using a mode of the gas generation type from galvanic electricity. The ultimate goal of this equipment is to lubricate an adequate amount of grease with galvanic corrosion. In an electrolyte, combining anode(Mo) with cathode(Zn) is pressing out hydrogen gas of an galvanic element with galvanic reaction. The characteristics of this method is continuous flowing small hydrogen gas and controling the usage of the amount of the generation of hydrogen gas. The exterior body of grease lubricator was analyzed by Digital Mock-up of CATIA V5 and finite element analysis. The maximum stress is distributed over the outlet part where the grease lubricator suddenly narrowly contracts. The outlet part is analyzed with different constructed angle due to the different loading and setting angles. Using the analyzed design, RP trial products were producted and tested.

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아크성 스트리머방전을 이용한 플라즈마 반응기의 수소발생 특성 (The characteristic of Hydrogen generation by Plasma reactor using arc like streamer discharge)

  • 김종석;박재윤;정장근;한상보;고희석;박상현;이현우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.2109-2111
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    • 2005
  • The effect of arc like streamer discharge is investigated on the hydrogen generation in the plasma reactor with multineedle - plate electrode geometry and SDR (Plasma reactor using the surface discharge). An additive of the two type (the saw type and the pellet type) was placed under the water surface to investigate the effect of the water surface conditions. The experimental results are compared in case of the reactor with and without an additive on the water surface. The generation of arc streamer discharge is more powerful with increasing applied voltage in the saw type. The maximum hydrogen Production concentration is about 4300 ppm at 74W in the SDR with additive of the saw type. Also, the Energy yield of the SDR (28990 g/kWh, 4300ppm, 74W) is higher than of the multineedle - plate electrode geometry (20892g/kWh, 3300ppm, 77W).

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고농도 과산화수소와 수소화물의 지속적인 반응에 대한 연구 (Feasibility of Energy Generation from Chemical Reaction between Hydrogen Peroxide/Hydride)

  • 서성현
    • 한국수소및신에너지학회논문집
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    • 제26권3호
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    • pp.271-277
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    • 2015
  • The present paper discusses about noble idea on various reactions including hydrides, hydrogen peroxide and nano-sized metal powders, which do not emit toxic materials as well as carbon dioxide. Here in this paper, the very first-ever concept that heat energy can be generated from the direct reaction between sodium borohydride and hydrogen peroxide is presented. Sodium hydride as fuel can supply hydrogen reacting with oxygen provided by the decomposition of hydrogen peroxide solution. Solid sodium borohydride can be resolved in water and treated as liquid solution for the easy handling and the practical usage although its solid powder can be directly mixed with hydrogen peroxide for the higher reactivity. The thermodynamic analysis was conducted to estimate adiabatic reaction temperatures from these materials. The preliminary experiment on the reactions conducted using sodium borohydride powder and hydrogen peroxide water solution revealed that the self-propagating reaction can occur and that its reactivity increases with an increase of hydrogen peroxide concentration.

바이오가스 MGT 발전용 전처리시스템 재료특성 평가 (Test Evaluation of Pretreatment System Material for Bio-gas Micro Gas Turbine Power Generation)

  • 허광범;박정극;임상규;김재훈
    • 신재생에너지
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    • 제4권1호
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    • pp.37-43
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    • 2008
  • As the distributed generation becomes more reliable and economically feasible, it is expected that a higher application of the distributed generation units would be interconnected to the existing grids. This paper describes the results for the mechanical and environmental tests of pretreatment system material. Mechanical Characteristics make differences between parent / weldment, Notch existence / non-existence and air/$H_2O$ conditions. As a result, the life of pipe lines needs to maintain and fit for the operating period. Based on actual situations, the tension test of pipe welding-parts is carried out varying the exposure time of hydrogen sulfide and the fatigue resistance test is also performed inserting a notch into the pipe welding part, being exposed to the hydrogen sulfide environment for 720 hours.

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온도측정에 의한 히트파이프의 수명예측 (Prediction of Life of Heat Pipes by Measuring Temperature Distribution)

  • 신흥태;;이윤표
    • 대한기계학회논문집B
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    • 제23권7호
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    • pp.856-863
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    • 1999
  • The thermal performance degradation of heat pipes is caused by the non-condensable gas generation mainly due to the electrochemical corrosion which results from the reaction of working fluids with tube materials. In this study, a simplified method described below was proposed to estimate the life of heat pipes concerning the non-condensable gas generation. The temperature distributions at the outer surface of heat pipes was measured, and based on them the amount of non-condensable gas of hydrogen was estimated. Applying it to the Arrhenius model, the mass generation of hydrogen and the volume occupied by the gas In heat pipes could be estimated for an operating temperature and time. Moreover, this simplified method was applied to the accelerated life test of nine methanol-stainless steel heat pipe samples.