• Title/Summary/Keyword: hydrogen charging

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A Study of Hydrogen Embrittlement on a Material of CNG Storage Tank (CNG 저장용기 재료의 수소취성에 관한 연구)

  • Han, J.O.;Lee, Y.C.;Lee, J.S.;Chae, J.M.;Hong, S.H.
    • Journal of the Korean Institute of Gas
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    • v.15 no.2
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    • pp.9-14
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    • 2011
  • A set of test was conducted on a SA-372 steel for CNG storage tank to study the effect of hydrogen embrittlement. Tensile tests were carried out several conditions such as CNG, HCNG and H2 gas environment including air and Ar under the 35 MPa. Also, the test speed was set at 4*10^-4/s and 4*10^-5/s respectively. To maintain the high pressure for environmental gas during test process, we chose MTS which was installed autoclave. Test results showed that tensile stress, elongation rate and cross sectional contraction under Ar and CNG charging condition were similar to that of reference of air. And there was little bit change with test speed variations. However, hydrogen added conditions such as HCNG and H2 were revealed noticeable change in elongation rate and cross sectional contraction. Tensile stress was still uniform for all conditions. From the results, the effect of hydrogen embrittlement was confirmed on the hydrogen enriched conditions. Also its effect was showed more strong with much hydrogen concentration and slower test speed.

The Change of Microstructures According to the Charging Amounts of Hydrogen in High Strength DP Steels and TRIP Steel (고강도 DP강과 TRIP강의 표면 수소 주입량에 따른 수소취성평가)

  • Park, Jae-U;Lee, Cheol-Chi;Gang, Gye-Myeong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2012.05a
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    • pp.252-253
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    • 2012
  • 음극전기분해법을 이용하여 고강도 DP강과 TRIP강에 수소를 강제 주입시켜, 시험편 내 수소량을 정량적으로 분석하였고, 표면하 미소경도분포 측정과 소형펀치시험 및 파단면 관찰을 통하여 수소주입량에 따른 고강도 박강판재의 수소침투 및 수소취화거동을 평가하고자 하였다. DP강은 강도가 클수록 높은 수소량으로 조사되었고, TRIP강은 DP강에 비해 주입된 수소량이 적은 것으로 조사되었다. 또한 미소경도분포 및 소형펀치시험에서도 DP강은 TRIP강에 비해 수소취성에 민감성이 높은 것으로 평가되었다.

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A Study on Narrowband Electromagnetic Interference in The Cabin of Vehicle (자동차 실내 전자파의 협대역 특성에 관한 연구)

  • Kim, Minwoo;Woo, Hyungu
    • Journal of Auto-vehicle Safety Association
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    • v.8 no.2
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    • pp.30-36
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    • 2016
  • According to revolutionary developments in automobile technologies, various electronically controlled components of vehicles are rapidly increasing. A variety of advanced vehicles (hybrid vehicle, hydrogen fuel-cell vehicle, electric vehicle, etc.) using electrical energy source are increasing, too. The electromagnetic compatibility is getting more important for development of a vehicle because those advanced vehicles are equipped with more new electronic systems. In general, electromagnetic compatibility tests consist of an electromagnetic interference (EMI) test and an electromagnetic susceptibility (EMS) test. In this paper, in order to investigate the electromagnetic interference in the cabin of vehicle by various electric and electronic components of vehicles, a series of narrowband electromagnetic emission tests are conducted. For comparison, the several digital home appliances (smartphone under charging, laptop compuer and digital camera), which are used a lot in daily lives, are tested.

A Study on Electrolysis of Heavy Water and Interaction of Hydrogen with Lattice Defects in Palladium Electrodes (팔라디움전극에서 중수소의 전기분해와 수소와 격자결함의 반응에 관한 연구)

  • Ko, Won-Il;Yoon, Young-Ku;Park, Yong-Ki
    • Nuclear Engineering and Technology
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    • v.24 no.2
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    • pp.141-153
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    • 1992
  • Excess tritium analysis was peformed to verify whether or not cold fusion occurs during electrolysis of heavy water in the current density range of 83~600 mA/$\textrm{cm}^2$ for a period of 24 ~ 48 hours with use of palladium electrodes of seven different processing treatments and geometries. The extent of recombination of D$_2$ and $O_2$gases in the electrolytic cell was measured for the calculation of accurate enthaplpy values. The behavior and interaction of hydrogen atoms with defects in Pd electrodes were examined using the Sieverts gas charging and the positron annihilation(PA) method. Slight enrichment of tritium observed was attributed to electrolytic enrichment but not to the formation of a by-product of cold fusion. The extent of recombination of D$_2$and $O_2$gases was 32%. Hence the excess heat measured during the electrolysis was considered to be due to the exothermic reaction of recombination but not to nuclear fusion. Lifetime results from the PA measurements on the Pd electrodes indicated that hydrogen atoms could be trapped at dislocations and vacancies in the electrodes and that dislocations were slightly more preferred sites than vacancies. It was also inferred from R parameters that the formation of hydrides was accompanied by generation of mostly dislocations. Doppler broadening results of the Pd electrodes indicated that lattiec defect sites where positrons were trapped first increased and then decreased, and this cycle was repeated as electrolysis continued. It can be inferred from PA measurements on the cold-rolled Pd and the isochronally annealed Pd hydride specimens that microvoid-type defects existed in the hydrogen-charged electrode specimen.

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Effect of Hydride Reorientation on Delayed Hydride Cracking In Zr-2.5Nb Tubes

  • Yun Yeo Bum;Kim Young Suk;Im Kyung Soo;Cheong Yong Moo;Kim Sung Soo
    • Nuclear Engineering and Technology
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    • v.35 no.6
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    • pp.529-536
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    • 2003
  • The objective of this study is to investigate the reorientation of hydrides with applied stress intensity factor, the peak temperature and the time when to apply the stress intensity factor in a Zr-2.5Nb pressure tube during its thermal cycle treatment. Cantilever beam (CB) specimens with a notch of 0.5 mm in depth made from the Zr-2.5Nb tube were subjected to electrolytic hydrogen charging to contain 60 ppm H and then to a thermal cycle involving heating to the peak temperature of either 310 or $380^{\circ}C$, holding there for 50 h and then cooling to the test temperature of $250^{\circ}C$. The stress intensity factor of either 6.13 or $18.4\;MPa\sqrt{m}$ was applied at the beginning of the thermal cycle, at the end of the hold at the peak temperatures and after cooling to the test temperature, respectively. The reorientation of hydrides in the Zr-2.5Nb tube was enhanced with the increased peak temperature and applied stress intensity factor. Furthermore, when the CB specimens were subjected to $18.4\;MPa\sqrt{m}$ from the beginning of the thermal cycle, the reoriented hydrides occurred almost all over the Zr-2.5Nb tube, surprisingly suppressing the growth of a DHC crack. In contrast, when the CB specimens were subjected to the stress intensity factor at the test temperature, little reorientation of hydrides was observed except the notch region, leading the Zr-2.5Nb to grow a large DHC crack. Based on the correlation between the reorientation of hydrides and the DHC crack growth, a governing factor for DHC is discussed along with the feasibility of the Kim's DHC model.

Effect of Electrolyte Flow Rates on the Performance of Vanadium Redox Flow Battery (바나듐레독스흐름전지 전해질 유량에 따른 성능변화)

  • LEE, KEON JOO;KIM, SUNHOE
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.4
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    • pp.324-330
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    • 2015
  • The electrolyte flow rates of vanadium redox flow battery play very important role in terms of ion transfer to electrolyte, kinetics and pump efficiency in system. In this paper a vanadium redox flow battery single cell was tested to suggest the optimization criteria of electrolyte flow rates on the efficiencies. The compared electrolyte circulation flow rates in this experimental work were 15, 30 and 45 mL/min. The charge/discharge characteristics of the flow rate of 30 mL/min was the best out of all flow rates in terms of charging and discharging time. The current efficiencies, voltage efficiencies and energy efficiencies at the flow rate of 30 mL/min were the best. The IR losses obtained at thd current density of $40mA/cm^2$, at the flow rates of 15, 30 and 45 mL/min were 0.085 V, 0.042 V and 0.115 V, respectively. The charge efficiencies at the current density of $40mA/cm^2$ were 96.42%, 96.45% and 96.29% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. The voltge efficiencies at the current density of $40mA/cm^2$ were 77.34%, 80.62% and 76.10% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. Finally, the energy efficiencies at the current density of $40mA/cm^2$ were 74.57%, 77.76% and 73.27% for the electrolyte flow rates of 15, 30 and 45 mL/min, respectively. The optimum flow rates of electrolytes were 20 mL/min in most of operating variables of vanadium redox flow battery.

A Study on the Full Load Performance and Emission Characteristics with Turbo-charger Change in a HCNG Engine (HCNG 엔진의 터보차저 변경에 따른 전부하 출력 및 배출가스 특성 연구)

  • Park, Cheolwoong;Kim, Changgi;Lim, Gihun;Lee, Sungwon;Choi, Young;Lee, Sunyoup
    • Journal of the Korean Institute of Gas
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    • v.17 no.5
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    • pp.8-14
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    • 2013
  • Hydrogen-natural gas blends(HCNG) engine is optimizing technology of performance and emission characteristics with use of hydrogen's fast flame speed and wide flammability limit. As lean-burn limit is extended, the improvement in thermal efficiency and harmful emissions can be achieved. However, the extension of lean-burn limit under a wide open throttle operation point could be realized with the increase in boosting capacity in a lean-burn engine with turbo-charging system. In the present study, the power output characteristics of HCNG engine with turbo-charger change is assessed and feasibility of the increase in boosting capacity is evaluated. The turbo-charger design with high efficiency at higher flow rate rather than higher boosting pressure makes efficient operation possible at relatively rich mixture condition.

Study on Fuel Economy Characteristics of Plug-In Hybrid Electric Vehicle by Cumulative Distance (누적 주행거리에 따른 플러그인 하이브리드 자동차의 연비 특성 연구)

  • PARK, JINSUNG;LIM, JAEHYUK;KIM, KIHO;LEE, JUNGMIN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.6
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    • pp.661-667
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    • 2018
  • Electric vehicles are taken a long time to charge and are restricted driving where charging infrastructure was not sufficiently constructed. The vehicle developed to solve these problems is a plug-in hybrid vehicle. It is possible to drive a certain distance by using electric motor and when the battery runs out, it operate the engine. Plug-in hybrid vehicle have a complicated structure and a lot of parts comparing a general vehicle because the electric parts and the internal combustion engine are installed together. Therefore, as the aging (mileage) of the plug-in hybrid vehicle, the influence which change of fuel consumption is expected to be larger than a general vehicle, but an experimental data are lacking. In this paper, we cumulate a mileage of the plug-in hybrid vehicle about 15,000 km and measured the fuel economy when the cumulated distance reached within 160 km, 6,500 km, 15,000 km respectively, by using domestic public test method. For measuring fuel economy of the vehicle, CD mode (driving distance on a single charge) which use only motor and the CS mode which operate motor and combustion engine were measured respectively. As a result, the fuel economy slightly increased at cumulated mileage of 6,500 km compared to the 160 km and the fuel economy of 15,000 km was similar to 160 km.

Electrostatic Charging and Substrate Seeding in Gas Phase Synthesis of Nanocrystalline Diamond Powder

  • Cho, Jung-Min;Lee, Hak-Joo;Choi, Heon-Jin;Lee, Wook-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.418-418
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    • 2012
  • Synthesis of nanocrystalline diamond powder was investigated via a gas-to-particle scheme using the hot filament chemical vapor deposition. Effect of substrate surface seeding by nano diamond powder, and that of the electrical conductance of the substrate were studied. The substrate temperature, methane content in the precursor gas, filament-substrate distance and filament temperature were $670^{\circ}C$, 5% methane in hydrogen, 10 mm and $2400^{\circ}C$, respectively. The powder formation by gas-to-particle mechanism were greatly enhanced by the substrate seeding by the nano diamond powder. It was attributed to the removal of the electrostatic force between the substrate and the seeded nano diamond particle by the thermal electron shower from the hot filament, via the depolarization of the substrate surface or the attached diamond powder and subsequent levitation into the gas phase to serve as the gas-phase nucleation site. The powder formation was greatly favoured by the conducting substrate relative to the insulating substrate, which proved the actual effect of the electric static force in the powder formation.

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Influence of Safety Valve Pressure on Gelled Electrolyte Valve-Regulated Lead/Acid Batteries Under Deep Cycling Applications

  • Oh, Sang-Hyub;Kim, Myung-Soo;Lee, Jin-Bok;Lee, Heung-Lark;, Myung-Soo
    • Bulletin of the Korean Chemical Society
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    • v.23 no.1
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    • pp.75-80
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    • 2002
  • Cycle life tests have been carried out to evaluate the influence of safety valve pressure on valve regulated lead/acid batteries under deep cycling applications. Batteries were cycled at 5 hour rates at 100% DOD, and safety valve pressure was set to 1.08 and 2.00 bar, respectively. The batteries lost 248.3 g and 235.3 g of water for each case after about 1,200 cycles, but the cyclic performances of the batteries were comparable. Most of the gas of the battery during discharging was hydrogen, and the oxygen concentration increased to 18% after 3 hours of charging. The micro structure of the positive active materials was completely changed and the corrosion layer of the positive grid was less than $50{\mu}m$, regardless of the pressure of the safety valve after cycle life tests. The cause of discharge capacity decrease was found to be water loss and the shedding of the positive active materials. The pressure of safety valve does not give little effect to the cyclic performances and the failure modes of the gelled electrolyte valve-regulated lead acid batteries.