• Title/Summary/Keyword: hydrazine

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Performance Analysis of the Supersonic Nozzle Employed in a Small Liquid-rocket Engine for Ground Firing Test (소형 액체로켓엔진 지상연소시험용 초음속 노즐의 성능해석)

  • Kam, Ho-Dong;Kim, Jeong-Soo;Bae, Dae-Seok;Lee, Jae-Won
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.321-324
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    • 2011
  • A computational analysis of nozzle flow characteristics and plume structure using Reynolds-averaged Navier-Stokes equations with $k-{\omega}$ SST turbulence model was conducted to examine performance of the supersonic nozzle employed in a small liquid-rocket engine for ground firing test. Computed results and experimental outcome of 2-D converging-diverging nozzle flow were compared for verifying the computational capability as well as the turbulence model validity. Numerical computations of 2-D axisymmetric nozzle flow was carried out with the selected model. As a result, flow separation with backflow appeared around the nozzle exit. This investigation was reported as a background data for the optimal nozzle design of small liquid-propellant rocket engine for ground test.

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Development of Lunar Llander Thruster for Ground Test (달 착륙선 지상시험용 추력기 개발)

  • Lee, Jong-Lyul;Kim, In-Tae;Kim, Su-Kyum;Han, Cho-Young;Yu, Myoung-Jong;Kim, Ki-Ro;Byun, Do-Young
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.135-138
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    • 2011
  • As a basic research for the development of Korean lunar lander, propulsion system development for ground test is in progress. Thrust for descent is 200 N class. Design target is 220 N in vacuum thrust at 100 g/s flow rate, 200 psi chamber pressure. For ground test, thrust measurement system using LM guide was developed and test was performed. The result shows 160 N thrust in atmosphere condition at 210 psi chamber pressure.

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Synthesis of [1,2,4]-Triazole Derivatives and Their Anticancer Activities ([1,2,4]-Triazole 유도체의 합성 및 항암활성)

  • Lee, So-Ha;Kim, Jun-Suck;Jeon, Jae-Ho;Lee, Sook-Ja
    • Journal of the Korean Applied Science and Technology
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    • v.24 no.2
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    • pp.109-116
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    • 2007
  • 2-Chlorobenzoyl hydrazine refluxed with benzoyl isothiocyanate and phenyl isothiocyanate in ethanol for 3 hours to give benzamide derivative (1) and anilinederivative (2) on yield of 71%and 95%, respectively. Benzamide derivative (1) reacted with ethanolic sodium hydroxide on reflux to afford cyclization product (3), followed by general substitution reaction of two steps to give acetamide (5), and derivatived acetamides 7a-7k, while aniline derivative (2) reacted with ethanolic sodium hydroxide on reflux to afford another cyclization product (4). Thiol (4) reacted with N-phenyl chloroacetamide in the presence of potassim carbonate to give acetamide derivative (6). Compounds 1-7kwere evaluated for their growth inhibition against five cancer cell lines, including human lung carcinoma (A-549), human prostate cancer (DU145), human colon adenocarcinoma (HT-29), human malignant melanoma (SK-MEL-2) and human ovary malignant ascites (SK-OV-3) with sulforhodamine B (SRB) assay. All compounds (1-7k) showed low inhibition activities under 50% on 100M concentration.

Spray Pattern Analysis of the Injector in a Small Liquid-Rocket Engine (소형 액체로켓엔진 인젝터의 분무패턴 분석)

  • Jung, Hun;Kim, Jin-Seok;Kim, Jeong-Soo;Park, Jeong;Kim, Sung-Cho;Jang, Ki-Won
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.146-149
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    • 2006
  • Spray characteristics of an injector employed in mono-propellant hydrazine thrusters were investigated by PIV(particle image velocimetry) and LDA/PDA(laser/phase Doppler anemometry) techniques. The instanteneous plane image data captured by PIV measurement were examined in order to judge a pass-fail criteria of spray injection performance according to the specific pressure supplied. LDA/PDA technique were also applied to measure the velocity and droplet size of spray were not obtained from PIV measurement. The objective of this experimental study was the clear understanding of spray characteristics as well as the derivation of injector performance to understand clearly the spray characteristics by comparing the both results.

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A Study on the Variation of Vitamin C Content in Cooked Spinach by the Cookery Method. (시금치나물의 조리방법에 따른 Vitamin C 함량변화에 관한 연구)

  • 김양희
    • Journal of the Korean Home Economics Association
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    • v.11 no.1
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    • pp.44-56
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    • 1973
  • The effect of the temperature and the time of scalding, and the addition of various seasoning on the remaining % of total Vitamin C contained in Spinach (Spinacia oleracea) was studied and discussed by means of chemical kinetics. The quantitative measurements of total Vitamin C were made by 2,4-dinitrophenyl hydrazine (DNPH) method with Clinical Electrophotometer (Fisher). The sample spinach contains 39.88mg. % of total vitamin C on the average, and the ratio of oxidized and reduced forms of Vitamin C is 1 : 4.7. When the sample spinach was scalded, the kinetics of the decrease of the remaining total vitamin C. % was observed to follow the first order reactions regardless of the temperatures applied (i,e. 70$^{o}$ , 80$^{o}$ , 90$^{o}$ and 100$^{o}$ ) with half-life range of 2.10 - 1.47 minutes. In the case of the addition of various seasonings, the addition of various seasonings, the kinetics remaining Vitamin C % showed to be the zero order reactions regardless of the kinds of seasonings and storage temperatures. With the addition of seasonings, the stability of Vitamin C was found to be increased in the order table salt+sesame oil+vinegar+soybean sauce, without seasoning, table salt+sesame oil, table salt+sesame oil+soybean sauce.

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Antioxidative activity of peony root

  • Lee, Seung-Chul;Kwon, Yong-Soo;Kim, Hyun-Pyo;Heo, Moon-Young
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 2003.11a
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    • pp.61-61
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    • 2003
  • The ethanol extract of peony root (Paeonia Lactiflora Pall, Paeoniaceae) and its major active components including gallic acid and methyl gallate were evaluated for their protective effects against free radical generation and lipid peroxidation. And protective effects against hydrogen peroxide-induced oxidative DNA damage in a mammalian cell line were performed. The ethanol extract of peony root (PRE), gallic acid and methyl gallate were shown to possess the significant free radical scavenging effect against 1,1-diphenyl-2-picryl hydrazine (DPPH) radical generation and were revealed the inhibitory effect of lipid peroxidation as expressed by malondialdehyde (MDA) formation. They were also found to strongly inhibit hydrogen peroxide-induced DNA damage from NIH/3T3 fibroblasts, assessed by single cell gel electrophoresis. Furthermore, oral administration of 50% PRE (50% ethanol extract), gallic acid and methyl gallate potently inhibited micronucleated reticulocyte (MNRET) formation of mouse peripheral blood induced by KBrO3 treatment in vivo. Therefore, PRE containing gallic acid and methyl gallate may be a useful natural antioxidant by scavenging free radicals, inhibition of lipid peroxidation and protecting oxidative DNA damage.

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Demonstration of EPRI CHECWORKS Code to Predict FAC Wear of Secondary System Pipings of a Nuclear Power Plant

  • Lee, Sung-Ho;Seong Jegarl;Chung, Han-Sub
    • Nuclear Engineering and Technology
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    • v.31 no.4
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    • pp.375-384
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    • 1999
  • The credibility of CHECWORKS FAC model analysis was evaluated for plant application in a model plant chosen for demonstration. The operation condition at each pipe component was defined before the wear rate analysis by plant data base, water chemistry analysis, and network flow analysis. The predicted wear was compared with the measured wear for 57 sample components selected from 43 susceptible line groups analysed. The inspected 57 locations represent components of highest predicted wear in each line group. Both absolute value and relative ranking comparisons indicated reasonable correlations between the predicted and the measured values. Four components showed much higher measured wear rates than the predicted ones in the feed water train from main feed water pump discharge to steam generator, probably due to high hydrazine concentration operation the effect of which had not been incorporated into the CHECWORKS model. The measured wear was higher than the predicted one consistently for components with least susceptibility to FAC. It is believed that the conservatism maintained during UT data analysis dominated the measurement accuracy. A great deal of enhancement is anticipated over the current plant pipe management program when a comprehensive plant pipe management program is implemented based on the model analysis.

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Reductive Dissolution of Spinel-Type Iron Oxide by N2H4-Cu(I)-HNO3

  • Won, Hui Jun;Chang, Na On;Park, Sang Yoon;Kim, Seon Byeong
    • Journal of the Korean Ceramic Society
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    • v.56 no.4
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    • pp.387-393
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    • 2019
  • A N2H4-Cu(I)-HNO3 solution was used to dissolve magnetite powders and a simulated oxide film on Inconel 600. The addition of Cu(I) ions to N2H4-HNO3 increased the dissolution rate of magnetite, and the reaction rate was found to depend on the solution pH, temperature, and [N2H4]. The dissolution of magnetite in the N2H4-Cu(I)-HNO3 solution followed the contracting core law. This suggests that the complexes of [Cu+(N2H4)] formed in the solution increased the dissolution rate. The dissolution reaction is explained by the complex formation, adsorption of the complexes onto the surface ferric ions of magnetite, and the effective electron transfer from the complexes to ferric ions. The oxide film formed on Inconel 600 is satisfactorily dissolved through the successive iteration of oxidation and reductive dissolution steps.

Possible Protective Effects of Quercetin and Sodium Gluconate Against Colon Cancer Induction by Dimethylhydrazine in Mice

  • Saleem, TH;Attya, AM;Ahmed, EA;Ragab, SMM;Abdallah, MA Ali;Omar, HM
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.14
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    • pp.5823-5828
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    • 2015
  • Micronutrients in food have been found to have chemopreventive effects, supporting the conclusions from epidemiologie studies that consumption of fresh fruits and vegetables reduces cancer risk. The present study was carried out to evaluate the role of querctin (Q) and sodium gluconate (GNA) supplementation separately or in combination in ameliorating promotion of colon tumor development by dimethyl-hydrazine (DMH) in mice. Histopathological observation of colons in mice treated with DMH showed goblet cell dysplasia with inflammatory cell infiltration. This pathological finding was associated with significant alteration in oxidative stress markers in colon tissues and carcinoembryonic antigen (CEA) levels in plasma. Mice co-treated with GNA and Q showed mild changes of absorptive and goblet cells and inflammatory cell infiltration in lamina properia, with improvement in oxidative stress markers. In conclusion, findings of the present study indicate significant roles for reactive oxygen species (ROS) in pathogenesis of DMH-induced colon toxicity and initiation of colon cancer. Also, they suggest that Q, GNA or the combination of both have a positive beneficial effect against DMH induced colonic cancer induction in mice.

Study of Hydrazine-Bromine Reaction in Sulfuric Acid Media (히드라진과 브롬의 반응의 메카니즘에 관한연구)

  • Q. Won Choi;Byoung Bin Park
    • Journal of the Korean Chemical Society
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    • v.19 no.6
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    • pp.403-407
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    • 1975
  • The rate constant for the $N_2H_4-Br_2$ reaction has been measured in sulfuric acid media by direct mixing method and chronopotentiometric method. The former gave 105 mole-1 l sec-1 whereas the latter 103 mole-1 l sec-1. It has been inferred that the former represents the rate constant for $N_2H_4-Br_2$ {\rightarrow} $N_2H_2$ and the latter for $N_2H_2+Br_2$ {\rightarrow} X. When the concentrations of KBr and $H_2SO_4$ are both high, drastic reduction of rate constant has been observed.

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