• Title/Summary/Keyword: hydration time

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Effect of Alkali Activators on Early Compressive Strength of Blast-Furnace Slag Mortar (고로슬래그 모르타르의 초기 강도에 대한 알칼리자극제의 영향)

  • Moon, Han-Young;Shin, Dong-Gu
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.9 no.3
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    • pp.120-128
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    • 2005
  • In the construction industry, due to the cost rise of raw material for concrete, we have looked into recycling by-products which came from foundry. When using the Ground Granulated Blast-Furnace Slag(SG), it is good for enhancing the qualities of concrete such as reducing hydration heat, increasing fluidity, long-term strength and durability, but it has some problems : construction time is increased or the rotation rate of form is decreased due to low development of early strength. In this study, therefore, to enhance the early strength of SG mortar, we used some alkali activators(KOH, NaOH, $Na_2CO_3$, $Na_2SO_4$, water glass, $Ca(OH)_2$, alum. This paper deals with reacted products, setting time, heat evolution rate, flow and the strength development of SG cement mortar activated by alkali activators. From the results, if alkali activators were selected and added properly, SG is good for using as the materials of mortar and concrete.

Effects of H$_2$BO$_3$ on the Hydration of $C_4$A$_3$S Blended Rapid Hardign Cement (CSA계 혼합 시멘트 수화에 미치는 Boric Acid 의 영향)

  • Yoo, K.S.;Lee, K.H.;Kim, N.H.;Lee, Y.S.;Hun, K.H.;Lee, J.W.;Yim, Going
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.583-593
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    • 1998
  • The study was carried on the influence of {{{{ { {H }_{3 }BO }_{3 } }} for hydration of blended rapid hardening cement which was composed of {{{{ {{C }`_{4 } ^{ }A }_{3 } }} Adding {{{{ { {H }_{3 }BO }_{3 } }} to the mortar of blended rapid hardening cement delayed the setting time and increased the flow of the mortar. When {{{{ { {H }_{3 }BO }_{3 } }} added to the blended rapid hardening cement mono-sulfate was produced rather than ettringite and the existing time of monosulfate also prolonged. After hours monosulfate was converted to ettringite through being producted like gels. This monosulfate phase in-fluences on the setting time and flow of fresh mortar.

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Electro-mechanical impedance based strength monitoring technique for hydrating blended cements

  • Thirumalaiselvi, A.;Sasmal, Saptarshi
    • Smart Structures and Systems
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    • v.25 no.6
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    • pp.751-764
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    • 2020
  • Real-time monitoring of stiffness and strength in cement based system has received significant attention in past few decades owing to the development of advanced techniques. Also, use of environment friendly supplementary cementitious materials (SCM) in cement, though gaining huge interest, severely affect the strength gain especially in early ages. Continuous monitoring of strength- and stiffness- gain using an efficient technique will systematically facilitate to choose the suitable time of removal of formwork for structures made with SCM incorporated concrete. This paper presents a technique for monitoring the strength and stiffness evolution in hydrating fly ash blended cement systems using electro-mechanical impedance (EMI) based technique. It is important to observe that the slower pozzolanic reactivity of fly ash blended cement systems could be effectively tracked using the evolution of equivalent local stiffness of the hydrating medium. Strength prediction models are proposed for estimating the strength and stiffness of the fly ash cement system, where curing age (in terms of hours/days) and the percentage replacement of cement by fly ash are the parameters. Evaluation of strength as obtained from EMI characteristics is validated with the results from destructive compression test and also compared with the same obtained from commonly used ultrasonic wave velocity (UPV). Statistical error indices indicate that the EMI technique is capable of predicting the strength of fly ash blended cement system more accurate than that from UPV. Further, the correlations between stiffness- and strength- gain over the time of hydration are also established. From the study, it is found that EMI based method can be effectively used for monitoring of strength gain in the fly ash incorporated cement system during hardening.

Setting and Micro-structures of the Cement Pastes Using Sugar-Based Super Retarding Agents (당류계 초지연성 혼화제를 사용한 시멘트 페이스트의 응결 및 미시구조 특성)

  • Jeong, Yeong-Jin;Hyun, Seung-Yong;Han, Jun-Hui;Kim, Jong;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.703-714
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    • 2023
  • This research conducts a series of tests to investigate the setting retarding properties and strength development in cement pastes incorporating various types and dosages of sugar-based super retarding agents. Six such agents, including Sucrose, Sugar powder, Saccharin, Aspartame, Stevioside, and Mogroside, commercially available, were selected for evaluation. The study also examines the micro-structural properties of these cement pastes. The test mixtures were prepared using a 27.5% water-to-cement ratio and ordinary Portland cement. Micro-structural analyses were conducted using Scanning Electron Microscopy(SEM), X-Ray Diffraction(XRD), and Energy Dispersive Spectroscopy(EDS). The findings reveal that the incorporation of sucrose, sugar powder, and stevioside significantly retards the setting time. Particularly, adding 0.1% sucrose extended the setting time by approximately two-fold compared to the control(Plain) mixture. Most mixtures, barring those with sugar powder and stevioside, exhibited compressive strength comparable to the Plain mixture. Notably, with 0.2% sucrose, strength measurements were not feasible at 1 day, but at 3 days, the strength gains aligned with the Plain mixture. XRD, SEM, and EDS analyses confirmed the hydration delay(set retarding) of C3S due to sucrose, with further quantitative corroboration provided by EDS. SEM was used to verify the presence or absence of hydration products. The study concludes that sucrose, as a sugar-based retarder, offers effective set retarding capabilities and compressive strength development in concrete.

A Study on the Reduction of Kidney Uptake of 18F-FDG due to the Water Intake at the Time of Additional Examination in the PET/CT scan (PET/CT 검사에서 추가 검사 시 수분섭취에 따른 18F-FDG의 신장 섭취 감소에 대한 고찰)

  • Lee, Yi Lang;Kim, Sang Gyu;Ham, Jun Chul;Nam-Koong, Hyuk;Lim, Han Sang;Kim, Jae Sam
    • The Korean Journal of Nuclear Medicine Technology
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    • v.20 no.1
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    • pp.47-51
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    • 2016
  • Purpose By ingestion of 18F-FDG of kidney of PET/CT during the inspection, if additional examination is required, depending on whether you want to water intake, we want to confirm a change in the rate of decrease of F-18 FDG of the kidney. Materials and Methods The 80 patients without kidney disease were performed PET/CT examination. Device was analyzed after setting the kidney to a three-dimensional region of interest. In patients require additional examination, and inspection after 30 minutes, a PET/CT torso examination after the water of the 500 cc ingested at a time. After the addition of both water intake group and no hydration group of kidney of SUV, it was compared with PET/CT torso scan. Results High and low of the kidney SUV did not show a significant difference in the rate of decrease. Reduction rates of background (BKG) of additional examination was 2.8% and reduction rates of SUV was 49.7% (Hydration) : -6.8% (No hydration), so did show a significant difference. In the image blind test, the average point score of hydration and no hydration was 34.25 : 17.25. Conclusion An undercurrent of 18F-FDG in the kidney at the time of torso examination, it was confirmed that the reduction rate after the addition of water intake is high. It is considered that can be expected to improve the quality of an image due to a decrease in elongation through the kidneys examination with additional fluid intake as needed intake.

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A Study on the Factors Affecting the Strength of Alkali-Activated Slag Binders (알칼리 활성화 슬래그 결합재의 강도 발현 인자에 관한 연구)

  • Hwang, Byoung-Il;Kang, Suk-Pyo;Kim, Sang-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.2
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    • pp.130-137
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    • 2018
  • In the construction industry, research on alkali activated cement using fly ash or blast furnace slag fine powder has been published in Korea and abroad as a way to reuse industrial byproducts without using cement at all and to obtain economical effects at the same time. the purpose of this paper is to evaluate the effect of the ratio and coefficient of hydration ratio and lime saturation degree on the strength of alkali activated slag cement by chemical quantitative analysis of alkali activated slag cement used in the management of existing portland cement. as a result, it was confirmed that the ratio and coefficient of hydration ratio and lime saturation are all within a certain range.

Effect of Extracting Conditions on the Soluble Solid's Yield of Korean Red Ginseng (추출 조건이 홍미삼(紅尾蔘)의 가용성 물질의 용출률에 미치는 영향)

  • Sung, Hyun-Soon;Kim, Woo-Jung
    • Korean Journal of Food Science and Technology
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    • v.18 no.2
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    • pp.168-172
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    • 1986
  • The swelling and hydration properties of Korean red ginseng tails and yield of total solids in extract were studied during extraction with ethanol solution having a concentration of 0-90% at $60-100^{\circ}C$. Extraction was carried out 5 times which was taken 8 hours per each time of extraction. The swelling, hydration and total solids yield were increased as the ethanol concentration decreased and as the extraction temperature raised. The cumulative value of solids yield suggested that three times of extractions with water or 70% ethanol were effective to recover more than 84%. Linear regression analysis on the properties investigated and extraction conditions showed a linear logarithmic relationship .

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Prediction of thermal stress in concrete structures with various restraints using thermal stress device

  • Cha, Sang Lyul;Lee, Yun;An, Gyeong Hee;Kim, Jin Keun
    • Computers and Concrete
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    • v.17 no.2
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    • pp.173-188
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    • 2016
  • Generally, thermal stress induced by hydration heat causes cracking in mass concrete structures, requiring a thorough control during the construction. The prediction of the thermal stress is currently undertaken by means of numerical analysis despite its lack of reliability due to the properties of concrete varying over time. In this paper, a method for the prediction of thermal stress in concrete structures by adjusting thermal stress measured by a thermal stress device according to the degree of restraint is proposed to improve the prediction accuracy. The ratio of stress in concrete structures to stress under complete restraint is used as the degree of restraint. To consider the history of the degree of restraint, incremental stress is predicted by comparing the degree of restraint and the incremental stress obtained by the thermal stress device. Furthermore, the thermal stresses of wall and foundation predicted by the proposed method are compared to those obtained by numerical analysis. The thermal stresses obtained by the proposed method are similar to those obtained by the analysis for structures with internally as well as externally strong restraint. It is therefore concluded that the prediction of thermal stress for concrete structures with various boundary conditions using the proposed method is suggested to be accurate.

Pre-estimate on Structural Behavior and Cracks of Subway Wall Structures Using Gage Measurement (계측에 의한 지하철 박스구조물 벽체부의 균열 밑 구조거동 예측)

  • Kim, Young-Jin;Kim, Sang-Chel
    • Journal of the Korean Society for Railway
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    • v.9 no.6 s.37
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    • pp.657-663
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    • 2006
  • By measuring concrete temperature and strains of concrete and reinforcing bars throughout gages embedded and also by observing the crack occurrence, this study aims at the characteristics of structural behavior of subway wall structure in associate with concrete ages. The length of 23.5m, thickness of 2.0m of real subway custody line was selected as a representative structure and 7 thermocouples and 6 strain gages were installed to measure the behavior of wall structure. The results were compared and verified with analytical results using MIDAS in order to show their usefulness. It was found that only attachment of strain gages on the surface of reinforcing bars can figure out the timing of crack occurrence and hydration heat program is useful to estimate comparatively exact magnitudes of temperature. Since estimated time of crack occurrence throughout thermal stress analysis depends on the period of transferred thermal stress from concrete to reinforcing bars, however, cracks from naked eyes were identified later than analytical results. Cracks were observed first at the center of wall line and then to the end of line symmetrically.

Adsorption Behaviors of Transition Metal Ions Using the Poly(N,N'-bispalmitoyl-1, 12-diaza-3, 4;9,10-dibenzo-5,8-cyclopentadecane) in Aqueous Solution (수용액에서 Poly(N,N'-bispalmitoyl-1, 12-diaza-3, 4;9,10-dibenzo-5,8-cyclopentadecane)를 이용한 전이금속이온들의 흡착특성)

  • Shin, Young-Kook;Kwon, Soo Han;Kim, Hae Joong
    • Analytical Science and Technology
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    • v.9 no.4
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    • pp.406-410
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    • 1996
  • The adsorption behaviors of transition metal ions on the poly(N,N'-bispalmitoyl-1, 12-diaza-3, 4;9,10-dibenzo-5,8-cyclopentadecane) has been determined by adsorption process in aqueous solution. The order of concentration factor(CF) and the amount of adsorption were Cu(II)

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