• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2021년도 봄 학술논문 발표대회
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• pp.110-111
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• 2021

The eggshell is a type of bio-waste which is considered hazardous to the environment. In this research, the waste eggshell is utilized as a potential filler in cementitious material. This study has measured by zeta potential to analyze the interaction between the surface of the filler and the calcium ion in the solution. Meanwhile, the effect of eggshell powder on cement hydration process has been determined by isothermal calorimeter. The results show that the surface of eggshell powder have a strong adsorption of Ca2+, and addition of the eggshell powder provides a heterogeneous nucleation site for cement, which promotes the growth of hydration products.

• 한국임상수의학회지
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• 제18권3호
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• pp.206-210
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• 2001

피부질환에는 보조 치료로 다양한 치료용 샴푸가 빈번하게 적용되고 있으나 이들 샴푸의 피부수분에 미치는 영향은 일반적으로 평가되지 않고 있는 실정이다. 따라서 치료용 샴푸의 정확한 처방을 위해서는 피부의 수분을 측정하기 위한 측정법이 필요하다. 본 연구는 여러 종류의 치료용 샴푸의 피부 수분에 대한 영향을 알아보기 위해 Corneometer를 이용하여 피부에 샴푸를 적용후 수분을 측정하였다. 5두의 건강한 개를 대상으로 7가지 샴푸로 Humilac, Sebocalm, Sebolytics, Etiderm, Benzoyl peroxide, HyLyt, Zn-7 Derm를 선정하여 적용하였다. Humilac의 경우 통계학적으로 유의한 피부수분의 증가는 적용 후 17분(p<0.05), 77분(p<0.01)에 나타났으며, Benzoyl peroxide의 경우 적용 후 77분(p<0.05)에 피부의 수분이 유의하게 감소되었다. 다른 샴푸의 경우 통계학적으로 유의하지 않았으나 전반적으로 감소하는 경향을 보였으며 적용 후 77분에 최초 적용 수치에 근접하게 감소하였다. 어떤 샴푸도 피부에 부작용을 유발하지 않았다. Corneometer는 실제 임상에서 피부의 수분을 평가하는데 간단하고 유용한 측정방법을 사료된다.

• 콘크리트학회논문집
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• 제14권1호
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• pp.118-125
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• 2002

콘크리트는 수화과정을 통하여 재료가 성숙되고, 경화된다. 수화의 진행은 엄밀한 의미에서 재령에 의하지 않고 수화도에 의해 제어되므로, 경화가 진행되는 콘크리트의 모든 재료특성과 미세구조 형성과정은 수화도에 의해 정식화되는 것이 바람직하다. 기존 연구는 주로 양생온도가 수화발열속도에 미치는 영향을 고려한 반응함수 개념을 주로 사용하였고, 또한 내부 수분상태의 영향을 습도함수의 형태로 고려한 연구결과는 실제 수화기구를 반영하지 못하고 단지 각 연구자의 실험조건과 배합조건에만 부합하는 결과를 보인다. 따라서 본 연구는 기존 제안식의 단점을 보완하기 위하여 수화기구와 미세구조 형성 과정에 기초하여 반응속도함수를 모델링하였다. 수화반응속도는 온도 및 수분상태에 따라 변화하므로, 본 연구에서는 수화발열 속도에 영향을 미치는 인자로, 시멘트 종류, 물-시멘트비 등의 배합특성과 양생온도 빛 세공조직의 내부수분상태를 고려하였다. 똔 연구에서 제시한 콘크리트의 수화도 예측모델은 기존의 온도영향만을 주로 고려하는 반응속도함수를 콘크리트내부의 수분분포 상태를 고려하여 모델을 개선하였으며, 이는 실제 측정한 수화도에 매우 근접하여 그 유용성을 검증하였다. 또한 수화도의 정의와 제시한 모델을 이용하여 콘크리트 요소내의 온도, 습도 덴 수화도를 수치적으로 결정하여 단열온도상승곡선을 정확히 모사 할 수 있었다. 제안된 모델은 수화가 진행되는 콘크리트의 여러 역학적 특성 및 미세구조 형성과정을 적절히 표현하고, 수화과정이 온도 및 습도상태를 결정하는 초기재령 콘크리트의 단면 내 온 습도상태를 추정하여 궁극적으로 초기재령 콘크리트의 균열 위험성을 평가하는데 유용하게 이용될 수 있을 것으로 사료된다.

• 한국세라믹학회지
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• 제35권2호
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• pp.185-195
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• 1998

This experiment carried out in order to investigate the effect of the chemical activators for acceleration of hydration the system of Fly ash-Cao The paste was consisted of 80wt% Fly ash and 20wt% CaO with 1. 3. 5wt% of 4 activators(N{{{{ alpha _2 }}S{{{{ OMICRON _4 }}, CaC{{{{ {l }_{2 } }}, NaOH, Ca(N{{{{ OMICRON _3 {)}_{2 } }} and W/S ratio of 0.42 After curing for 1, 3, 7, 14, 28 days the paste hydration was characterized by the measurement of compressive strength XRD analysis SEM observation the combined water and the reaction amount of Ca(OH)2 determination. As a result of this ex-periment all of the system which involved Na2SO4 or NaOH had a god compressive strength. In the case of 7 days curing a system which added CaCl2 showed the highest compressive strength among all especially NaOH system showed a high increase in strength as a dosage of it increased. Hydration products were different according to activatores added. Only C-S-H was observed in NaOH system. As the reaction amount of Ca(OH)2 and combined water were increased the compressive strength increased. There were few differences in the comparision of strength between ignited loss 3.1% and loss 9.3% of fly ash.

• 한국세라믹학회지
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• 제34권8호
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• pp.861-869
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• 1997

In order to investigate the reaction in the system of anhydrite II-blast furnace slag, the paste hydration which made up with a liquid/solid ratio of 0.45 for 1, 3, 7, 14, 28days by the addition of accelerators to 10~30wt.% slag with natural gypsum calcined for 1hour at 500/$700^{\circ}C$ was studied by combined water determination, XRD, DTA, DSC and SEM. As a result of this experiment, it was found that hydration rate was faster in the system calcined at 50$0^{\circ}C$. Therefore the anhydrite was converted to calcium sulfate dihydrate in the hydration for 1day but the slag was not almost reacted. For the gypsum calcined at $700^{\circ}C$, the hydraton rate in the system of K2SO4 addition was faster than others in the earier period, but the activated effect of the system of Al2(SO4)3 addition was regarded as the highest over 3days. As the amount of slag was increased, they dydration rate was delayed and ettringite was observed in the case of K2SO4 system. However both Al2(SO4)3 and AlK(SO4)2 systems showed calcium sulfate dhydrate only as hydrated products.

• 한국농공학회:학술대회논문집
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• 한국농공학회 2000년도 학술발표회 발표논문집
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• pp.266-271
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• 2000

This study was performed to find out how much water the cement hydration reaction need. It is real situation that it is difficult to find out the amount of chemical combined water with stoichiometric chemical reaction form. Because several variation occurred during hydration reaction it's not easy to divide water which used at cement paste mixture. In this study high temperature(105$^{\circ}C$) dry method was used to divide evaporable water and non-evaporable water. The last is combined water chemically and some free water absorbed to products of hydration physically. The test was processed with variation of water cement ratio from 10% to 45% with 5% intervals. The weight of cement paste specimens were measured after dry for 72hours at each checking time(0.5, 1, 3, 5, 10, 24, 48, 72, 168hour). In this study some conclusions such as follows were derived. Firstly, Pure combined water contents required at cement hydration result in 23.3percent of the weight of cement. Secondly, The sufficient mixing water needed to fully hydrated cement result in about 40∼45percent of weight of cement. That is, gel pores water could be about 16.7∼21.7percent of weight of cement.

• Computers and Concrete
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• 제32권1호
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• pp.45-60
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• 2023

Concrete in water environment is easily subjected to the attack of leaching, which causes its mechanical reduction and durability deterioration, and the key to improving the leaching resistance of concrete is to increase the compaction of its microstructure formed by the curing. This paper performs a numerical investigation on the intrinsic relationship between microstructures formed by the hydration of cement and slag and leaching resistance of concrete in water environment. Firstly, a shrinking-core hydration model of blended cement and slag is presented, in which the interaction of hydration process of cement and slag is considered and the microstructure composition is characterized by the hydration products, solution composition and pore structure. Secondly, based on Fick's law and mass conservation law, a leaching model of hardened paste is proposed, in which the multi-species ionic diffusion equation and modified Gérard model are established, and the model is numerically solved by applying the finite difference method. Finally, two models are combined by microstructure composition to form an integrated curing-leaching model, and it is used to investigate the relationship between microstructure composition and leaching resistance of slag-blended cement pastes.

• 대한환경공학회지
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• 제27권12호
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• pp.1327-1331
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• 2005

본 연구에서는 해안연약지반의 현장토(준설점토)를 차수층에 이용하기 위해 첨가되는 고화재에 의한 수화열을 저감하기 위한 방안을 모색하고자 산업부산물로 년간 다량 배출되는 고로슬래그를 이용하였다. 실험결과, 고로슬래그를 첨가한 준설혼합토(준설점토 95% w+시멘트 5% w)의 경우 고화재에 의한 초기수화반응열을 저감하는 것으로 나타났는데 이는 불투수성인 aluminosilicate 피막이 고로슬래그의 표면을 코팅하였기 때문으로 판단된다. 따라서 고화재의 수화반응에 따른 수화열에 의해 발생될 수 있는 매립지 차수층의 미세균열을 산업부산물인 고로슬래그가 저감해 줄 수 있을 것으로 판단된다.

• 한국세라믹학회지
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• 제53권2호
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• pp.206-214
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• 2016

This study aims to produce dolomitic hydraulic lime (D-NHL) using domestic low grade dolomitic limestone and to determine the effect of adding blast furnace slag (BFS) and gypsum as part of an investigation of the hydration properties of D-NHL to increase the mechanical properties. The main mineral phases of D-NHL as a hydraulic lime binder were $Ca(OH)_2$, $Mg(OH)_2$, $C_2S$, $C_3S$, and MgO residues. $Ca(OH)_2$ transformed into $CaCO_3$ in D-NHL paste over the period of 28 days, but the carbonation of $Mg(OH)_2$ and the hydration of $C_2S$ did not occur until hydration, after 28 days. Through an investigation of the hydration properties of D-NHL pastes mixed with BFS and gypsum, Al-based compounds such as calcium aluminate hydrates ($C_4AH_{13}$) and ettringite were observed at early hydration time. The compressive strength was improved due to the increased quantities of these hydration products. These results show that good performance results from the application of dolomitic hydraulic lime and that a high value product can be made from domestic waste materials.

• Architectural research
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• 제15권1호
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• pp.53-58
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• 2013

High strength concrete is being used increasingly in mass structure projects. The purpose of this study is to investigate the influence of temperature during mixing, placing and curing on the strength development, hydration products and pore structures of high strength concrete in mass structures. The experiments were conducted with two different model walls, viz.: 1.5 m and 0.3 m under typical summer and winter weather conditions. The final part of this study deal with the clarification of the relationship between the long-term strength loss and the microstructure of the high strength concrete at high temperatures. Test results indicated that high elevated temperatures in mass concrete structures significantly accelerate the strength development of concrete at the early ages, while the long-term strength development is decreased. The long-term strength loss is caused by the decomposition of ettringite and increased the total porosity and amount of small pores.