• Title/Summary/Keyword: hydration of cement

Search Result 884, Processing Time 0.021 seconds

A Study on the Gradation Effect of the Property of Roller Compacted Concrete Pavement (골재 입도분포가 도로포장용 롤러전압 콘크리트에 미치는 영향 연구)

  • Song, Si Hoon;Lee, Seung Woo
    • International Journal of Highway Engineering
    • /
    • v.17 no.3
    • /
    • pp.49-58
    • /
    • 2015
  • PURPOSES : The use of environmentally friendly construction methods has been recently encouraged to reduce fuel consumption and the effects of global warming. For this purpose, the roller compacted concrete pavement (RCCP) construction method has been developed. RCCP is more environmentally friendly and economically efficient than general concrete by reducing the amount of CO2 generated through the application of a smaller amount of cement. RCCP has a number of advantages such as an easy construction method, low cost, high structural hydration performance, and aggregate interlocking. However, mix design standards and construction guidelines of RCCP are required for domestic application. In addition, a study on aggregate selection, which has an effect on the characteristics of RCCP, is necessary owing to a limited number of researches. Thus, the aggregate effect on the performance of RCCP in securing the required strength and workability was evaluated in consideration of domestic construction. METHODS : Sand and coarse aggregates of both 19mm and 13mm in maximum size were used in this study. Four types of aggregate gradations (s/a = 30%, 58%, and 70% for the sand and coarse aggregate of 19mm in maximum size, and s/a = 50% for a combination of the three types of aggregates) were set up to investigate the effects of the PCA band on the RCC characteristics. The conditions of s/a = 30% and 70% were evaluated to check the gradation effect outside of the recommended band. The conditions of s/a = 58% and 50% were used because they are the optimum combination of the two and three types of aggregates, respectively. RCCP gradation band was suggested gradation with a proper construction method of RCCP by synthetically comparing and analyzing the correlation of optimum water content, maximum dry density, and strength of requirements through its consistency and compaction test. RESULTS : The lower and upper limit lines are insufficient to secure a relatively strong development and workability compared to an aggregate gradation in the RCCP gradation band region. On the other hand, the line in the RCCP gradation band and the 0.45 power curve in the RCCP gradation band region were satisfactory, ensuring the required strength and workability. CONCLUSIONS : The suitable aggregate gradation on RCCP process should meet the RCCP gradation band area; however, fine particles passing through a #60 sieve do not need to be within the recommended gradation band because the influence of this region on such fine particles is small.

Experimental Study on Coefficient of Air Convection (외기대류계수에 관한 실험적 연구)

  • Jeon, Sang-Eun;Kim, Jin-Keun
    • Journal of the Korea Concrete Institute
    • /
    • v.15 no.2
    • /
    • pp.305-313
    • /
    • 2003
  • The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the coefficient of air convection, which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind and types of form. From experimental results, the coefficient of air convection was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent coefficient of air convection including effects of velocity of wind and types of form was theoretically proposed. The coefficient of air convection in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with types of form. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the coefficient of air convection by this model was well agreed with those by experimental results.

Reduction of pH of Recycled Fine Aggregate due to Natural and Artificial Treatment Method (자연 및 인위적 처리방법 변화에 따른 순환잔골재의 pH저감)

  • Han, Cheon-Goo;Han, Min-Cheol;Han, Sang-Yoon
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.6 no.1
    • /
    • pp.103-110
    • /
    • 2011
  • This study is to comparatively analyze the characteristics of pH decrease in recycled fine aggregates for embankment and landfill produced from waste concrete by using natural process and artificial process. The result was as follows In case of recycled fine aggregates left outdoor, it was found that pH level was decreased if the thickness of embankment becomes thinner, or the materials left outdoors owing to high concentration of $CO_2$ in atmosphere caused by respirations of people. When the air was permeated, pH level was decreased more effectively. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$ in the recycled fine aggregates owing to high-pressure ventilators. In case of water spraying treatment, sprayed water facilitated hydration of unhydrated cement to dissolve calcium hydroxides which neutralized $CO_2$ in the atmosphere during desiccation process and decrease pH level by a considerable margin. In case of Immersed treatment, decrease of pH was not sufficient. When facilitating the supply of $CO_2$, pH level of the recycled fine aggregates was decreased by the largest margin. It was analyzed that this phenomenon was caused by efficient supply of $CO_2$. From the above results, it was analyzed that the most effective method of reducing pH level of the recycled fine aggregates from the aspects of pH reduction performance, economic efficiency and workability was repeated wet-dry cycles of spraying water to the aggregates in the proportion of 1:0.5 by weight and then treating by forcefully blowing $CO_2$ gas into the aggregates.

  • PDF

Experimental Study on Improving Compressive Strength of MWCNT Reinforced Cementitious Composites (MWCNT 보강 시멘트 복합체의 압축강도 향상에 대한 실험적 연구)

  • Kang, Su-Tae;Park, Soon-Hong
    • Journal of the Korea Concrete Institute
    • /
    • v.26 no.1
    • /
    • pp.63-70
    • /
    • 2014
  • This experimental study was intended to improve the compressive strength of multi-walled CNT reinforced cementitious composites with efficiency. The variables considered are the degree of sonication, the amount of surfactant, the replacement ratio of silica fume, etc. Optical microscope informed that fiber dispersion of CNT was improved with the increase of sonication time, and the compressive strength was proved to be enhanced as the degree of sonication increased. When superplasticizer as a surfactant had SP/CNT ratio of 4~6, the best improvement in strength was obtained. Silica fume was shown to produce the highest compressive strength at 10% replacement. Microstructure of CNT composites was also analyzed; XRD and SEM results indicated that CNT addition hardly changed hydration products and microstructure, and MIP analysis found the reduction of total porosity as well as the increase of nano-pores with the size of tens of nm instead of the decrease of pore distribution in the region of around 10 ${\mu}m$ and 100 nm. The results of microstructure analysis explains that the strength improvement is closely related to physical contribution rather than chemical influence by adding CNT.

Optimum Mix Proportion of the High Strength and Self Compacting Concrete Used Above-Ground LNG Storage Tank (지상식 LNG 저장탱크용 고강도 자기충전 콘크리트의 최적배합에 관한 연구)

  • Kwon, Yeong-Ho
    • Journal of the Korea Concrete Institute
    • /
    • v.23 no.1
    • /
    • pp.99-107
    • /
    • 2011
  • This study is to performed to find the optimum mix proportion of the high strength and self compacting concrete for the above-ground LNG storage tank construction and field application. If LNG storage tank wall thicknesscan be reduced, the construction cost and quality can be improved by using self-compacting high strength concrete with compressive strength 60~80 MPa. For this purpose, low heat cement (Type IV) and class F fly ash are used in concrete mix to control hydration heat, flowability, and viscosity. Mix design variables of unit water, fly ash replacement ratio, water-binder ratio, and fine aggregate ratio are selected and tested for material properties and manufacturing cost of the concrete. Also, fly ash replacement ratio is considered using confined water ratio test. The test results showed that the optimum mix proportion of the self-compacting high strength concrete characteristics are as follows. 1) In case of the concrete with specified compressive strength of 60 MPa, the optimum mix proportion is fly ash replacement ratio of 20% and water- binder ratio of 27~30%. 2) In case of the concrete with the strength of 80 MPa, the optimum mix proportion is fly ash replacement ratio of 10% and water-binder ratio 25%. But unit water and fine aggregate ratio are 165 $kg/m^3$ and $51{\pm}2%$, respectively, regardless of the traget concrete compressive strength range. Also, test results showed that concrete manufacturing cost of 60 MPa and 80 MPa concrete require additional costs of 14~22% and 33%, respectively, compared to the manufacturing cost of 40 MPa concrete. Therefore, application of the self-compacting high strength concrete has proven to be economical in the perspective of the material cost, quality control, and site management.

A Study on Moisture Transport of Artificial Lightweight Concrete (인공경량골재 콘크리트의 수분이동 특성에 관한 연구)

  • Lee, Chang Soo;Choi, Sang Hyun;Park, Jong Hyok;Kim, Young Ook
    • KSCE Journal of Civil and Environmental Engineering Research
    • /
    • v.29 no.4A
    • /
    • pp.373-384
    • /
    • 2009
  • For the first step on the quantitative evaluation of shrinkage reduction and differential shrinkage analysis of lightweight aggregate concrete, this study sets the moisture transport model of concrete by pre-absorbed water of porous lightweight aggregates and measured effective moisture diffusion coefficient, moisture capacity, degree of humidity supply and degree of humidity consumption by water binder ratio and aggregate type. The effective moisture diffusion coefficient in steady state caused by humidity difference between inside and outside of concrete had low value as low water-binder ratio. And in case of same water-binder ratio, effective moisture diffusion of mixtures used normal aggregates were lower than those used lightweight aggregates. To determine moisture store capability of concrete - moisture capacity, moisture contents were measured in 9 humidity conditions. As a result moisture contents of mixtures used lightweight aggregates was higher than mixtures used normal aggregates in all humidity conditions. This study measured lightweight aggregates' degree of humidity supply that applicable to normal atmospheric environment (above RH 50%) and made it quantitatively. Also amount of moisture release was set as a exponential function that represents a clear trend proportion to time and inverse proportion to humidity of the surroundings. As the result of measurement about degree of moisture consumption inside concrete following the internal consumption caused by cement hydration self-drying, it was showed that rapid decrease of humidity, around 10%, at early ages (7~10 days) when water-binder ratio is 0.3 and slow decrease around 5% and 1% when water-binder ratio is 0.4 and 0.5.

The Self-healing and Ageing Effect of OPC-GGBFS Cement in Sea-water and Tap-water (해수와 담수에서 OPC-GGBFS 시멘트의 자기치유와 재령효과)

  • Kim, Tae-Wan;Kang, Choonghyun
    • Journal of the Korea Concrete Institute
    • /
    • v.29 no.1
    • /
    • pp.11-21
    • /
    • 2017
  • The paper presents experimental results of self-healing effects of OPC-GGBFS paste with cracked and uncracked specimens. The self-healing of cracked specimens is processes of crack closing with re-hydration of unhydrated in crack surface. The OPC paste with GGBFS replacement ratios of 0%, 10%, 20% and 30% were prepared having a constant water-binder ratios of 0.5. The OPC-GGBFS paste specimens immersed in tap-water and sea-water. The temperature of tap and sea-water was $5^{\circ}C$, $15^{\circ}C$ and $25^{\circ}C$. The cracked specimens after deterioration were immersed for 60 days. The relationship between self-healing effect and age-effect was calculate based upon the experimental results. The self-healing effect was measured in ultrasonic pulse velocity (UPV) before and after loading. When the relative change rate of UPV is increases with the increase in GGBFS replacement ratios. Moreover, the self-healing effect is increased with the temperature of tap-water is increase. But the cracked specimens immersed in sea-water was unclear effects of different temperature. Furemore, most of the healing for OPC-GGBFS specimens immersed in tap-water and sea-water occurred during the first 30 days. The self-healing effect until 30 days is higher than that the age-effect. After 30 days, self-effect and age-effect was largely decreases. SEM/EDS analysis of crack on the surface of the specimens in tap-water were covered with aragonite, and sea-water were covered with brucite.

Determination of Convection Heat Transfer Coefficient Considering Curing Condition, Ambient Temperature and Boiling Effect (양생조건·외기온도·비등효과를 고려한 콘크리트 외기대류계수의 결정)

  • Choi Myoung-Sung;Kim Yun-Yong;Woo Sang-Kyun;Kim Jin-Keun
    • Journal of the Korea Concrete Institute
    • /
    • v.17 no.4 s.88
    • /
    • pp.551-558
    • /
    • 2005
  • The setting and hardening of concrete is accompanied with nonlinear temperature distribution caused by development of hydration heat of cement. Especially at early ages, this nonlinear distribution has a large influence on the crack evolution. As a result, in order to predict the exact temperature history in concrete structures it is required to examine thermal properties of concrete. In this study, the convection heat transfer coefficient which presents thermal transfer between surface of concrete and air, was experimentally investigated with variables such as velocity of wind, curing condition and ambient temperature. At initial stage, the convection heat transfer coefficient is overestimated by the evaporation quantity. So it is essential to modify the thermal equilibrium considered with the boiling effect. From experimental results, the convection heat transfer coefficient was calculated using equations of thermal equilibrium. Finally, the prediction model for equivalent convection heat transfer coefficient including effects of velocity of wind, curing condition, ambient temperature and boiling effects was theoretically proposed. The convection heat transfer coefficient in the proposed model increases with velocity of wind, and its dependance on wind velocity is varied with curing condition. This tendency is due to a combined heat transfer system of conduction through form and convection to air. From comparison with experimental results, the convection heat transfer coefficient by this model was well agreed with those by experimental results.

An Experimental Study on the Mechanical Healing Properties of Self-Healing Mortar with Solid Capsules Using Crystal Growth Type Inorganic Materials (결정성장형 무기재료 활용 고상 캡슐을 혼합한 자기치유 모르타르의 역학적 치유 특성에 관한 실험적 연구)

  • Choi, Yun-Wang;Nam, Eun-Joon;Oh, Sung-Rok;Lee, Kwang-Myong
    • Journal of the Korean Recycled Construction Resources Institute
    • /
    • v.8 no.4
    • /
    • pp.581-589
    • /
    • 2020
  • In this paper, a solid capsule was prepared using a crystal growth type inorganic material capable of hydration reaction, the quality and mechanical healing properties of self-healing mortar with solid capsules were evaluated. Solid capsules were mixed 5% by mass of cement. Reloading test results of compressive load, it was found to improve about 20% on average for the natural healing effect of Plain, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Reload test results of flexural load, in the case of the elastic range, the healing rate was about 79% at the 7 days of healing age and 98% at the 28 days of healing age. Through these results, it is judged that the healing performance of solid capsules has also an effect on mechanical healing properties such as strength in addition to the durability properties obtained by the permeability test. Since the strength tends to decrease as the solid capsules are mixed, it is considered necessary to compensate.

Autogeneous Shrinkage Characteristics of Ultra High Performance Concrete (초고성능 콘크리트의 자기수축 특성)

  • Kim, Sung-Wook;Choi, Sung;Lee, Kwang-Myong;Park, Jung-Jun
    • Journal of the Korea Concrete Institute
    • /
    • v.23 no.3
    • /
    • pp.295-301
    • /
    • 2011
  • Recently, the use of UHPC made of superplasticizers, silica fume, and steel fibers has been increasing worldwide. Although UHPC has a very high strength as well as an excellent durability performance due to its dense microstructures, earlyage cracks may occur due to the high heat of hydration and autogenous shrinkage caused by low W/B and high unit cement content. The early-age shrinkage cracking of UHPC can be controlled by using the shrinkage reducers and expansive admixtures having autogenous shrinkage compensation effect. In this paper, ultrasonic pulse velocity of UHPC containing shrinkage reducers and expansive agents was measured to predict its stiffness change. Also, the effect of shrinkage reducers and expansive agents on the autogenous shinkage of UHPC was investigated through the shrinkage test of UHPC specimens. Furthermore, the material coefficients of autogenous shrinkage prediction model were determined using the autogenous shrinkage values of UHPC with age. Consequently, the test results showed that, by adding shrinkage reducers and expansive agents, the stiffness of UHPC was rapidly developed at early-ages and the autogenous shrinkage was considerably reduced.