• Title/Summary/Keyword: hydration characteristics

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Effects of Petrolatum and Glycerin on Acetone Damaged Canine Skin Barrier

  • Oh, Won-Seok;Oh, Tae-Ho
    • Journal of Veterinary Clinics
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    • v.25 no.6
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    • pp.466-470
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    • 2008
  • The purpose of this study is to investigate whether the effects of topically applied petrolatum and glycerin on the barrier repair of acetone-induced skin damage in 6 beagle dogs. To confirm the effects of petrolatum and glycerin on acetone disrupted skin models, we performed to evaluate the characteristics of transepidermal water loss and SC hydration and scanning electron microscopic observations. TEWL and SC hydration measurements were carried out 3, 6, 12, 24, 48h after applying petrolatum and glycerin during recovery from acute disruption. Our results showed that there were some different effects between petrolatum and glycerin on the acetone damaged skin such as barrier function repair process and SC hydration status. The results indicate that the significant improvement could be observed in glycerin apply more than petrolatum after acetone damages, and further study will be required.

Hydration Characteristics of Cement Paste Added Liquid and Neutralized Red Mud (액상 및 중화 레드머드를 첨가한 시멘트 페이스트의 수화특성)

  • Kang, Hye Ju;Kang, Suk Pyo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2020.11a
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    • pp.104-105
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    • 2020
  • Red mud is a highly alkaline waste by-product of the aluminum industry. Although recycling of red mud is being actively researched, a feasible technological solution has not been found yet. In this study, we propose that neutralization of red mud alkalinity could assist in its use as a construction material. Neutralized red mud ( pH 6-8) was prepared by adding sulfuric acid to liquefied red mud (pH 10-12). After adding liquid and neutralized red mud to the cement paste, the heat of hydration was measured. As a result of the experiment, the calorific value of the cement paste with liquid red mud was lowered and delayed compared to the cement paste with neutralized red mud.

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A Study on The Hydration Heat Characteristics of non-fired Hwangto Substituted Concrete (비소성 황토 치환 콘크리트의 수화열 발현 특성 고찰)

  • Park, Min-Han;Suh, Dong-Kyun;Lee, Yae-Chan;Kim, Gyu-Yong;Nam, Jeong-Soo;Lee, Tae-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2021.11a
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    • pp.34-35
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    • 2021
  • In this study, we compared and analyzed hydration heat of the Concrete(NC) and non-fired Hwangto Concrete(HT). The Concrete(NC) was based on the mix that showed 30, 45 MPa on compressive strength on 28th and Only cement was used to make it. and We substituted 30% of weight of unit cement to non-fired Hwangto to create non-fired Hwangto Concrete(HT).

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Hydration Characteristics and Synthesis of Hauyne-Belite Cement as Low Temperature Sintering Cementitious Materials

  • Park, Sang-Jin;Jeon, Se-Hoon;Kim, Kyung-Nam;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.55 no.3
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    • pp.224-229
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    • 2018
  • OPC production requires high calorific value and emits a large amount of $CO_2$ through decarbonation of limestone, accounting for about 7% of $CO_2$ emissions. To reduce $CO_2$ emissions during the Ordinary Portland Cement (OPC) production process, there is a method of reducing the consumption of cement or lower temperature calcination for OPC product. In this study, for energy consumption reduction, we prepared Hauyne-belite cement by calcination at a low temperature compared to that used for OPC and studied the early hydration properties of the synthesized Hauyne-belite cement. We set the ratios of Hauyne and belite to 8 : 2, 5 : 5 and 3 : 7. For the hydration properties of the synthesized Hauyne-belite cement, we tested heat of hydration of paste and the compressive strength of mortar, using XRD and SEM for analysis of hydrates. As for our results, the temperature for optimum synthesis of Hauyne-belite is $1,250^{\circ}C$. Compressive strength of synthesized Hauyne-belite cement is lower than that of OPC, but it is confirmed that compressive strength of synthesized Hauyne-belite cement with mixing in of some other materials can be similar to that of OPC.

The Effect of the Structural State of Silica on the Pozzolanic Reactivity (Silica의 형태가 Pozzolan 반응성에 미치는 영향)

  • 한기성
    • Journal of the Korean Ceramic Society
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    • v.11 no.1
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    • pp.10-18
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    • 1974
  • The hydration at $23^{\circ}C$ between $Ca(OH)_2$ and siliceous materials with various compositions of silica gel and quartz were studied in paste state, and also diatomite was empolyed as another form of silica. The effect of the structural state of silica on the pozzolanic reactivity was investigated by X-ray, DTA, electron microscopy, and chemical analysis. The results obtained were as follows. (1) The molar ratio of $Ca(OH)_2$ to silica gel(C/Sg) being changed in 0.49, 0.81 and 1.22, the free $Ca(OH)_2$ was disappeared within six hours, three days and two weeks respectively and ill-crystallized CSH(I) was formed. However, in the case fo molar ratio of C/Sg=2.45, almost lime was remained uncombinedly after twenty four weeks yet. (2) Though the molar ratio C/Sg of diatomite was 0.71, the hydration was stabilized at three weeks and the result exhibited very peculiar characteristics from silica gel. (3) Pozzolanic reactivity of quartz was negligible, but $\alpha$-cristobalite in diatomite showed appreciable reactivity. (4) The thermal curves showed the exothermic peaks in the range 830 to $930^{\circ}C$ and lower broad peaks at high temperature in the initial steps of hydration, transfered to lower temperature with sharp peaks by proceeding of hydration. (5) The samples containing more silica gel exhibited higher pozzolanic reactivity and martar strength, but the diatomite gave remarkable result for them and they were matched to the strength development rate.

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Hydration Characteristics of Coal-Fly Ash Containing High CaO Compound (CaO 화합물이 다량 함유된 비산재의 수화 특성에 관한 연구)

  • Sim, Jun-Soo;Lee, Ki-Gang;Kim, Yu-Taek;Kang, Seung-Ku
    • Journal of the Korean Ceramic Society
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    • v.49 no.2
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    • pp.185-190
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    • 2012
  • The purpose of this study was to examine a possibility that fly ash could be used as raw material for carbonation by conducting the experiment on magnetic separation and hydration of fly ash that contained a large amount of CaO composite. Wet magnetic separation experiment was performed to remove the component of magnetic substance that contained fly ash, which aimed at increasing the content of CaO in the non-magnetic domain. The selected fly ash was used for hydration experiment before the TG-DTA, XRF and XRD analyses were made to confirm the Ca component that could be carbonated. Then, the fly ash was turned to a hydrate that was favorable to dissociation of $Ca^{2+}$ ion. As a result, the magnetic separation enabled detecting the content of CaO component by up to 61 wt% in the non-magnetic domain. Since the hydrate was confirmed, it is believed that the fly ash can be used as raw material for carbonation.

Mechanical Properties of Cement Material for Energy-Foundation (EF) Structures

  • Park, Yong-Boo;Choi, Hang-Seok;Sohn, Jeong-Rak;Sim, Young-Jong;Lee, Chul-Ho
    • Land and Housing Review
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    • v.3 no.1
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    • pp.83-88
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    • 2012
  • In this study, physical characteristics of cement and/or concrete materials that are typically used for energy-foundation (EF) structures have been studied. The thermal conductivity and structural integrity of the cement-based materials were examined, which are commonly encountered in backfilling a vertical ground heat exchangers, cast-in-place concrete piles and concrete lining in tunnel. For this purpose the thermal conductivity and unconfined compression strength of cement-based materials with various curing conditions were experimentally estimated and compared. Hydration heat generated from massive concrete in the cast-in-place concrete energy pile was observed for 4 weeks to estimate its dissipation time in the underground. The hydration heat may mask the in-situ thermal response test (TRT) result performed in the cast-in-place concrete energy pile. It is concluded that at least two weeks are needed to dissipate the hydration heat in this case. In addition, a series of numerical analysis was performed to compare the effect of thermal property of the concrete material on the cast-in-place pile.

Effect of Superplasticizer on the Early Hydration Ordinary Potland Cement (고성능감수제가 시멘트 초기 수화에 미치는 영향)

  • Na, Seung-Hun;Kang, Hyun-Ju;Song, Young-Jin;Song, Myong-Shin
    • Journal of the Korean Ceramic Society
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    • v.47 no.5
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    • pp.387-393
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    • 2010
  • To improve concrete quality one of the most widely used chemical admixtures is polycarboxylate type superplasticizer. Unlike lignosulfonate and naphthalene-sulfonate, it has high dispersion property and excellent sustainable dispersion property for cement and concrete. Thus, polycarboxylate type superplasticizer has been widely used as a high-performance water reducing admixture together with silica fume in high-performance concrete and other applications for the dispersion of high-strength concrete over 100 MPa. However, even though there have been many studied on the dispersion of concrete by the structure of polycarboxylate type superplasticizer, there have a few studied that clarified the relationships between its rheological properties and microstructure properties in the early hydration behavior of ordinary portland cement. To investigate the correlations between the rheological properties and microstructure of cementitious materials with polycarboxylate type superplasticizer, this study experimented on the rheology, pore structure, heat evolution, and consistency in early hydration as well as on the compressive strength by early dispersion characteristics.

Characteristics of Facial Skin Surface According to Sasang Constitution Classification (사상체질에 따른 피부 표면 상태 분석)

  • Choi, Eun-Young
    • Proceedings of the KAIS Fall Conference
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    • 2010.11b
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    • pp.878-881
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    • 2010
  • For better diagnosis and prescription in Korean traditional medicine, Lee Je-Ma (1837-1900) created Sasang Constitution classification which was divided into four groups of Taeyangin, Soyangin, Taeumin and Soumin based on both body shape and natural disposition. The purpose of this study was to investigate the characteristics of facial skin parameters (hydration, lipid and pH) on forehead and cheek according to Sasang Constitution classifications of Taeumin, Soyangin and Soumin in Korean. Eighty-nine Korean female subjects were recruited for this study and the average age of them was 19.9${\pm}$0.84 years. The four groups by the Sasang Constitution were classified by questionnaire for the Sasang Constitution classification proposed by Kyung-Hee Oriental Medicine Hospital. Consequently, thirty-eight (42.7%) among the subjects were grouped into Soumin, twenty-nine (32.6%) into Taeumin, twenty (22.5%) into Soyangin and two (2%) into Taeyangin. Taeyangin group was excluded from statistical analysis due to small subjects. Hydration, lipid and pH parameters on forehead and cheek were measured by using non-invasive instruments of Corneometer (CM 825, Schwarzhaup, Germany), Sebumeter (SM 815, Schwarzhaup, Germany) and Skin-pH-meter (pH 905, Schwarzhaup, Germany), respectively. The measurements by the same investigator were performed under standardized condition with a room temperature of $21^{\circ}C$ and a humidity level of 40% to 50%. As a result, hydration (F=25.481, p=.000), lipid (F=5.753, p=.005) and pH (F=5.010, p=.009) of the forehead skin showed significant differences in the order of Taeumin, Soyangin and Soumin. Hydration (F=23.216, p=.000), lipid (F=6.898 p=.002) and pH (F=5.070, p=.008) of the cheek skin showed significant differences in the order of Taeumin, Soyangin and Soumin. In conclusion, facial skin surface seemed to be dependent on Sasang Constitution classification in Korean. These findings indicated that Sasang Constitution classification might be an useful esthetic treatment for caring facial skin in the future.

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The Hydration Characteristics of High-Durable Portland Cement Treated with Asphalt and Carbon Black (ASPHALT와 CARBON BLACK으로 처리(處理)된 고내구성(高耐久性) 포틀랜드시멘트의 수화특성(水化特性))

  • Cho, Heon-Young;Kim, Hee-Rack;Hong, Won-Pyo
    • Applied Chemistry for Engineering
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    • v.3 no.1
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    • pp.148-155
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    • 1992
  • For the enhancement of the concrete durability, we developed high - durable portland cement (ACTPC) by physical treatment of ordinary portland cement with asphalt and carbon black. In this research, the hydration reaction characteristics of ACTPC were studied by using SEM, X-Ray, Conduction Micro Calolimeter etc. When the ACTPC is mixed with water, it is believed the asphalt films on cement particles suppress the early stage of hydration reactions of cements, because the films hinder the contact with water and the elusion of soluble ions from particles. But the carbon blacks on the cement particles accelerated the hydration reactions of cement after a while, because the micro particles can be used as seed crystals in $CaO-SiO_2-H_2O$ gel formation.

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