• Title/Summary/Keyword: hydration

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The Solidification of the Heavy Metal Ion by Using DSP Cement (DSP 시멘트를 이용한 중금속 이온의 고화)

  • 소정섭;최상홀
    • Journal of the Korean Ceramic Society
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    • v.33 no.8
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    • pp.889-894
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    • 1996
  • This study was subjected to the stabilization of heavy metals using DSp cement. Heavy metal Cr and Pb ions were mixed with cement paste and hydration behavior and leaching property by heavy metal were exami-ned. It was found that, Cr ion accelerated the early hydration of the cement and has no accelerating effect in later hydration period. However Pb ion retarded the hydration of the cement for a early hydration periods. As a result of leaching test the quantity of leachant has a very low value and the influence of leached heavy metal effected on the environments is very weak.

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Effects of Salts on the Hydration of $\alpha$-Calcium Sulfate Hemihydrate ($\alpha$형 반수석고의 수화에 미치는 염류의 영향)

  • 최상흘;이구종;홍성윤;이석곤
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.449-454
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    • 1988
  • The effects of salts which was used as a catalysis in formation of $\alpha$-calciumusulfate hemihydrate from dicalcium sulfate hydrate were investigated on the hydration of $\alpha$-calciumsulfate hemihydrate. The hydration of $\alpha$-calciumsulfate hemihydrate was studied by the measurements of crystalline water, heat evolution. Also the hydrates were analyzed by XRD, DSC and SEM. The promotive effect each salts on the hydration was as follows: NaCl>NH4Cl>NaNO3>NH4NO3, and the hydration rate was accelerated with concentration of salts. The effect of Al2(SO4)3 and potassium sodium tartrate on the hydration was slmilar to water, whereas sodium succinate and gelatin retarded the hydration in comparision with water. These salts affected the hydration time but total heat evoution was similar.

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A Hydration Model for Blended Concrete utilizing Secondary Cementitious Powders (혼화재를 사용한 콘크리트의 수화모델)

  • Noh Jea Myoung;Byun Keun Joo;Song Ha-Won
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.05a
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    • pp.140-143
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    • 2004
  • Heat of hydration of concrete under different curing temperatures can be characterized with knowledge of the thermal activity, the heat rate at the reference temperature, and the total heat of hydration of the mixture. The so-called multi-component hydration model incorporates the effect of following variables: cement chemical composition, cement fineness, secondary cementitious powders, mixture proportions, and concrete properties. However, the model does not consider the use of silica fume as a secondary cementitious powder. Therefore, the model that quantifies the heat of hydration due to the use of silica fume is needed. In this thesis, the effects of silica fume on heat of hydration are evaluated and the influence on the heat of hydration are also quantified to be included in the model, so that the analysis using modified multi-component hydration model for silica fume concrete provides more accurate results than normal concrete.

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The simulation of hydration of Portland cement blended with chemical inert filler

  • Xiaoyong, Wang;Lee, Han-Seung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1041-1044
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    • 2008
  • The addition of chemical inert filler in blended cement, such as limestone or chemical inert silica fume, will produce a physical effect on cement hydration. Due to the high surface area of inert filler in the mixtures, it provides sites for the nucleation and growth of hydration products, thus improving the hydration rate of cement compounds and consequently increasing the strength at early age. This paper proposes a model of hydration of Portland cement blended with chemical inert filler. This model considers the influence of water to cement ratio, cement particle size, cement composition and addition of chemical inert filler on hydration. The heat evolution, degree of hydration and porosity are obtained as accompanied results in hydration process. The prediction results agree well with experiment results.

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The Characteristics of Hydration Heat Generation of Low Heat Concrete using Hydration Heat Reducing Admixtures (분말형 수화열저감재를 사용한 저발열 콘크리트의 수화발열 특성)

  • Kim, Yong-Ro;Jung, Yang-Hee;Lee, Sang-Ho;Kim, Do-Su;Khil, Bae-Su;Kim, Won-Ki
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.709-712
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    • 2006
  • It is necessary to develop a new technology for controling thermal cracking by hydration heat according to the increase construction of massive concrete structures, high strength concrete and early strength concrete. Therefore, it was investigated the characteristics of hydration heat generation of low heat concrete using hydration heat reducing admixtures in this study. To investigate the performance of hydration heat reducing admixtures, it was evaluated hydration heat according to the kind and replacement ratio of phase change material series I, II and the way of using hydration heat reducing admixtures in series III.

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Degree of hydration-based thermal stress analysis of large-size CFST incorporating creep

  • Xie, Jinbao;Sun, Jianyuan;Bai, Zhizhou
    • Steel and Composite Structures
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    • v.45 no.2
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    • pp.263-279
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    • 2022
  • With the span and arch rib size of concrete-filled steel tube (CFST) arch bridges increase, the hydration heat of pumped mass concrete inside large-size steel tube causes a significant temperature variation, leading to a risk of thermal stress-induced cracking during construction. In order to tackle this phenomenon, a hydration heat conduction model based on hydration degree was established through a nonlinear temperature analysis incorporating an exothermic hydration process to obtain the temperature field of large-size CFST. Subsequently, based on the evolution of elastic modulus based on hydration degree and early-age creep rectification, the finite element model (FEM) model and analytical study were respectively adopted to investigate the variation of the thermal stress of CFST during hydration heat release, and reasonable agreement between the results of two methods is found. Finally, a comparative study of the thermal stress with and without considering early-age creep was conducted.

Mathematical Modeling of Degree of Hydration and Adiabatic Temperature Rise (콘크리트의 수화도 및 단열온도상승량 예측모델 개발)

  • 차수원
    • Journal of the Korea Concrete Institute
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    • v.14 no.1
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    • pp.118-125
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    • 2002
  • Hydration is the main reason for the growth of the material properties. An exact parameter to control the chemical and physical process is not the time, but the degree of hydration. Therefore, it is reasonable that development of all material properties and the formation of microstructure should be formulated in terms of degree of hydration. Mathematical formulation of degree of hydration is based on combination of reaction rate functions. The effect of moisture conditions as well as temperature on the rate of reaction is considered in the degree of hydration model. This effect is subdivided into two contributions: water shortage and water distribution. The former is associated with the effect of W/C ratio on the progress of hydration. The water needed for progress of hydration do not exist and there is not enough space for the reaction products to form. The tatter is associated with the effect of free capillary water distribution in the pore system. Physically absorption layer does not contribute to progress of hydration and only free water is available for further hydration. In this study, the effects of chemical composition of cement, W/C ratio, temperature, and moisture conditions on the degree of hydration are considered. Parameters that can be used to indicate or approximate the real degree of hydration are liberated heat of hydration, amount of chemically bound water, and chemical shrinkage, etc. Thus, the degree of heat liberation and adiabatic temperature rise could be determined by prediction of degree of hydration.

A Study on the Effect of Admixture Types and Replacement Ratio on Hydration Heat Reduction of High-Strength Concrete (고강도 콘크리트의 수화열 저감에 미치는 혼화재 종류 및 대체율의 영향에 관한 연구)

  • Kim, Moo-Han;Choi, Se-Jin;Oh, Si-Duk;Kim, Yong-Ro;Lee, Jong-Ho
    • Journal of the Korea Institute of Building Construction
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    • v.2 no.2
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    • pp.145-150
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    • 2002
  • The hydration of cement paste occurs when the cement is miked with water. During the hydration, hydration heat causes the thermal stress depending on the site of concrete and the cement content. Especially in the high-strength concrete, we must give care to the concrete due to its large cement content. In this study conduction calorimeter and concrete insulation hydration heat meter were used to investigation the hydration heat characteristics of cement and concrete. To reduce hydration heat of high-strength concrete, several types of replacement of fly-ash and blast-furnace slag powder were used in this experiment. As a result of this study, it was found that hydration heat of high-strength concrete was reduced by replacement of fly-ash and blast-furnace slag powder. In case of high-strength concrete using blast-furnace slag powder, the max-heat arrival time was delayed but an effect of heat reduction was lower than a case of high-strength concrete using fly-ash, because it was considered that the heat-dependence property of blast-furnace slag powder was higher than that of fly-ash.

The Correlation Analysis of Fluid Intake, Skin Hydration and Skin pH of College Students (대학생의 수분섭취, 피부 수분보유도 및 피부 pH와의 관계)

  • Kim, Nam-Jo;Hong, Hae Sook
    • Journal of Korean Biological Nursing Science
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    • v.17 no.2
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    • pp.132-139
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    • 2015
  • Purpose: The purpose of this study was to verify the correlation analysis between fluid intake on skin hydration and pH of college students. Methods: The subjects were 129 female nursing students in D city. Data were collected by a self-administered questionnaire, using a skin moisture checker and skin pH meter on faces, hands, and feet. The collected data were analyzed by descriptive statistics, t-test, ANOVA, and Pearson correlation analysis, using SPSS WIN, 20. Results: The daily fluid intake was composed of 57% pure water, 21% caffeinated beverages, 22% non-caffeinated beverages. There were significant differences in average skin hydration on the three body parts according to pure water, caffeinated beverages, and non-caffeinated beverages; however, there was no significant difference measured by fluid intake. There was a significant positive correlation between fluid intake and skin hydration: between pure water and skin hydration. There was significant negative correlation between caffeinated beverages and skin hydration: between non-caffeinated beverages and skin hydration. Conclusion: The results suggest that fluid intake, pure water, caffeinated beverages, and non-caffeinated beverages have an effect on skin hydration and pH. Therefore, it is good to increase the amount of fluid intake but, it is recommended to increase the amount of intake of pure water rather than beverages to improve skin status.

Dispersion Effect of Hydration Heat in Mass Concrete Using Embedded Heat Pipe (매입형 히트파이프를 이용한 매스콘크리트 수화열 분산 효과)

  • Kim, Myung-Sik;Youm, Chi-Sun;Baek, Dong-Il
    • Journal of Ocean Engineering and Technology
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    • v.23 no.4
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    • pp.85-90
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    • 2009
  • Although most of existing hydration heat control methods show a certain degree of hydration heat control, generally, there are many problems as mentioned above. Therefore, our laboratory previously developed a hydration heat control method using an exposed heat pipe, which solves most of these problems and simultaneously displays excellent hydration heat control. Unfortunately, even this method had some problems such as the processing, transport, and assembly of heat pipes, and the surface treatment of a cut plane after pouring, and hardening concrete. Therefore, in this study, a hydration heat control method using an embedded pipe has been developed with the expectation that this method solves those problems in hydration heat control using an exposed heat pipe. As a result of the experiment, the peak temperature of ECHP and ICHP specimen about $4.5{\sim}6.5^{\circ}C$ than the OPC specimen and the probability of thermal cracked generated in ECHP and ICHP specimen decreased up to $13{\sim}20%$. Finally, it was confirmed in this study that the hydration heat control method using an embedded heat pipe is significantly more superior and cost effective than the existing method of an exposed one.