• 한국표면공학회지
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• 제42권6호
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• pp.287-293
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• 2009

The passivation films with epoxy layer on LiF, $SiN_x$ and LiF/$SiN_x$ inorganic layer were fabricated on OLED to protect device from the direct damage of $O_2$ and $H_2O$ and to apply for a buffer layer between OLED device and passivation multi-layer with organic/inorganic hybrid structure as to diminish the thermal stress and expansion. Red OLED doped with 1 vol.% Rubrene in $Alq_3$ was used as a basic device. The device structure was multi-layer of ITO(150 nm) / ELM200_HIL(50 nm) / ELM002_HTL(30 nm) / $Alq_3$: 1 vol.% Rubrene(30 nm) / $Alq_3$(30 nm) / LiF(0.7 nm) / Al(100 nm). LiF/epoxy applied as a protective layer didn't contribute to the improvement of life time. While in case of $SiN_x$/epoxy, damage was done in the passivation process because of difference in heat expansion between films which could occur during the formation of epoxy film. Using LiF/$SiN_x$/epoxy improved lifetime significantly without suffering damage in the process of forming films, therefore, the best structure of passivation film with inorganic/epoxy layers was LiF/$SiN_x$/E1.

• 한국표면공학회지
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• 제45권1호
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• pp.20-24
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• 2012

Multilayer passivation film on OLED with organic/inorganic hybrid structure as to diminish the thermal stress and expansion was researched to protect device from the direct damage of $O_2$ and $H_2O$ and improve life time characteristics. Red OLED doped with 1 vol.% Rubrene in $Alq_3$ was used as a basic device. The films consist of ITO(150 nm)/ELM200_HIL(50 nm)/ELM002_HTL(30 nm)/$Alq_3$: 1 vol.% Rubrene(30 nm)/$Alq_3$(30 nm) and LiF(0.7 nm)/Al(100 nm) which were formed in that order. Using LiF/$SiN_x$ as a buffer layer was determined because it significantly improved life time characteristics without suffering damage in the process of forming passivation film. Multilayer passivation film on buffer layer didn't produce much change in current efficiency, while the half life time at 1,000 $cd/m^2$ of OLED/LiF/$SiN_x$/E1/$SiN_x$ was 710 hours which showed about 1.5 times longer than OLED/LiF/$SiN_x$/E1 with 498 hours. futhermore, OLED/LiF/$SiN_x$/E1/$SiN_x$/E1/$SiN_x$ with 1301 hours showed about twice than OLED/LiF/$SiN_x$/E1/$SiN_x$ which demonstrated that superior characteristics of life time was obtained in multilayer passivation film. Through the above result, it was suggested using LiF/$SiN_x$ as a buffer layer could reduce the damage from the difference of thermal expansion coefficient in OLED with protective films, and epoxy layer in multilayer passivation film could function like a buffer between $SiN_x$ inorganic layers with relatively large thermal stress.

• Composites Research
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• 제19권1호
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• pp.9-14
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• 2006

본 연구는 KS F 2278 2003 (창호의 단열성 시험 방법)에 의하여 철도차량 및 버스의 내/외장재로 적용 가능한 카본/에폭시 스킨-알루미늄 하니콤 & 발사코어 샌드위치 판넬(두께 : 37mm), 카본/에폭시 스킨-알루미늄 하니콤 코어 샌드위치 판넬(두께 : 57mm, 단열재 포함) 및 카본/에폭시 스킨-알루미늄 하니콤 코어 샌드위치 판넬(두께 : 37mm)에 대한 열관류율 시험을 하였다. 또한 KS F2277 . 2002 (건축용 구성재의 단열성 측정방법-교정열상자법 및 보호열상자법)에 의하여 추가로 알루미늄 스킨-알류미늄 하니콤 샌드위치 판넬들 (두께 : 27mm, 35n1m)과 알루미늄 스킨-포밍 알루미늄 샌드위치 판넬 (두께27mm)에 대한 열관류율 시험을 수행하였다. 본 연구를 통해 면제와 심재사이에 열전달은 실제 단면적이 넓을수록 열관류율이 높았으며, 하이브리드형 복합재 일수록 단열성능이 우수함을 확인하였다.