• 제목/요약/키워드: hybrid materials

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부직포를 이용한 하이브리드 복합재료의 개발 (On the Development of Hybrid Composites with Non-Woven Tissue)

  • 이승환;노구찌히로시;정성균
    • Composites Research
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    • 제19권2호
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    • pp.20-27
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    • 2006
  • 부직포를 이용한 하이브리드 복합재료는 일반적인 섬유강화 적층복합재료의 기계적 특성을 개선하기 위하여 개발되었다. 부직포 하이브리드 프리프레그는 전형적 FRP 프리프레그와 부직포 프리프레그로 이루어전 있다. 부직포 프리프레그는 부직포와 수지의 조합에 의해 만들어진다. 부직포는 단섬유가 평면상에 불규칙적으로 분산되어 배치된 형상이다. 부직포를 이용한 하이브리드 프리프레그의 개발목적은 (i) 적층간의 층간특성(층간파괴인성 및 층간강도)을 향상시키고, (ii) 저비용으로 재료의 기계적 강도에 대한 신뢰성을 개선하며, (iii) 복합적층판에서 강화가 요구되는 층에 인성과 강도를 부여함에 있다. 상기의 목적을 달성하기 위하여 부직포층의 기포를 감소시키기 위한 제조기술을 제안하였다. 그 결과, 부직포를 이용한 하이브리드 개념을 도입함으로써 복합적층판의 층간파손특성이 크게 개선되었다.

졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성 (An Experimental Study on the Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials by A Sol-Gel Process)

  • 한흥구;공호성;윤의성;양승호
    • 한국윤활학회:학술대회논문집
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    • 한국윤활학회 2002년도 제35회 춘계학술대회
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    • pp.215-225
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several combinations of metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), $titaniumisopropoxide(Ti(Opr^{j})_{4})$, $zirconiumisopropoxide(Zr(Opr^{j})_{4})$ and $aluminumbutoxide(Al(Obu^{t})_{4})$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively, in this work. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribe-tester where a reciprocating steel ball slid on a test material, and the tribological property was also evaluated with respect to both heat-curing temperature and tile time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher heat-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that it was caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C$.

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Influence of a silane coupling agent on the optoelectrical properties of carbon nanotube/binder hybrid thin films

  • Han, Joong-Tark;Woo, Jong-Seok;Jeong, Hee-Jin;Jeong, Seung-Yol;Lee, Geon-Woong
    • Carbon letters
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    • 제12권2호
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    • pp.90-94
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    • 2011
  • We present the effect of a coupling agent on the optoelectrical properties of few-walled carbon nanotube (FWCNT)/epoxy resin hybrid films fabricated on glass substrates. The FWCNT/epoxy resin mixture solution was successfully prepared by the direct mixing of a $HNO_3$-treated FWCNT solution and epoxy resin. FWCNT/binder hybrid films containing different amounts of the coupling agent were then fabricated on UV-ozone-treated glass substrates. To determine the critical binder content ($X_c$), the effects of varying the binder content in the FWCNT/silane hybrid films on their optoelectrical properties were investigated. In this system, the $X_c$ value was approximately 75 wt%. It was found that above $X_c$, the coupling agent effectively decreased the sheet resistance of the films. From microscopy images, it was observed that by adding the coupling agent, more uniform FWCNT/binder films were formed.

졸-겔 공정에 의한 유기변성 하이브리드 세라믹 물질의 미세 마찰마모 특성 (Micro Friction and Wear Characteristics of Organically Modified Hybrid Ceramic Materials Synthesized by A Sol-Gel Process)

  • 한흥구;공호성;윤의성;양승호
    • Tribology and Lubricants
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    • 제18권5호
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    • pp.324-332
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    • 2002
  • In order to enhance the thermal stability of binder materials of bonded type solid lubricants, several metal-alkoxide based sol-gel materials such as methyltrimethoxysilane(MTMOS), titaniumisopropoxide$(Ti(Opr^i)_4),$ zirconiumisopropoxide $(Zr(Opr^i)_4)$ and aluminumbutoxide$(Al(Obu^t)_4)$ were chemically modified by epoxy-, acrylic- and fluoro-silane compounds, respectively. Friction and wear characteristics of these hybrid ceramic materials were tested with a micro tribo-tester, and evaluated with respect to both heat-curing temperature and the time. Test results generally showed that hybrid ceramic materials modified by epoxy-silane compounds had a low friction compared to others. And the higher het-curing temperature and the longer heat treatment time resulted in the higher friction and the lower wear. IR spectroscopic analyses revealed that these results were caused mainly by the increased metal oxide content in hybrid ceramics when the heat-curing temperature was over $320^{\circ}C.$

Processing of Polyurethane/polystyrene Hybrid Foam and Numerical Simulation

  • Lee, Won Ho;Lee, Seok Won;Kang, Tae Jin;Chung, Kwansoo;Youn, Jae Ryoun
    • Fibers and Polymers
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    • 제3권4호
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    • pp.159-168
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    • 2002
  • Polyurethane foams were produced by using a homogenizer as a mixing equipment. Effects of stirring speed on the foam structure were investigated with SEM observations. Variation of the bubble size, density of the foam, compressive strength, and thermal conductivity were studied. A hybrid foam consisting of polyurethane foam and commercial polystyrene foam is produced. Mechanical and thermal properties of the hybrid foam were compared with those of pure polyurethane foam. Advancement of flow front during mold filling was observed by using a digital camcorder. Four types of mold geometry were used for mold filling experiments. Flow during mold filling was analyzed by using a two-dimensional control volume finite element method. Variation of foam density with respect to time was experimentally measured. Creeping flow, uniform density, uniform conversion, and uniform temperature were assumed for the numerical simulation. It was assumed for the numerical analysis that the cavity has thin planar geometry and the viscosity is constant. The theoretical predictions were compared with the experimental results and showed good agreement.

Fabrication and Characterization of Carbon Nanotube/Carbon Fiber/Polycarbonate Multiscale Hybrid Composites

  • Cho, Beom-Gon;Hwang, Sang-Ha;Park, Young-Bin
    • Composites Research
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    • 제29권5호
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    • pp.269-275
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    • 2016
  • Multiscale hybrid composites, which consist of polymeric resins, microscale fibers and nanoscale reinforcements, have drawn significant attention in the field of advanced, high-performance materials. Despite their advantages, multiscale hybrid composites show challenges associated with nanomaterial dispersion, viscosity, interfacial bonding and load transfer, and orientation control. In this paper, carbon nanotube(CNT)/carbon fiber(CF)/polycarbonate(PC) multiscale hybrid composite were fabricated by a solution process to overcome the difficulties associated with controlling the melt viscosity of thermoplastic resins. The dependence of CNT loading was studied by varying the method to add CNTs, i.e., impregnation of CF with CNT/PC/solvent solution and impregnation of CNT-coated CF with PC/solvent solution. In addition, hybrid composites were fabricated through surfactant-aided CNT dispersion followed by vacuum filtration. The morphologies of the surfaces of hybrid composites, as analyzed by scanning electron microscopy, revealed the quality of PC impregnation depends on the processing method. Dynamic mechanical analysis was performed to evaluate their mechanical performance. It was analyzed that if the position of the value of tan ${\delta}$ is closer to the ideal line, the adhesion between polymer and carbon fiber is stronger. The effect of mechanical interlocking has a great influence on the dynamic mechanical properties of the composites with CNT-coated CF, which indicates that coating CF with CNTs is a suitable method to fabricate CNT/CF/PC hybrid composites.

유리/케블라 하이브리드 구조로 강화된 복합재료의 충격 거동 (Impact Properties of Glass/Kevlar Hybrid Composites)

  • 주기호;류한선;정관수;강태진
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 춘계학술발표대회 논문집
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    • pp.191-194
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    • 2005
  • Impact properties of glass/Kevlar hybrid composites which have 3-D braided structures were studied. Results were compared to those of composites made of only glass fibers where the same epoxy resin were used as matrix. Absorbed impact energies evaluated through the combination of the data from the impact tester and high speed camera were compared to each other. In order to see the difference between the damaged area distribution CCD camera captures were performed.

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하이브리드 삼차원 브레이딩 복합재료의 기하학적 모델링 (Geometrical Modeling for Hybrid 3-D Braided Composites)

  • 한문희;강태진;윤재륜
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2003년도 추계학술발표대회 논문집
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    • pp.67-70
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    • 2003
  • To develop an effective geometric modeling is essential in order that precise mechanical properties and the geometrical properties of the 3-D braided composites can be estimated. RVE(representative volume element) was adopted fur geometrical modeling. RVE consisted of IC(inner unit cell), ISUC(interior surface unit cell) and ESUC(exterior surface unit cell). The whole geometrical model fur hybrid 3-D braided composites was developed.

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Low-Loss Multimode Waveguides Using Organic-Inorganic Hybrid Materials

  • Yoon, Keun-Byoung
    • Macromolecular Research
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    • 제12권3호
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    • pp.290-292
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    • 2004
  • Multimode channel waveguides were fabricated using a direct UV patterning technology from thick films deposited by the one-step dip-coating of an organic/inorganic hybrid material (ORMOCER(equation omitted). The core size of the covered ridge waveguide was 43${\times}$51 $\mu\textrm{m}$$^2$; the waveguides can be readily prepared for multimode applications by direct UV patterning. The waveguides exhibited smooth surface profiles and a low optical loss of 0.07 ㏈/cm at the most important wavelength (850nm) used for optical interconnects.

철계 연자성 분말용 하이브리드 절연 코팅막 개발 (Development of Hybrid Insulating Coating for Fe-based Soft Magnetic Powder)

  • 김정준;김선겸;김영균;장태석;김휘준;김용진;최현주
    • 한국분말재료학회지
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    • 제28권3호
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    • pp.233-238
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    • 2021
  • Iron-based amorphous powder attracts increasing attention because of its excellent soft magnetic properties and low iron loss at high frequencies. The development of an insulating layer on the surface of the amorphous soft magnetic powder is important for minimizing the eddy current loss and enhancing the energy efficiency of high-frequency devices by further increasing the electrical resistivity of the cores. In this study, a hybrid insulating coating layer is investigated to compensate for the limitations of monolithic organic or inorganic coating layers. Fe2O3 nanoparticles are added to the flexible silicon-based epoxy layer to prevent magnetic dilution; in addition TiO2 nanoparticles are added to enhance the mechanical durability of the coating layer. In the hybrid coating layer with optimal composition, the decrease in magnetic permeability and saturation magnetization is suppressed.