• Korean Journal of Materials Research
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• v.13 no.11
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• pp.737-741
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• 2003

Polycrystalline $Ti_{l-x}$ $Co_{x}$ $O_2$thin films on $SiO_2$ (200 nm)/Si (100) substrates were prepared using liquid-delivery metalorganic chemical vapor deposition. Microstructures and ferromagnetic properties were investigated as a function of doped Co concentration. Ferromagnetic behaviors of polycrystalline films were observed at room temperature, and the magnetic and structural properties strongly depended on the Co distribution, which varied widely with doped Co concentration. The annealed $Ti_{l-x}$ $Co_{x}$ $O_2$thin films with $x\leq$0.05 showed a homogeneous structure without any clusters, and pure ferromagnetic properties of thin films are only attributed to the X$l-x_{l-x}$ $Co_{x}$X$O_2$phases. On the other hand, in case of thin films above x = 0.05, Co-rich clusters formed in a homogeneous $Ti_{l-x}$ $Co_{x}$ $O_2$phase, and the overall ferromagnetic (FM) properties depended on both FMTCO and FMCo. Co-rich clusters with about 10-150 nm size decreased the value of Mr (the remanent magnetization) and increased the saturation magnetic field.

• Korean Journal of Materials Research
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• v.23 no.7
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• pp.392-398
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• 2013

A two-pass differential speed rolling(DSR) was applied to a deoxidized low-phosphorous copper alloy sheet in order to form a homogeneous microstructure. Copper alloy with a thickness of 3 mm was rolled to 75 % reduction by two-pass rolling at $150^{\circ}C$ without lubrication at a differential speed ratio of 2.0:1. In order to introduce uniform shear strain into the copper alloy sheet, the second rolling was performed after turning the sample by $180^{\circ}$ on the transverse direction axis. Conventional rolling(CR), in which the rotating speeds of the upper roll and lower roll are identical to each other, was also performed by two-pass rolling under a total rolling reduction of 75 %, for comparison. The shear strain introduced by the conventional rolling showed positive values at positions of the upper roll side and negative values at positions of the lower roll side. However, samples processed by the DSR showed zero or positive values at all positions. {100}//ND texture was primarily developed near the surface and center of thickness for the CR, while {110}//ND texture was primarily developed for the DSR. The difference in misorientation distribution of grain boundary between the upper roll side surface and center regions was very small in the CR, while it was large in the DSR. The grain size was smallest in the upper roll side region for both the CR and the DSR. The hardness showed homogeneous distribution in the thickness direction in both CR and DSR. The average hardness was larger in CR than in DSR.

• Journal of Electrochemical Science and Technology
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• v.2 no.1
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• pp.1-7
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• 2011

Nanocomposites of reduced graphene oxide and manganese (II,III) oxide can be synthesized by the freeze-drying process of the mixed colloidal suspension of graphene oxide and manganese oxide, and the subsequent heat-treatment. The calcined reduced graphene oxide-manganese (II,III) oxide nanocomposites are X-ray amorphous, suggesting the formation of homogeneous and disordered mixture without any phase separation. The reduction of graphene oxide to reduced graphene oxide upon the heat-treatment is evidenced by Fourier-transformed infrared spectroscopy. Field emission-scanning electronic microscopy and energy dispersive spectrometry clearly demonstrate the formation of porous structure by the house-of-cards type stacking of reduced graphene oxide nanosheets and the homogeneous distribution of manganese ions in the nanocomposites. According to Mn K-edge X-ray absorption spectroscopy, manganese ions in the calcined nanocomposites are stabilized in octahedral symmetry with mixed Mn oxidation state of Mn(II)/Mn(III). The present reduced graphene oxide-manganese oxide nanocomposites show characteristic pseudocapacitance behavior superior to the pristine manganese oxide, suggesting their applicability as electrode material for supercapacitors.

• Journal of the Korean Society for Precision Engineering
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• v.19 no.5
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• pp.19-24
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• 2002

• Metals and materials international
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• v.24 no.6
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• pp.1262-1274
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• 2018

The inhibition of gravity segregation has been a long-standing challenge in fabrication and applications of homogeneous immiscible alloys. Therefore, the effect of rare-earth La on the gravity segregation of Al-Bi immiscible alloys was investigated to understand the homogenization mechanism. The results showed that the addition of La can completely suppress the gravity segregation. This is attributed to the nucleation of Bi-rich liquid phase on the in-situ produced $LaBi_2$ phase and the change of the shape of $LaBi_2@Bi$ droplets. In addition, a novel strategy is developed to prepare the homogeneous immiscible alloys through the addition of rare-earth elements. This strategy not only is applicable to other immiscible alloys, but also is conducive to finding more elements to suppress the gravity segregation. This study provided a useful reference for the fabrication of the homogeneous immiscible alloys.

• Proceedings of the Polymer Society of Korea Conference
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• 2006.10a
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• pp.212-212
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• 2006

Polyurethane wastes can be depolymerized with glycols and/or amines. The depolymerization products may be recycled for the preparation of various polyurethanes. Caprolactam was employed to depolymerize Spandex fibers and the depolymerization products were evaluated as raw materials for the preparation of polyurethane elastomers. The depolymerization products were homogeneous and could be used to prepare polyurethane elastomers acceptable for various applications as binders.

• Coupled systems mechanics
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• v.7 no.1
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• pp.61-77
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• 2018

This paper establish a high concentration ratio approximation of linear elastic properties of materials with periodic microstructure with cubic inclusions. The approximation is derived using first few terms of power series expansion of the solution of the equivalent eigenstrain problem with a homogeneous eigenstrain approximation. Viability of the approximation at high concentration ratios is proved by comparison with a numerical solution of the homogenization problem. To this end some theoretical result of symmetry properties of the homogenization problem are given. Using these results efficient numerical computation on a reduced computational domain is presented.

• Journal of the Korean Ceramic Society
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• v.49 no.1
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• pp.29-36
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• 2012

In many applications of functional oxides originally homogeneous materials are exposed to gradients in the chemical potential of oxygen. Prominent examples are solid oxide fuel cells (SOFCs) or oxygen permeation membranes (OPMs). Other thermodynamic potential gradients are gradients of electrical potential, temperature or uni-axial pressure. The applied gradients act as generalized thermodynamic forces and induce directed fluxes of the mobile components. These fluxes may lead to three basic degradation phenomena of the materials, which are kinetic demixing, kinetic decomposition, and morphological instabilities.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.11
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• pp.2277-2286
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• 2002

The application of bonded dissimilar materials to industries as automobiles, aircraft, rolling stocks, electronic devices and engineering structures is increasing gradually because these materials, compared to the homogeneous materials, have many advantages for material properties. In spite of such wide applications of bonded dissimilar materials, the evaluation method of quantitative strength considering the stress singularities for its bonded interface has not been established clearly. In this paper, the stress singularity for Bctors and the stress intensity factors were analyzed by boundary element method(BEM) for the scarf joints of Al/Epoxy with and without a crack, respectively. From static fracture experiments of the bonded scarf joints, a fracture criterion and a evaluation method of interface strength in bonded dissimilar materials were proposed and discussed.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2002.10a
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• pp.816-819
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• 2002

Accurate stress intensity factor analyses and crack growth rate of surface-cracked components in inhomogeneous materials are needed for reliable prediction of their fatigue lift and fracture strengths. This paper describes an automated system for analyzing the stress intensity factors of three-dimensional (3D) cracks in inhomogeneous materials. 3D finite element method (FEM) was used to obtain the stress intensity factor for subsurface cracks and surface cracks existing in inhomogeneous materials. To examine accuracy and efficiency of the present system, the stress intensity factor for a semi-elliptical surface crack in a plate subjected to uniform tension is calculated, and compared with Raju-Newman's solutions. Then the system is applied to analyze cladding effect of subsurface cracks in inhomogeneous materials. The results were compared with those surface cracks in homogeneous materials. It is clearly demonstrated from these analyses that the stress intensity factors for subsurface cracks are less than those of surface cracks.