• Steel and Composite Structures
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• v.7 no.1
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• pp.19-34
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• 2007

This paper presents results of a non-linear finite element analysis of axially loaded slender hollow structural section (HSS) columns, strengthened using high modulus carbon-fiber reinforced polymer (CFRP) longitudinal sheets. The model was developed and verified against both experimental and other analytical models. Both geometric and material nonlinearities, which are attributed to the column's initial imperfection and plasticity of steel, respectively, are accounted for. Residual stresses have also been modeled. The axial strength in the experimental study was found to be highly dependent on the column's imperfection. Consequently, no specific correlation was established experimentally between strength gain and amount of CFRP. The model predicted the ultimate loads and failure modes quite reasonably and was used to isolate the effects of CFRP strengthening from the columns' imperfections. It was then used in a parametric study to examine columns of different slenderness ratios, imperfections, number of CFRP layers, and level of residual stresses. The study demonstrated the effectiveness of high modulus CFRP in increasing stiffness and strength of slender columns. While the columns' imperfections affect their actual strengths before and after strengthening,the percentage gain in strength is highly dependent on slenderness ratio and CFRP reinforcement ratio, rather than the value of imperfection.

• Environmental Analysis Health and Toxicology
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• v.23 no.2
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• pp.67-77
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• 2008

It has been observed that the linear relationship between the logarithm of bioconcentration factor (log BCF) of highly hydrophobic chemicals and their log $K_{ow}$ breaks when log $K_{ow}$ becomes greater than 6.0. Consequently, super hydrophobic chemicals were not thought to cause baseline toxicity as a single compound. Researchers often call this phenomenon as "hydrophobicity cutoff" meaning that bioconcentration or corresponding baseline toxicity has a certain cutoff at high log $K_{ow}$ value of hydrophobic organic pollutants. The underlying assumption is that the increased molecular size with increasing hydrophobicity prohibits highly hydrophobic compounds from crossing biological membranes. However, there are debates among scientists about mechanisms and at which log $K_{ow}$ this phenomenon occurs. This paper reviews three hypotheses to explain observed "cutoff": steric effects, kinetic or physiological limitations, and chemical activity cutoff. Although the critical molecular size that makes biological membranes not permeable to hydrophobic organic chemicals is uncertain, size effects in combination with kinetic limitation would explain observed non-linearity between log BCF and log $K_{ow}$. Chemical activity of hydrophobic chemicals generally decreases with increasing melting point at their aqueous solubility. Thus, there may be a chemical activity cutoff of baseline toxicity if there is a critical chemical activity over which baseline effects can be observed.

• Journal of Photoscience
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• v.5 no.1
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• pp.11-15
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• 1998

The texture change of non-linear optical molecules at the air/water interface was investigated as a function of surface pressure with Brewster angle microscopy. The texture change resulted from the aggregation of dye molecules is important to understand the film uniformity and grain formation process. The 4-Octadecylhydroxy-4'-nitrostilbene (OHNS) generated the small spots of size around 1$\mu$m. The spots exhibit high contrast with other film area and do not show angle dependent reflectivity change. It is interesting to observe that the size of the domain stays the same as the film pressure increases. At high surface pressure, the contrast ratio of domains becomes high, which means dense packing of OHNS. And, the size of domain grows. In the middle of domain, highly contrasted domains are formed. The first and the second order transitions of OHNS observed from surface pressure-area isotherm result from the two types of grains. The N,N-Dihexadecylcyanoaniline (DHCA) formed highly contrasted gains over entire region, and the grains are the double layers. The difference in Langmuir film of OHNS and DHCA at the air/water interface is consistent with the small tilt angle from the surface normal for OHNS and the large tilt angle for DHCA in the Langmuir-Blodgett films.

• Macromolecular Research
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• v.8 no.1
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• pp.12-18
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• 2000

Six aromatic polyesters with ether-linkages were prepared from 4,4'-oxybis(benzoic acid) and naphthalenediol (ND) isomers which were 1,4-, 1,5-, 1,6-, 2,3-, 2,6- and 2,7-derivatives. The solution viscosity numbers ranged from 0.23 to 0.65 dL/g. The glass transition temperatures ranged from 142 to 179$\^{C}$. The initial decomposition temperatures were all above 400$\^{C}$, and the residue weights at 600$\^{C}$ were in the range of 50-64%. Only the polyesters derived from 1,5- and 2,6-NDs, which have a linear linking mode, were found to be semicrystalline and could form thermotropically nematic phase. Multiple melting phenomena and annealing of the polyester derived from 1,5-ND and related polymers are described. The experimental results show that the polyester derived from 1,4-ND of linear shape was amorphous and non-liquid crystalline. Particularly, the polyester derived from 2,3-ND could form a smectic mesophase as banana-shaped molecules, and this is ascribed to the C/sub_2v/ symmetry where highly kinked molecules are packed in the same direction.

• Macromolecular Research
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• v.17 no.12
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• pp.943-949
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• 2009

A highly dispersed W/O emulsion of silicone oil (cyclomethicone)/water system was prepared with a nonionic surfactant. The surface and interfacial tension between the oil and water were characterized in terms of the droplet size distribution and viscosity change of the emulsion. When the dispersed phase concentration was relatively high, the viscosity of the emulsion was rapidly increased and the droplet size of the emulsion was decreased. The rheological behavior of the emulsion system showed non-Newtonian and shear thinning phenomena depending upon the content of the dispersed phase. The droplet size of the emulsion was decreased with increasing surfactant content and water concentration. The relative viscosity of the emulsion was better predicted with the Choi-Schowalter model than with the Taylor model. The value of the complex modulus increased with increasing surfactant concentration. The linear viscoelastic region was expanded with a dispersed phase concentration. According to the change in the viscosity, the behavior was classified into three distinct regions: [I] linear viscoelastic, [II] partially viscoelastic, and [III] viscous. The creep/recovery behaviors in each region were characterized.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.283-286
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• 2002

Solubilization and partitioning of naphthalene was investigated in an aqueous system containing soils and surfactants. The environmental behavior of polycyclic aromatic hydrocarbons(PAHs) was mainly governed by their solubility and partitioning properties on soil media in a subsurface system. In surfactant-enhanced remediation systems, surfactants might be an additional variable. a natural soil ,silica and kaolinite were tested as soil media. two nonionic surfactants, Triton X-100 and Hydropropy1-$\beta$-cyclodextrin (HPCD) were employed for naphthalene solubilization. Naphthalene showed linear on natural soil while non-linear sorption on silica and kaolinite. Soils have higher sorption capacity for Triton X-100 than HPCD indicating Triton X-100 formed ad-micelle on the soil surface. Desorption study showed a hysterysis and reversible desorption. The partitioning coefficient(K$_{D}$) of naphthalene was increased as the concentration of surfactant was increased. (below CMC), however, the coefficient was decreased above CMC. This indicates that naphthalene is partitioned into the micelles and the partition occurs competitively on both ad-micelle and free micelles as surfactant concentration increases. Therefore, the target compounds to be dissolved into aqueous phase in a surfactant enhanced remediation system might be highly partitioned on to the ad-micelle resulting in an adverse effect rather increased solubilization would be achieved.d.

• Journal of the Korean Wood Science and Technology
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• v.21 no.4
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• pp.64-72
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• 1993

Mechanical properties of 15 mm thick, three-layer particleboard were studied by varying resin content, specific gravity, mat moisture content, pressing time and pressing temperature. Based on the results of the study, Multiple regression models were developed to estimate the mechanical properties of three-layer particleboard. The results of this study showed the mechanical properties of particleboard were highly related with resin content. specific gravity and mat moisture content in decending order. The mechanical properties were able to estimated as the linear function of resin content and specific gravity. However, the effects of change in mat moisture content on the mechanical properties showed a non-linear pattern. The mechanical properties curves over mat moisture content reached peaks at 15 %, and then decreased at 18 % and 21 % of mat moisture contents. On the other hand, the effects of pressing time and pressing temperature on the mechanical properties of particleboard were not significant.

• Journal of the Korean Geosynthetics Society
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• v.13 no.4
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• pp.69-75
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• 2014

The shear strength characteristics of an unsaturated earth material are highly important not only for evaluating the seepage characteristics but also the stability of levee for a lifelong. In this study, unsaturated strength characteristics of Nak-dong river sand and clay that frequently used for the levee construction in southern province of Korea were analyzed using unsaturated triaxial compressive test. The strength characteristics due to the variation of matric suction were analyzed using multi-stage compression technique and the results were directly compared with the non-linear formulation for the apparent cohesion ($C_{max}$), and the friction component ${\varphi}^b$ were determined and evaluated from the test for the application of linear Mohr-Coulomb failure criteria. Cohesion and friction characteristics of the unsaturated levee material under various suction phases were also explored during this study.

• Computers and Concrete
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• v.22 no.6
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• pp.539-550
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• 2018

Concrete is highly non-linear material which is originating from the transition zone in the form of micro-cracks, governs material response under various loadings. In this paper, the constitutive models published by many researchers have been used to generate novel stiffness parameters and constitutive curves for concrete. Following such linear material formulations, where the energy is conservative during the curvature, and a nonlinear contribution to the concrete has been made and investigated. In which, nonlinear concrete elastic modulus modeling has been developed that is capable-of representing concrete elasticity for grades ranging from 10 to 140 MPa. Thus, covering the grades range of concrete up to the ultra-high strength concrete, and replacing many concrete models that are valid for narrow ranges of concrete strength grades. This has been followed by the introduction of the nonlinear Hooke's law for the concrete material through the replacement of the Young constant modulus with the nonlinear modulus. In addition, the concept of concrete elasticity index (${\varphi}$) has been proposed and this factor has been introduced to account for the degradation of concrete stiffness in compression under increased loading as well as the multi-stages micro-cracking behavior of concrete under uniaxial compression. Finally, a sub-routine artificial neural network model has been developed to capture the concrete behavior that has been introduced to facilitate the prediction of concrete properties under increased loading.

• Journal of the Korean Geotechnical Society
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• v.22 no.1
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• pp.35-44
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• 2006

In general typically granular soils contain a certain amount of fines. It is also widely recognized that foundation soils under working loads show highly non-linear behavior from very early stages of loading. In the present study, a series of laboratory tests with sands of different silt contents are conducted and methods to assess strength and stiffiness characteristics are proposed. Modified hyperbolic stress-strain model is used to analyze non-linearity of silty sands in terms of non-linear Degradation parameters f and g as a function of silt contents and Relative density Dr. Stress-strain curves were obtained from a series of triaxial tests on sands containing different amounts of silt. Initial shear modulus, which is used to normalize Degradation modulus of silty sands, was determined from resonant column test results. From the laboratory test results, it was observed that, as the Relative density increases, values of f decrease and those of g increase. In addition, it was found that values of f and g increase and decrease respectively as a Skeleton void ratio $(e_{sk})$ increases.