• Title/Summary/Keyword: high-nitrogen

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Deformation behavior of the Fe-18Cr-14Mn-4Ni-0.9N high nitrogen steel under different strain rate conditions (Fe-18Cr-14Mn-4Ni-0.9N 고질소 내식강의 고온 석출과 변형률 속도에 따른 변형특성 연구)

  • Nam, S.M.;Kim, Y.S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2006.05a
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    • pp.421-424
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    • 2006
  • High nitrogen steels (HNS) exhibit both high strength and ductility during tensile deformation. In the present study the Fe-18Cr-14Mn-4Ni-0.9N high nitrogen steel was heat treated at $1000^{\circ}C$ and $1100^{\circ}C$ to produce $Cr_2N$ precipitates in austenite matrix and full austenite microstructures, respectively. Tensile tests of the heat treated specimens were performed at two different strain rates of 0.05/sec and 0.00005/sec. Each tensile curve of the specimens could be well characterized by the the modified Ludwik equation. Plastic deformation of the steel was adequately represented by the four parameters of the modified Ludwik equation. At 0.05/s strain rate, the specimen with the $Cr_2N$ precipitate exhibited higher strength than the full austenite specimen, while the full austenite specimen showed better mechanical properties at 0.00005/s strain rate. It was found that the $Cr_2N$ precipitates influences deformation behavior of the high nitrogen steel significantly.

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Properties of As-casted High Nitrogen Steel for Core of Over-head Transmission Line (가공 송전선 강심용 고질소강 주조재의 제특성)

  • Yoo, Kyung-Jae;Kim, Bong-Seo;Kwon, Hae-Woong;Kim, Byung-Geol;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.861-863
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    • 1998
  • As-casted high nitrogen alloys (Fe-25%Mn-12%Cr-1%Ni) have been investigated to study core material. Nitrogen concentration in molten alloys was increased with increasing the square root of nitrogen gas pressure in melting chamber. This result can be explained by Sievert's law. Nitrogen that dissolved as a interstital solid solution element in austenite stainless steel increased lattice parameter and hardness. Electric resistivity($\rho$) was increased with increasing nitrogen concentration and was about $80{\mu}{\Omega}cm$ at room temperature. Coefficient of linear thermal expansion of the nitrogen steel was about $22{\times}10^{-6}/^{\circ}C$.

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The effect of dry matter allocation at the early seedling stare on the growth of two grass species (두 초본 종의 생장에 있어서 실생 초기의 물질분해 효과)

  • Park, Young-Mok
    • The Korean Journal of Ecology
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    • v.15 no.3
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    • pp.297-309
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    • 1992
  • The growth of digitaria adscendens and eleusine indica, annual weeds common in japan, was experimentally analyzed under varying untrient conditions. compared with e. indica, d. adscendensshowed a higher the two under high nitrogen availability. Higher net assimilation rate(nar) in d. adscendens than e. india was responsible for high RGR in D. adscendens under the low nitrogen availability. The different of NAR in the two species was induced not by leaf nitrogen content but by nitrogen use efficiency. Under unfertilized conditions nitrogen uptake rate(nur) was greater in d. adscendens than e. indica. Specific absorption rate in two species was similar, but root mass was greater in d. adscendens than e. indica.d. adscendens allocated more dry matter to roots than e. india earlier stage of seedlings. The contributed to higher rot mass and in turn resulted in higher nur in d. adscendens than that in e. india. It is concluuded that the larger allocation of dry matter to roots at early seedling stage in d. adscendens plays an important role in obtaining nitrogen for the continuation of growth under low nitrogen availability.

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Growth Characteristics and Removal Effect of Nitrogen and Phosphoric Acid of Iris pseudoacorus at Waterway Soils of Mangyeong River (만경강 하천토양에서 노랑꽃창포의 생장특성과 질소·인 제거효과)

  • Seo, Byungsoo;Choi, Sumin;Park, Woojin;Park, Chongmin
    • Journal of the Korean Society of Environmental Restoration Technology
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    • v.7 no.5
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    • pp.57-65
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    • 2004
  • This study was carried out to measure the growth and photosynthesis of Iris pseudoacorus, the reduction rate of nitrogen(T-N) and phosphoric acid($P_2O_5$) from soils, and the increase rate of two substance into plants which cultivated at waterway soils of different concentration of two substance. The results are summarized as follows; 1. The contents of nitrogen and phosphoric acid at waterway soils of Mangyeong river showed the highest level in the around Samrye railway bridge where was located in the downstream and sewage of stock raising flowed in 2. The Iris pseudoacorus which cultivated at waterway soils showed the leaf and root growth of 43~50 and 9~13cm, respectively. And the growth was higher in the waterway soils contained high level of nitrogen The rate of photosynthesis was $3.5-5.9{\mu}mol\;m^{-2}s^{-1}$ ranges and this rate increased from the end of June to August and then decreased. The rate of photosynthesis was higher in waterway soils contained high nitrogen regardless of seasons. 4. The Iris pseudoacorus removed nitrogen and phosphoric acid from waterway soils about 19~21% and 13~15%, respectively. The Iris pseudoacorus was effective to remove nitrogen more than phosphoric acid. And the waterway soil which included high concentration of two substance showed highly removal 5. The results of Iris pseudoacorus vegetation in the waterway soils showed that nitrogen and phosphoric acid of inside plant increased with 0.2-1.0% and 0.01-0.10% ranges, respectively. The contents of nitrogen and phosphoric acid in plants were increase in the soils of higher contents of nitrogen and phosphoric acid, and the rate of increase of nitrogen and phosphoric acid was higher at roots than leaves.

Radiochemical behavior of nitrogen species in high temperature water

  • Young-Jin Kim;Geun Dong Song;Seung Heon Baek;Beom Kyu Kim;Jin Sik Cheon;Jun Hwan Kim;Hee-Sang Shim;Soon-Hyeok Jeon;Hyunmyung Kim
    • Nuclear Engineering and Technology
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    • v.55 no.9
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    • pp.3183-3193
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    • 2023
  • The water radiolysis in-core at light water reactors (LWRs) produces various radicals with other ionic species/molecules and radioactive nitrogen species in the reactor coolant. Nitrogen species can exist in many different chemical forms and recirculate in water and steam, and consequently contribute to what extent the environmental safety at nuclear power plants. Therefore, a clear understanding of formation kinetics and chemical behaviors of nitrogen species under irradiation is crucial for better insight into the characteristics of major radioactive species released to the main steam or relevant coolant systems and eventually development of advanced processes/methodologies to enhance the environmental safety at nuclear power plants. This paper thus focuses on basic principles on electrochemical interaction kinetics of radiolytic molecules and various nitrogen species in high temperature water, fundamental approaches for calculating thermodynamic values to predict their stability and domain in LWRs, and the effect of nitrogen species on crevice chemistry/corrosion and intergranular stress corrosion cracking (IGSCC) susceptibility of structure materials in high temperature water.

Effect of Nitrogen Gas Pressure on the Property of TiN-Coated Layer of High Speed Steel by Arc ion Plating (AIP 법에서 질소가스 압력이 고속도강의 TiN 코팅층 성질에 미치는 영향)

  • Kim, Hae-Ji;Joun, Man-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.7
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    • pp.124-130
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    • 2008
  • The effect of nitrogen gas pressure in arc ion plating on surface properties of the TiN-coated high speed steel(SKH51) is presented in this paper. The surface roughness, micro-particle, micro-hardness, coated thickness, atomic distribution of TiN, and adhesion strength are measured fur various nitrogen gas pressures. It has been shown that the nitrogen gas pressure has a considerable effect on the surface roughness, adhesion strength, atomic distribution of TiN, and surface deposition of TiN of the high speed steels but that it has little influence on the micro-hardness and coated thickness.

Removal Characteristic of Ammonia Nitrogen and Behavior of Nitrogen in Synthetic Wastewater Using Leclercia Adecarboxylata (Leclercia Adecarboxylata를 이용한 합성폐수의 암모니아성질소 제거특성 및 질소거동)

  • Lee, Hyun-Hee;Phae, Chae-Gun
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.4
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    • pp.460-465
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    • 2007
  • In this study, the removal characteristic of ammonia nitrogen and behavior of nitrogen was investigated using Leclercia adecarboxylata, which was derived from the culture contaminated by ammonia nitrogen of high concentration. The method of ammonia nitrogen removal was not biological nitrification and denitrification but elimination of nutrient salt with internal synthesis of microorganisms which use ammonia nitrogen as substrate. L. adecarboxylata(one of ammonia synthesis microorganisms) was highly activated and showed the most high removal efficiency in free salt condition but the removal efficiency decreased badly in salt concentration of more than 4%. About 80 mg/L of $NH_3-N$ was mostly removed within 20 hours and 500 mg/L of $NH_3-N$ showed less then removal efficiency of 50% because carbon source was not enough. However, ammonium nitrogen concentration was decreased again when the carbon source was inserted additionally thus, ammonium nitrogen removal efficiency by L. adecarboxylata, was related to amount of carbon source. pH decreased from 8.0 to 6.36 according to growth of L. adecarboxylata. Concentration of nitrite nitrogen and nitrate nitrogen did not increase and TKN concentration showed no variation while ammonia nitrogen was removed by L. adecarboxylata. In addition to, when content of protein in organic nitrogen was measured, protein was not detected at the beginning of microorganism synthesis but protein of 193.1 mg/L was detected after 48 hours. Hence, ammonium nitrogen was not decomposed as nitrate nitrogen and nitrite nitrogen but synthesized by L. adecarboxylata, which has excellent ability of nitrogen synthesis and can threat ammonia nitrogen of high concentration in wastewater.

Nitrogen Efficiency and its Relation to Various Physiological Characteristics among Rice Varieties (수도품종간(水稻品種間) 질소효율(窒素効率) 및 수종(數種) 생리적특성(生理的特性)과의 관계(關係))

  • Park, Hoon;Mok, Sung Kyun
    • Korean Journal of Soil Science and Fertilizer
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    • v.8 no.2
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    • pp.105-111
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    • 1975
  • Nitrogen efficiency for grain yield(E) and its relation to grain yield(Y), harvesting index(HI), percent translocation of nitrogen from straw to grain(T), nitrogen uptake amount(N), concentration in grain (GN%) or straw (SN%) and total dry matter yield (TY) among rice varieties (Oryza sativa, old and new varieties) were investigated at four nitrogen nutritional status (high and low fertilizer levels in high and low fertility fields) by simple correlation analysis. Relation between any two of above parameters or total dry matter yield (TY) and nitrogen efficiency for total dry matter yield (TE) was also investigated. 1. E is significantly and positively correlated with T, Y, HI but negatively with SN%, N, GN% and in negative trend with TY. 2. T is significantly and positively with GN% or Y, but negatively with SN%. 3. TE is significantly and positively correlated with TY but negatively with N. 4. The order of E among varieties showed consistency among different nitrogen nutritional environments. 5. From the above facts it was concluded that high yielding varieties have high nitrogen efficiency due to high percent translocation of nitrogen from straw to grain, subsequent low nitrogen concentration in straw and that translocated nitrogen in grain is greatly diluted with photosynthates. 6. Reported physiological characteristics of newly bred high yielding IR lines are well accordance with their high nitrogen efficiency and rice breeding was a selection on the basis of nitrogen efficiency. 7. It is postulated that high nitrogen efficiency varieties for yields have high nitrogen efficiency for root growth in early stage so that uptake more efficient soil nitrogen in later growth stage.

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Effects of Nitrogen Fertilization on Growth of Populus sibirica and Ulmus pumila Seedlings and Soil Properties in a Semi-Arid Area, Mongolia (몽골 반건조지에서 질소 시비가 백양나무와 비술나무 묘목의 생장 및 토양 특성에 미치는 영향)

  • Chang, Hanna;Han, Seung Hyun;Kim, Seongjun;Park, Min Ji;An, Jiae;Kang, Hoduck;Yi, Myong-Jong;Akhmadi, Khaulenbek;Son, Yowhan
    • Journal of Climate Change Research
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    • v.6 no.3
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    • pp.249-256
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    • 2015
  • This study was conducted to investigate the effects of different levels and types of nitrogen fertilizer on seedlings and soil chemical properties in a semi-arid area, Mongolia. 2-year-old Populus sibirica and 4-year-old Ulmus pumila seedlings were planted in May 2014. Six treatments with three levels of nitrogen (low-level: urea $5g\;tree^{-1}$; medium-level: urea $15g\;tree^{-1}$, ammonium sulfate $33g\;tree^{-1}$, urea $15g\;tree^{-1}$ with potassium phosphate $10g\;tree^{-1}$; high-level: urea $30g\;tree^{-1}$) were applied and for the medium-level of nitrogen, different types of fertilizer were treated. Survival rate, root collar diameter (RCD) growth rate, leaf nitrogen concentration of seedlings, and soil chemical properties were determined in August 2014. The seedling survival rate of both species decreased as the level of nitrogen increased. This result can be explained by water stress caused by nitrogen fertilization in arid regions. The RCD growth rate of P. sibirica was significantly decreased by the treatment of high-level of nitrogen due to excessive nitrogen fertilization, and was increased by the treatment of ammonium sulfate due to sulfur which might promote nitrogen uptake. The leaf nitrogen concentration of P. sibirica did not change by the treatment of low-level of nitrogen, and was increased by the treatment of medium-level of nitrogen. There were no significant differences in the RCD growth rate and the leaf nitrogen concentration of U. pumila among the six treatments. None of soil chemical properties was affected by nitrogen fertilization. Overall, the low-level of nitrogen showed no effect on seedlings and soil chemical properties, except on survival rate of U. pumila and the high-level of nitrogen was considered excessive fertilization. Continuous monitoring of medium-level nitrogen fertilization including the ammonium sulfate, which increased early growth of seedlings, would be needed to elucidate the effect of fertilization on seedling growth and soil properties in a semi-arid region.

High Nitrogen-Bearing Austenitic Stainless Steels Resistant to Marine Corrosion

  • Kodama, Toshiaki;Katada, Yasuyuki;Baba, Haruo;Sagara, Masayuki
    • Corrosion Science and Technology
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    • v.2 no.6
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    • pp.272-276
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    • 2003
  • High nitrogen-bearing stainless steel (HNS) containing more than Imass% N was successfully created by means of pressurized electro-slag remelting (P-ESR) without the addition of manganese. Excellent localized corrosion resistant properties of the HNS were confirmed in terms of pitting and crevice corrosion in artificial seawater. The repassivation kinetics proved higher repassivation rate for HNS.