• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.470-473
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• 2005

Spent nuclear fuels are regarded as a high level radioactive waste and they will be disposed in a deep geological repository. To maintain the safety of the repository for hundreds of thousands of years, the spent fuels are encapsulated in a disposal canister and the canister containing spent fuels should have the structural integrity and the corrosion resistance below the several hundreds meters from the ground surface. In this study, the concept of the spent fuel encapsulation process and the process equipment fur deep geological disposal were established. To do this, the design requirements, such as the functions and the spent fuel accumulations, were reviewed. Also, the design principles and the bases were established. Based on the requirements and the bases, the encapsulation process and the equipment from spent fuel receiving process to transferring canister into the underground repository including hot cell processes was established. The established concept of the spent fuel encapsulation process and the process equipment will be improved continuously with the future studies. And this concept can be effectively used in implementing the reference repository system of our own case.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.14 no.2
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• pp.101-112
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• 2016

This study investigated the removal of Sr, which was one of the high radioactive nuclides, by adsorption with Barium (Ba) impregnated 4A zeolite (BaA) from high-radioactive seawater waste (HSW). Adsorption of Sr by BaA (BaA-Sr), in the impregnated Ba concentration of above 20.2wt%, was decreased by increasing the impregnated Ba concentration, and the impregnated Ba concentration was suitable at 20.2wt%. The BaA-Sr adsorption was added to the co-precipitation of Sr with $BaSO_4$ precipitation in the adsorption of Sr by 4A (4A-Sr) within BaA. Thus, it was possible to remove Sr more than 99% at m/V (adsorbent weight/solution volume)=5 g/L for BaA and m/V >20 g/L for 4A, respectively, in the Sr concentration of less than 0.2 mg/L (actual concentration level of Sr in HSW). It shows that BaA-Sr adsorption is better than 4A-Sr adsorption in for the removal capacity of Sr per unit gram of adsorbent, and the reduction of the secondary solid waste generation (spent adsorbent etc.). Also, BaA-Sr adsorption was more excellent removal capacity of Sr in the seawater waste than distilled water. Therefore, it seems to be effective for the direct removal of Sr from HSW. On the other hand, the adsorption of Cs by BaA (BaA-Cs) was mainly performed by 4A within BaA. Accordingly, it seems to be little effect of impregnated Ba into BaA. Meanwhile, BaA-Sr adsorption kinetics could be expressed the pseudo-second order rate equation. By increasing the initial Sr concentrations and the ratios of V/m, the adsorption rate constants ($k_2$) were decreased, but the equilibrium adsorption capacities ($q_e$) were increasing. However, with increasing the temperature of solution, $k_2$ was conversely increased, and $q_e$ was decreased. The activation energy of BaA-Sr adsorption was 38 kJ/mol. Thus, the chemical adsorption seems to be dominant rather than physical adsorption, although it is not a chemisorption with strong bonding form.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.4
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• pp.339-350
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• 2007

Status on the spent nuclear fuel management policy and R&D plan of the major countries is surveyed. Also the prospect of the future R&D plan is suggested. Recently so-called fuel cycle nations, which have the reprocess policy of the spent fuel, announced new spent fuel management policy based on the advanced fuel cycle technology. The policy is focused to transmute highly radioactive material and material having a very long half-life, and to recycle the Pu and U contained in the spent fuel. In this way the radio-foxily of the spent fuel as well as the amount of the high level waste to be eventually disposed can greatly be reduced. Most of countries selected the wet process as a primary option for the treatment of the spent fuel since the advanced wet process, which is based on the existing PUREX process, looks more feasible as compared with the dry process. The wet process, however, is much more sensitive in terms of proliferation-resistance compared with the dry process. The pure Pu can easily be obtained by simply modifying the process. On the other hand the pure Pu can not be extracted in the dry process based on the high temperature molten salt process such as a pyroprocess. Even though the pyroprocess technology is very premature, it has a great merit. Thus it is necessary for Korea to have a long term strategy for pursuing a spent fuel treatment technology with a proliferation resistance and a great merit for the GEN-IV fuel cycles. Pyroprocess is one of the best candidates to satisfy these purposes.

• Transactions of the KSME C: Technology and Education
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• v.3 no.4
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• pp.257-264
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• 2015

To maintain sustainability of nuclear energy as an important energy source, both safety problem and Spent Nuclear Fuels(SNFs) problem should be solved. In case of Gen-IV reactors such as fast reactor, SNFs can be used as fuels by using fast neutrons. It can be a suitable treatment method of high-level waste in near future. Liquid metals such as Sodium or Lead-Bismuth Eutectic (LBE) can be possibly used as a coolant to use fast neutrons. In this paper, it was described that natural circulation parameter studies, design analyses, material selections and a completion of facilities. To develop a natural circulation facility, thermal hydraulic analyses were performed. Installation technique of liquid metal natural circulation were secured.

• Nuclear Engineering and Technology
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• v.40 no.7
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• pp.593-606
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• 2008

In this study, data on radionuclide migration and retardation processes in the engineered and natural barriers of High-Level Radioactive Waste (HLW) repository have been reviewed and compiled for use in the performance assessment of a HLW disposal system in Korea. The status of the database on radionuclide migration and retardation that is being developed in Korea is investigated and summarized in this study. The solubilities of major actinides such as D, Th, Am, Np, and Pu both in Korean bentonite porewater and in deep Korean groundwater are calculated by using the geochemical code PHREEQC (Ver. 2.0) based on the KAERI-TDB(Korea Atomic Energy Research Institute-Thermochemical Database), which is under development. Databases for the diffusion coefficients ($D^b_e$ values) and distribution coefficients ($K^b_d$ values) of some radionuclides in the compacted Korean Ca-bentonite are developed based upon domestic experimental results. Databases for the rock matrix diffusion coefficients ($D^r_e$ values) and distribution coefficients ($K^r_d$ values) of some radionuclides for Korean granite rock and deep groundwater are also developed based upon domestic experimental results. Finally, data related to colloids such as the characteristics of natural groundwater colloids and the pseudo-colloid formation constants ($K_{pc}$ values) are provided for the consideration of colloid effects in the performance assessment.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.4 no.3
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• pp.235-243
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• 2006

In this study, an experimental study on the sorption properties of uranium(VI) onto a bentonite colloid generated from Gyeongju bentonite which is a potential buffer material in a high-level radioactive waste repository was performed as a function of the pH and the ionic strength. The bentonite colloid prepared by separating a colloidal fraction was mainly composed of montmorillonite. The concentration and the size fraction of the prepared bentonite colloid measured using a gravitational filtration method was about 5100 ppm and 200-450 nm in diameter, respectively. The amount of uranium removed by the sorption reaction bottle walls, by precipitation, and by ultrafiltration was analyzed by carrying out some blank tests. The removed amount of uranium was found not to be significant except the case of ultrafiltration at 0.001 M $NaClO_4$. The ultrafiltration was significant in the lower ionic strength of 0.001 M $NaClO_4$ due to the cationic sorption onto the ultrafilter by a surface charge reversion. The distribution coefficient $K_d$ (or pseudo-colloid formation constant) of uranium(VI) for the bentonite colloid was about $10^4{\sim}10^7mL/g$ depending upon pH and ionic strength of $NaClO_4$ and the $K_d$ was highest in the neutral pH around 6.5. It is noted that the sorption of uranium(VI) onto the bentonite colloid is closely related with aqueous species of uranium depending upon geochemical parameters such as pH, ionic strength, and carbonate concentration. As a consequence, the bentonite colloids generated from a bentonite buffer can mobilize the uranium(VI) as a colloidal form through geological media due to their high sorption capacity.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.18 no.2
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• pp.133-141
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• 2020

A geological repository comprises a natural barrier and an engineered barrier system. Its design components consist of canisters, buffers, backfill, and near-field rock. Among the engineered barrier system components, bentonite buffers minimize the groundwater flow from near-field rock and prevent the release of nuclide. Investigation of the hydraulic conductivity of the buffer to groundwater flow is an important factor in the performance evaluation of the stability and integrity of the engineered barrier of the repository. In this study, saturated hydraulic conductivity tests were performed using Gyeongju bentonite at various dry densities and temperatures, and a hydraulic conductivity prediction model was developed through multiple regression analysis using the 120 result sets of hydraulic conductivity. The test results showed that the hydraulic conductivity tends to decrease as the dry density increases. In addition, the hydraulic conductivity increased with increasing temperature. The multiple regression analysis results showed that the coefficient of determination (R²) of the hydraulic conductivity prediction equation was as high as 0.93. The hydraulic conductivity prediction equation presented in this study could be used for the design of engineered barrier systems.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.11 no.4
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• pp.281-291
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• 2013

A hypothetical repository was assumed to be located at the KURT (KAERI Underground Research Tunnel) site, and the travel times of radionuclides released from three source positions were calculated. The groundwater flow around the KURT site was simulated and the groundwater pathways from the hypothetical source positions to the shallow groundwater were identified. Of the pathways, three pathways were selected because they had highly water-conductive features. The transport travel times of the radionuclides were calculated by a TDRW (Time-Domain Random Walk) method. Diffusion and sorption mechanisms in a host rock matrix as well as advection-dispersion mechanisms under the KURT field condition were considered. To reflect the radioactive decay, four decay chains with the radionuclides included in the high-level radioactive wastes were selected. From the simulation results, the half-life and distribution coefficient in the rock matrix, as well as multiple pathways, had an influence on the mass flux of the radionuclides. For enhancing the reliability of safety assessment, this reveals that identifying the history of the radionuclides contained in the high-level wastes and investigating the sorption processes between the radionuclides and the rock matrix in the field condition are preferentially necessary.

• Tunnel and Underground Space
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• v.30 no.4
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• pp.271-305
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• 2020

An effect of coupled thermo-hydro-mechanical and chemical (THMC) behavior is an essential part of the performance and safety assessment of geological disposal systems for high-level radioactive waste and spent nuclear fuel. Furthermore, numerical models and modeling techniques are necessary to analyze and predict the coupled THMC behavior in the disposal systems. However, phenomena associated with the coupled THMC behavior are nonlinear, and the constitutive relationships between them are not well known. Therefore, it is challenging to develop numerical models and modeling techniques to analyze and predict the coupled THMC behavior in the geological disposal systems. It is also difficult to verify and validate the development of the models and techniques because it requires expensive laboratory tests and in-situ experiments that need to be performed for a long time. DECOVALEX was initiated in 1992 to efficiently develop numerical models and modeling techniques and validate the developed models and techniques against the lab and in-situ experiments. In Korea, Korea Atomic Energy Research Institute has participated in DECOVALEX-2011, DECOVALEX-2015, and DECOVALEX-2019 since 2008. In this study, all tasks in the three DECOVALEX projects were introduced to the researcher in the field of rock mechanics and geotechnical engineering in Korea.

• Tunnel and Underground Space
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• v.34 no.1
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• pp.28-53
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• 2024

In general, high-level radioactive waste (HLW) generated as a result of nuclear power generation should be disposed within the country. Determination of the disposal site and host rock for HLW deep geological repository is an important issue not only scientifically but also politically, economically, and socially. Considered host rock types worldwide for geological disposal include crystalline rocks, sedimentary rocks, volcanic rocks, and salt dome. However, South Korea consists of various rock types except salt dome. This paper not only analyzed the geological and rock mechanical characteristics on a nationwide scale with the preliminary results on various rock type studies for the disposal host rock, but also reviewed the characteristics and possibility of various rock types as a host rock through deep drilling surveys. Based on the nationwide screening for host rock types resulted from literature review, rock distributions, and detailed case studies, Jurassic granites and Cretaceous sedimentary rocks (Jinju and Jindong formations) were derived as a possible candidate host rock types for the geological disposal. However, since the analyzed data for candidate rock types from this study is not enough, it is suggested that the disposal rock type should be carefully determined from additional and detailed analysis on disposal depth, regional characteristics, multidisciplinary investigations, etc.