• 제목/요약/키워드: high temperature retention time

검색결과 100건 처리시간 0.026초

고온성 종균제를 이용한 제지폐수 처리 (A Study on the Treatment of Paper Mill Wastewater with the Addition of High Thermal Microbial Inoculants)

  • 이성호;임택준;조준형
    • 펄프종이기술
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    • 제34권2호
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    • pp.54-60
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    • 2002
  • The Wastewater of toilet paper mill recycling recovered milk carton was used as a raw material for this study. According to the actual mill conditions, hydraulic retention time was adjusted to 12 hours and F/M (Food/Micro-organism) ratio was adjusted to 0.23. Temperature of aeration basin was varied from 2$0^{\circ}C$ to 5$0^{\circ}C$. The change of Micro-organisms and removal efficiency of pollutant were investigated at the varied temperature of basin. Aeration basin using high thermal microbial inoculants showed more removal efficiency of SS, COD than aeration basin using conventional microbial inoculants at high temperature. Floc consolidation of aeration basin using high thermal microbial inoculants added sludge was better than that of sludge from aeration basin using conventional microbial inoculants.

혐기 소화조 유출수의 아질산화 반응에 온도가 미치는 영향 (Effect of Temperature on Nitritation using Effluent of Anaerobic Digester)

  • 임지열;길경익
    • 한국물환경학회지
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    • 제27권3호
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    • pp.286-292
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    • 2011
  • Preparing for the Standards for Effluents which will be strengthen from 2012, many ways like remodellings and repairs of sewage treatment plant (STP) are considered. The treatment of the recycle water from the sludge treatment process contains high-strength organic compounds and nitrogen is considered as alternative. In the treatment of high-strength nitrogen, nitritation has more economic advantages than nitrification. In this study, lab-scale reactor was operated at the $35^{\circ}C$, $20^{\circ}C$ and $10^{\circ}C$ conditions using effluent of anaerobic digester to investigate the nitrogen removal by nitritation. Long-term stable nitritation was achieved at the $35^{\circ}C$, $20^{\circ}C$ but $10^{\circ}C$. In the stable nitritation states, nitrite conversion was higher at the high temperature of $35^{\circ}C$ than the room temperature of $20^{\circ}C$. Also shorter solid retention time (SRT) was needed to induce high nitrite conversion at the high temperature of $35^{\circ}C$. It was showed that temperature and SRT are important factors to induce nitritation.

알루미늄 함량에 따른 알루미늄 주철의 내산화성에 관한 연구 (A Study on the Oxidation Resistance of Aluminum Cast Iron by Aluminum Content)

  • 김동혁
    • 한국주조공학회지
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    • 제40권6호
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    • pp.135-145
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    • 2020
  • Aluminum cast iron has excellent oxidation resistance, sulfurization resistance, and corrosion resistance. However, the ductility at room temperature is insufficient, and at temperatures above 600?, the strength drops sharply and practicality is limited. In the case of heat-resistant cast iron, high-temperature materials containing Cr and Ni account for 30 to 50% or more. However, these high-temperature materials are expensive. Aluminum heat-resistant cast iron is considered as a substitute for expensive heat-resistant materials. Oxidation due to the aging temperature and holding time conditions increases more in 0 wt.% Al-cast iron than in 2 and 4 wt.% Al-cast iron according to oxidized weight and gravimetric oxide layer thickness measurements. As a result of observing the cross-section of the oxide layer, it was found to contain 0 wt.% of Al-cast iron silicon oxide-containing SiO2 or Fe2SiO4 oxide film. In cast iron containing aluminum, the thickness of the internal oxide layer due to aluminum increases as the aging temperature and retention time increase, and the amount of the iron oxide layer generated on the surface decreases.

Characteristics of Si Nano-Crystal Memory

  • Kwangseok Han;Kim, Ilgweon;Hyungcheol Shin
    • JSTS:Journal of Semiconductor Technology and Science
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    • 제1권1호
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    • pp.40-49
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    • 2001
  • We have developed a repeatable process of forming uniform, small-size and high-density self-assembled Si nano-crystals. The Si nano-crystals were fabricated in a conventional LPCVD (low pressure chemical vapor deposition) reactor at $620^{\circ}c$ for 15 sec. The nano-crystals were spherical shaped with about 4.5 nm in diameter and density of $5{\times}l0^{11}/$\textrm{cm}^2$. More uniform dots were fabricated on nitride film than on oxide film. To take advantage of the above-mentioned characteristics of nitride film while keeping the high interface quality between the tunneling dielectrics and the Si substrate, nitride-oxide tunneling dielectrics is proposed in n-channel device. For the first time, the single electron effect at room temperature, which shows a saturation of threshold voltage in a range of gate voltages with a periodicity of ${\Delta}V_{GS}\;{\approx}\;1.7{\;}V$, corresponding to single and multiple electron storage is reported. The feasibility of p-channel nano-crystal memory with thin oxide in direct tunneling regime is demonstrated. The programming mechanisms of p-channel nano-crystal memory were investigated by charge separation technique. For small gate programming voltage, hole tunneling component from inversion layer is dominant. However, valence band electron tunneling component from the valence band in the nano-crystal becomes dominant for large gate voltage. Finally, the comparison of retention between programmed holes and electrons shows that holes have longer retention time.

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Ferroelectric-gate Field Effect Transistor Based Nonvolatile Memory Devices Using Silicon Nanowire Conducting Channel

  • Van, Ngoc Huynh;Lee, Jae-Hyun;Sohn, Jung-Inn;Cha, Seung-Nam;Hwang, Dong-Mok;Kim, Jong-Min;Kang, Dae-Joon
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.427-427
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    • 2012
  • Ferroelectric-gate field effect transistor based memory using a nanowire as a conducting channel offers exceptional advantages over conventional memory devices, like small cell size, low-voltage operation, low power consumption, fast programming/erase speed and non-volatility. We successfully fabricated ferroelectric nonvolatile memory devices using both n-type and p-type Si nanowires coated with organic ferroelectric poly(vinylidene fluoride-trifluoroethylene) [P(VDF-TrFE)] via a low temperature fabrication process. The devices performance was carefully characterized in terms of their electrical transport, retention time and endurance test. Our p-type Si NW ferroelectric memory devices exhibit excellent memory characteristics with a large modulation in channel conductance between ON and OFF states exceeding $10^5$; long retention time of over $5{\times}10^4$ sec and high endurance of over 105 programming cycles while maintaining ON/OFF ratio higher $10^3$. This result offers a viable way to fabricate a high performance high-density nonvolatile memory device using a low temperature fabrication processing technique, which makes it suitable for flexible electronics.

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미이용 목질폐잔재의 탄화 이용개발(I) -수종의 간벌재 탄화와 탄화물의 특성- (Development of Carbonization Technology and Application of Unutilized Wood Wastes(I) -Carbonization and It's Properties of Thinned Trees-)

  • 김병로;공석우
    • Journal of the Korean Wood Science and Technology
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    • 제27권2호
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    • pp.70-77
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    • 1999
  • 목질폐잔재중 용이하게 입수할 수 있는 간벌재를 이용하여 그 기초적 제탄 기술을 검토하고, 이 탄화물을 이용하여 토양개량, 탈취, 수분 등의 흡착, 미생물활동 담체, 하천등 수질정화제 등으로 이용하는데 기초자료를 얻을 목적으로 탄화물의 성능을 조사하였다. 간벌재의 공업분석결과 회분 0.22~0.73%, 휘발분 77~80%, 고정탄소 약 10~14% 범위로 나타났다. 간벌재의 탄화 수율은 온도가 높아질수록, 탄화시간이 길수록 낮게 나타났고 수축률은 높게 나타났다. 수율은 낙엽송, 리기다소나무, 소나무가 높았고, 잣나무, 굴참나무가 낮았다. 탄화에 의한 수축률은 목재의 수분에 의한 수축률과 같은 경향을 나타냈다. 탄화후 비중은 각 수종에서 약 50% 감소했다. 탄화물의 공업분석은 회분 0.89~4.08%, 휘발분 6.31~13.79%, 고정탄소 73.9~83.5% 였다. 수소이온농도는 온도가 높아질수록, 탄화시간이 길수록 높게 나타났다. 탄화온도 $400^{\circ}C$의 경우 약 pH 7.5를 나타냈고, $600^{\circ}C$$800^{\circ}C$의 경우는 차이가 거의 없이 약 pH 10정도를 나타냈다. 보수성은 본 실험의 탄화온도와 시간의 조건에 따른 영향 없이 비슷한 값을 나타냈다. 초기 24시간 내의 보수성은 시료무게의 약 2.5~3배 정도이고, 그후 평형함수율은 2~10%의 범위를 나타냈다.

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투.보수성 시멘트 콘크리트 포장의 열물성 및 수분보유특성이 표면온도에 미치는 영향 (Effects of Thermal Properties and Water Retention Characteristics of Permeable Concrete Pavement on Surface Temperature)

  • 류남형;유병림
    • 한국조경학회지
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    • 제34권1호
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    • pp.21-36
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    • 2006
  • This study was undertaken to analyze the effects of pavement thermal properties and water retention characteristics on the surface temperature of the gray permeable cement concrete pavement during the summer. Following is a summary of major results. 1) The hourly surface temperature of pavement could be well predicted with a heat transfer model program that incorporated the input data of major meteorological variables including solar radiation, atmospheric temperature, dew point, wind velocity, cloudiness and the evaporation rate of the pavements predicted by the time domain reflectometry (TDR) method. 2) When the albedo was changed to 0.5 from an arbitrary starting condition of 0.3, holding other variables constant, the peak surface temperature of the pavement dropped by 11.5%. When heat capacity was changed to $2.5\;kJm^{-3}K^{-1}\;from\;1.5\;kJm^{-3}K^{-1}$, surface temperature dropped by 8.0%. When daily evaporation was changed to 1 mm from 2 mm, temperature dropped by 5.7%. When heat conductivity was changed to $2.5\;Wm^{-1}K^{-1}\;from\;1.5\;Wm^{-1}K^{-1}$, the peak surface temperature of the pavement fell by 1.2%. The peak pavement surface temperature under the arbitrary basic condition was $24.46^{\circ}C$ (12 a.m.). 3) It accordingly became evident that the pavement surface temperature can be most effectively lowered by using materials with a high albedo, a high heat capacity or a high evaporation at the pavement surface. The glare situation, however, is intensified by raising of the albedo, moreover if reflected light is absorbed into surrounding physical masses, it is changed into heat. It accordingly became evident that raising the heat capacity and the evaporative capacity may be the moot acceptable measures to improve the thermal characteristics of the pavement. 4) The sensitivity of the surface temperature to major meteorological variables was as follows. When the daily average temperature changed to $0^{\circ}C\;from\;15^{\circ}C$, holding all other variables constant, the peak surface temperature of the pavement decreased by 56.1 %. When the global solar radiation changed to $200\;Wm^{-2}\;from\;600\;Wm^{-2}$, the temperature of the pavement decreased by 23.4%. When the wind velocity changed to $8\;ms^{-1}\;from\;4\;ms^{-1}$, the temperature decreased by 1.4%. When the cloudiness level changed to 1.0 from 0.5, the peak surface temperature decreased by 0.7%. The peak pavement surface temperature under the arbitrary basic conditions was $24.46^{\circ}C$ (12 a.m.)

Determination of Thiamine in Pharmaceutical Preparations by Reverse Phase Liquid Chromatography Without Use of Organic Solvent

  • Suh, Joon Hyuk;Kim, Junghyun;Jung, Juhee;Kim, Kyunghyun;Lee, Seul Gi;Cho, Hyun-Deok;Jung, Yura;Han, Sang Beom
    • Bulletin of the Korean Chemical Society
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    • 제34권6호
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    • pp.1745-1750
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    • 2013
  • A novel green aqueous mobile phase modified with room temperature ionic liquids (RTILs) was employed in the absence of volatile organic solvents or ion-pairing reagents to analyze thiamine, a very polar compound, by reverse phase high performance liquid chromatography (RP-HPLC). Due to its strongly hydrophilic nature, thiamine was eluted near the column dead time ($t_0$) using a mobile phase without adding RTILs or ion-pairing reagents, even if a 100% aqueous mobile phase, which has weak elution power under reverse phase conditions, was used. Thus, 1-ethyl-3-methyl-imidazolium hexafluorophosphate ([EMIM][$PF_6$]), which has the strongest chaotropic effect, was selected as a mobile phase additive to improve retention and avoid baseline disturbances at $t_0$. Various mobile phase parameters such as cation moiety, chaotropic anion moiety, pH and concentration of RTILs were optimized to determine thiamine at the proper retention time. Method validation was performed to assess linearity, intra- and inter-day accuracy and precision, recovery and repeatability; all results were found to be satisfactory. The developed method was also compared to the current official United States Pharmacopoeia (USP) and Korean Pharmacopoeia (KP) methods using an organic mobile phase containing an ionpairing reagent by means of evaluating various chromatographic parameters such as the capacity factor, theoretical plate number, peak asymmetry and tailing factor. The results indicated that the proposed method exhibited better efficiency of thiamine analysis than the official methods, and it was successfully applied to quantify thiamine in pharmaceutical preparations.

하수처리장에서 발생하는 고농축 잉여슬러지의 열적가용화 특성에 관한 연구 (A Study on the Thermal Solubilization Characteristics of Highly Thickened Excess Sludge in Municipal Wastewater Treatment Plant)

  • 김은혁;박명수;구슬기
    • 유기물자원화
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    • 제30권4호
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    • pp.5-13
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    • 2022
  • 현대의 환경문제는 다량의 폐기물의 발생과 무분별한 에너지의 소비로 인한 환경오염이 가속화 되고 있다는 것이다. 대표적인 에너지 생산 연료인 화석연료는 에너지를 생산하는 과정에서 연소가 이루어져 다량의 온실가스가 발생하고 최종적으로 기후변화를 야기한다. 또한 전 세계적으로 발생하는 폐기물의 양도 지속적으로 증가하고 있으며 처리하는 과정에서 환경오염이 발생하고 있다. 이와 같은 문제들을 동시에 해결하기 위한 방법 중 하나는 유기성 폐기물의 에너지화 및 감량화이다. 하수처리장에서 발생하는 하수슬러지는 해양매립이 전면 금지된 이후로 다양하게 처리되고 있으나, 그 발생량은 지속적으로 증가하는 추세이다. 하수슬러지는 유기물을 다량 함유하고 있어 혐기소화를 통하여 하수슬러지를 에너지화 하고 최종 배출되는 폐기물을 감량화 하는 것이 바람직하다. 하지만, 잉여슬러지의 경우 대부분이 하수처리에 이용되었던 미생물 덩어리로써 잉여슬러지가 혐기성소화 되기 위해서는 먼저 미생물의 세포벽이 파괴되어야 하는데 세포벽 파괴에는 많은 시간이 요구되기 때문에 혐기성 소화 과정만으로는 높은 바이오가스 생산율이나 폐기물 감량율을 달성할 수 없다. 따라서 잉여슬러지를 가용화하는 전처리 공정이 필요하며, 여러 가지 가용화 공법 중에서 열적 가용화 공정이 가장 효율적인 것으로 검증되었고, 혐기성소화 공정의 전처리 과정으로써 열적가용화 공정을 이용하여 잉여슬러지에 포함된 세포벽을 파괴한 후 전처리 된 잉여슬러지를 혐기성소화 함으로써 높은 바이오가스 생산율과 폐기물 감량율을 달성할 수 있다. 본 연구에서는 열적 가용화장치를 통하여 TS 10%의 농축 잉여슬러지를 전처리하는데 있어서 체류시간 및 운전온도 변수에 따른 가용화 특성에 대한 연구를 수행하였다. 열적 가용화장치의 체류시간에 대한 실험변수는 운전온도를 160 ℃로 고정한 상태에서 각각 30분, 60분, 90분, 120분이었다. 실험 결과로 도출된 TCOD와 SCOD를 통해 계산된 가용화율은 각각 12.11%, 20.52%, 28.62%, 31.40% 순으로 증가하였다. 또한, 운전온도에 따른 변수는 반응시간을 60분으로 고정한 상태에서 각각 120℃, 140℃, 160℃, 180℃, 200℃였으며 가용화율은 각각 7.14%, 14.52%, 20.52%, 40.72%, 57.85% 순으로 증가하였다. 이 외에 TS, VS, T-N, T-P, NH4+-N, VFAs를 분석하여 농축 잉여슬러지를 대상으로 하는 열적 가용화 특성에 대한 평가를 수행 했으며, 그 결과 TS 10%의 농축 잉여슬러지에 대한 열적 가용화를 통하여 30% 이상의 가용화율을 얻기 위해서는 운전온도를 160℃로 고정할 경우 120분의 체류시간이 필요하며, 운전시간을 60분으로 고정할 경우 170℃ 이상의 운전온도가 요구되어 진다.

호기성 침지형 생물막 여과장치를 이용한 오수처리 (Sewage Treatment using Aerated Submerged Biological Filter(ASBF))

  • 박종웅;송주석
    • 한국물환경학회지
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    • 제16권4호
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    • pp.523-532
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    • 2000
  • The purpose of this study was to investigate the effects of the hydraulic retention time (HRT) and organic loading rate (OLR) on microbial characteristics and treatment efficiency in sewage treatment using aerated submerged biological filter (ASBF) reactor. This reactor combines biodegradation of organic substrates by fixed biomass with a physical separation of biomass by filtration in a single reactor. Both simulated wastewater and domestic wastewater were used as feed solutions. The experimental conditions were a temperature of 17 to $27^{\circ}C$, a hydraulic retention time of 1 to 9hr, an organic loading rate of 0.47 to $3.84kg\;BOD/m^3{\cdot}day$ in ASBF reactor. This equipment could obtain a stable effluent quality in spite of high variation of influent loading rate. Total biomass concentration. biofilm thickness and biofilm mass increased an exponential function according to the increasing OLR. The relationships between water content and biofilm density were in inverse proportion. The percentage of backwash water to influent flow was almost 9%. The separation efficiency of biomass was the percentage of 91 to 92 in ASBF reactor. The sludge production rates in feed solutions of simulated wastewater and domestic wastewater were 0.14~0.26 kg VSS/kg BODrem, 0.43~0.48 kg VSS/kg BODrem, respectively.

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