• Korean Chemical Engineering Research
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• v.56 no.3
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• pp.343-348
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• 2018

Each of the two polycarbonates (PC) of different molecular weights was blended with acrylonitrile-butadiene-styrene (ABS) under high-shear rate processing to afford PC/ABS. Sizes of ABS dispersed phases and mechanical properties of PC/ABS blends were investigated and high-shear rate processing of PC/ABS was carried out by changing screw speed and processing time. Prepared specimens were examined by scanning electron microscope (SEM) to observe morphology changes. Sizes of ABS dispersed phases in PC/ABS blends were observed to decrease gradually as screw speeds increased. Tensile strengths and elongations of specimens were investigated by universal testing method (UTM) to study the influence of molecular weight of PC exerting on PC/ABS blends. As a result, PC1/ABS blends (PC1: higher molecular weight PC) exhibited more strengthened properties than PC2/ABS (PC2: lower molecular weight PC). The tensile strength of PC1/ABS showed an increasing tendency when the screw speed increased, and the elongation did not show a significant decrease, but increased slightly with increasing shear time at a constant screw speed of 1000 rpm.

• Design & Manufacturing
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• v.11 no.2
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• pp.37-41
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• 2017

With light vehicle weight gradually becoming ever more importance due to tightened exhaust gas regulations, hot-stamping processing using boron alloyed steel is being applied more and more by major automobile OEMs since process assures both moldability and a high strength of 1.5 GPa. Although laser trimming is generally applied to the post-processing of the hot-stamped process with high strength, there have been many studies of in-die hot trimming using shear dies during the quenching of material in order to shorten processing times. As such, this study investigated the effects of the Shear rate and Shear mechanism on shear processes during the quenching process of hot-stamping material. In case of pad variable, padding force is very weak compared with shear force, so it does not affect the shear surface. In case of shear rate, the higher the shear at high temperatures and the higher the friction effect. As a result the rollover and the fracture distribution decreased, and the burnish distribution increased. Therefore, it is considered that the shear quality is guaranteed when high shear rate is applied in high temperature shear process.

• Polymer(Korea)
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• v.38 no.3
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• pp.320-326
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• 2014

The effects of high shear rate processing on the thermal properties of PC/ABS blends were studied. It was executed by the high shear processing machine (NHSS2-28) at the varied conditions of screw speeds and loaded duration. After the samples were processed with NHSS2-28, the $T_gs$ were shifted from 143 to $133^{\circ}C$, and the behavior of degradation determined by TGA showed two distinct steps before high shear rate processing, while it showed a straight line after the processing. In order to provide the reasons of the properties, it was showen by SEM and UTM that the droplet sizes morphologically decreased after the processing, and the elongations decreased slightly until 1000 rpm of screw speed and then sharply decreased, according to the conditions of high shear rate processing. Therefore, it can be confirmed that $T_g,s$ of PC/ABS blends were considerably shifted under an appropriate high shear rate condition, and rapidly dropped, so that blends degraded above the condition, due to stress-induced degradation.

• Korean Chemical Engineering Research
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• v.52 no.3
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• pp.382-387
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• 2014

The PC/ABS blends were manufactured with high shear rate processing. Changes of the blend morphology were analyzed according to the screw speed and processing time. To find optimal conditions of the high shear rate processing of the PC/ABS blend, blend morphology and size of the dispersed phase, ABS, were observed with a SEM. Also, tensile properties of the PC/ABS blends were measured to investigate the effect of the high shear rate process with the screw speed of 500 rpm to 3000 rpm for processing times of 10s to 40s. Especially, to observe the dispersed phase of the PC/ABS blend clearly, fracture surfaces of the PC/ABS blend were etched with chromic acid solution. As screw speed and processing time increase, dispersed phase size of the PC/ABS blend decreases and mechanical properties of the blend decrease as well. Especially, at screw speed over than 1000 rpm of high shear rate processing, mechanical properties of the PC/ABS blends decrease drastically due to the degradation of the blend during the high shear rate processing. Consequently, the optimal condition of screw speed of the high shear processing of the PC/ABS blend is set at 1000rpm, in this study. Under optimal condition, the PC/ABS blend has relatively high mechanical properties with the relatively stable micro-structure having nanometer scale dispersed phase.

• Polymer(Korea)
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• v.38 no.4
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• pp.471-476
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• 2014

Polycarbonate (PC) and acrylonitrile-butadiene-styrene (ABS) blends were prepared using a high shear extruder to investigate their thermal decomposition and mechanical properties with shear rate and shear time. In this experiment, high shear rate, from 1000 to 3000 rpm, in blending process was applied for 10 to 40 sec, respectively. At high shear rate over than 2000 rpm, the initial decomposition temperature was dropped significantly compared to a compounded sample because of thermal decomposition of the blend by high shear. Consequently, high shear processing gave an important effect on the mechanical and thermal properties of the PC/ABS blend. In particular, elongation of the blend decreased significantly with shear rate.

• Journal of the Korean Wood Science and Technology
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• v.36 no.5
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• pp.56-65
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• 2008

In this paper experimental results are presented for the rheological behavior of high-solids saccharification of mixed northeast hardwood as a model feedstock. The experimental determination of the viscosity, shear stress, and shear rate relationships of the 10 to 20 percent slurry concentrations with constant enzyme concentrations were performed under variable rotational speed of a viscometer (2.0 to 200 RPM) at combined temperatures (50 to $30^{\circ}C$) for the initial four hours. The viscosities of saccharification slurries observed were in the ranges of 0.024 to 0.028, 0.401 to 0.058, and 0.840 to 0.087 Pa s for shear rates up to 100 reciprocal seconds at 10, 15, and 20 percent initial solids (w/v) respectively. The fluid behavior of the suspensions was modeled using the power-law, the Herschel-Bulkley, the Casson, and the Bingham model. The results showed that broth slurries were pseudoplastic with a yield stress. The model slope increased and the model intercept decreased with increasing fermentation time at shear rates normal for the fermentor. The broth slurries exhibited Newtonian behavior at high and low shear rates during initial saccharification process. The solid particle size ranged from 57.8 to $70.0{\mu}m$ for $40^{\circ}C$ and from 44.0 to 57.5 11m for combined temperatures at 10, 15, and 20 percent initial solids (w/v) respectively.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2003.06a
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• pp.418-421
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• 2003

Specimens of Ti-10Ta-10Nb have been hot upset forged after heating to either the $\alpha$+$\beta$ and $\beta$-phase field. The variety temperatures (At 650, 700, 750, 800, 85$0^{\circ}C$) and strain rates (At 0.001, 0.01. 0.1, 1, 10 $s^{-1}$ ) were used. On the basis of flow stress data obtained as a function of temperature and strain rate in compression, a processing map for hot working has been developed. At strain rates lower than about 0.1 $s^{-1}$ and almost temperatures, processing efficiency exhibited high, but at 0.001 $s^{-l}$, and temperature 80$0^{\circ}C$, low because the Shear band has occurred. On the basis of the processing map, the optimum processing routes available for hot working of this material are outlined.d.

• Journal of Korea Foundry Society
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• v.14 no.5
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• pp.438-446
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• 1994

The effect of various thermomechanical treatments on the structure and rheological behaviour of Al-6.2wt%Si alloy in its solidification range were investigated using a Searle type high temperature viscometer. During continuous cooling, the viscosity increases gradually with increasing fraction of solidified alloy, until a critical fraction of solidified alloy is reached above which the viscosity sharply increases. The viscosity of the slurry, at a given volume fraction wolid, decreased with increasing shear rate. The size and morphology of primary solid particles during stirring is influenced strongly by shear rates, cooling rates, volume fraction and stirring time of solid. Morphological changes during stirring as a function of solid volume fractions, shear rate and processing time were also reported. In this study, the size of primary solid particles in these alloys consistently increases and the it`s aspect ratio decrease with the increase in fraction solid and decrease in shear rate. Crystal morphology changes from rosette type to spheroid type with the increase in shear rate and solid fraction.

• Transactions of Materials Processing
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• v.22 no.5
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• pp.258-263
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• 2013

The deformation behavior of NIMONIC 80A was studied in the high temperature range of $900{\sim}1200^{\circ}C$ and for strain rates varying between 0.02 and $20s^{-1}$ via the hot compression test. Processing maps for hot working were constructed on the basis of the power dissipation efficiency using a dynamic material model. The results showed that the strength during hot compression increased with increasing strain rate and decreasing temperature. At low strains, the processing map of NIMONIC 80A did not reveal any instability domain regardless of the strain rate and temperature. However, at high strains, the processing map exhibited an instability domain at a low strain rate of $0.2s^{-1}$ and within a temperature range of $900{\sim}960^{\circ}C$. In the instability domain, the deformed microstructure exhibited shear bands and carbide precipitation while, in the safe domain, full recrystallization occurred.

• Transactions of Materials Processing
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• v.12 no.4
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• pp.358-363
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• 2003

Adiabatic shear bands have been observed in the serrated chip during high strain rate metal cutting process of medium carbon steel and titanium alloy The recent microscopic observations have shown that dynamic recrystallization occurs in the narrow adiabatic shear bands. However the conventional flow stress models such as the Zerilli-Armstrong model and the Johnson-Cook model, in general, do not predict the occurrence of dynamic recrystallization (DRX) in the shear bands and the thermal softening effects accompanied by DRX. In the present study, a strain hardening and thermal softening model is proposed to predict the adiabatic shear localized chip formation. The finite element analysis (FEA) with this proposed flow stress model shows that the temperature of the shear band during cutting process rises above 0.5Τ$_{m}$. The simulation shows that temperature rises to initiate dynamic recrystallization, dynamic recrystallization lowers the flow stress, and that adiabatic shear localized band and the serrated chip are formed. FEA is also used to predict and compare chip formations of two flow stress models in orthogonal metal cutting with AISI 1045. The predictions of the FEA agreed well with the experimental measurements.s.