• Title/Summary/Keyword: high polymer material

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Flexural Properties of Reinforced Steel and GFRP Reinforced Polymer Concrete T-Beams (철근 및 GFRP 보강 폴리머 콘크리트 T형 보의 휨 특성)

  • Yeon Kyu Seok;Kweon Taek Jeong;Jeong jung Ho;Jin Xing Qi
    • Proceedings of the Korea Concrete Institute Conference
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    • 2004.11a
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    • pp.695-698
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    • 2004
  • Recently, the usage of polymer concrete mortar gathering an interest as a new construction material rapidly increases inside and outside of the country because it is an environment-friendly and endurable material. However, up to these days, the researches about the polymer composite have not been satisfactorily conducted. The polymer concrete is superior to the general cement materials in the properties of strength and durability while it is inferior in elastic modulus. Because that the members using the polymer concrete have therefore higher strength and ductility than the members of general cement concrete, an analysis equation of high-strength cement concrete can be referenced but it is not applied for the researches about the polymer concrete members. In this study, the flexural properties of T-shaped beam of the steel- and GFRP-reinforced polymer concrete are analyzed to examine the suggested analysis equation. Results of this experimental researches are to be used as the basic data in a structural design of the polymer concrete.

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Performance Evaluation of Polymer Insulator using Tracking Wheel and Multi-Aging Test (트래킹 휠과 복합열화시험에 의한 폴리머 애자의 성능 평가)

  • 조한구;안명상;한세원;허종철;이운용
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.119-122
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    • 2000
  • Recently polymer insulators are being used for outdoor high voltage applications. Polymer insulators for transmission line have significant advantages over porcelain and glass insulators, especially for ultra-high voltage transmission lines. Their advantages are light weight, vandalism resistance and hydrophobicity. Polymer insulators are a relatively new technology, but their expected life is still unknown. Therefore these estimating technique are very important. Their life time is related to weathering and operating condition. Multi-aging test is requested because aging factor is occurred by multi-aging than unique aging. The aging test about polymer insulators have mainly carried out by IEC 61109. This paper presents multi-stress chamber experiments and tracking wheel test to examine the tracking and erosion performance of polymer insulator for transmission. Multi-stress testing is able to demonstrate deficiencies of polymer insulator materials and designs, including the nature of interfaces in insulation design. We have investigated IEC 61109 Annex C (5000h aging test) and CEA tracking wheel test as test methods of artificial accelerated aging. The aging degree of polymer insulator is estimated by leakage current, measurement of hydrophobicity degree, damage conditions of insulator surface, withstand voltage test etc.

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Generation of High Pretilt Angle for Nematic Liquid Crystal on Blended Polyimide Surfaces Containing Fluorine Moiety (Fluorine 계열의 폴리머를 함유한 복합 폴리이미드 표면에서의 네마틱 액정의 고 프리틸트 발생)

  • Hwang, Jeoung-Yeon;Lee, Kyung-Jun;Seo, Dae-Shik
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.949-952
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    • 2002
  • The mechanisms of pretilt angle generation for a nematic liquid crystal (NLC) with negative dielectric anisotropy on the blended polyimide (PI) surface containing trifluoromethyl moiety was studied. High LC pretilt angle on the blended polymer surface with F3 was measured and the pretilt angle increased with rubbing strength. However, the low LC pretilt angle on the blended polymer surface with F1 and F2 was measured. The high LC pretilt angle generated is attributable to trifluoromethyl moiety in backbone structure on the blended PI surface. Therefore, the high pretilt angle of NLC can be achieved by using the blended polymer surface.

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Synthesis and Properties of High Voltage Silicone Rubber by Platinum-based Flame Retardant

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • v.7 no.6
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    • pp.283-292
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    • 2006
  • So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

In-Situ Cross-linked Polymer Electrolyte Membranes from Thermally Reactive Oligomers for Direct Methanol Fuel Cells

  • Kim, Hae-Kyoung;Lee, Won-Mok;Park, Sam-Dae;Chang, Yoon-Ju;Jung, Jin-Chul;Chang, H.
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.271-271
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    • 2006
  • The present article describes a novel method of preparing the sulfonated polysulfone-based PEMs for DMFC, which are excellent in film quality, proton conductivity, methanol impermeability and mechanical properties. No depression in film quality or difficulty in film preparation is observed, even though sulfonated group of the PEMs are kept as high as 70 mol %. Allyl-terminated cooligo-PESs containing the organic sulfonate groups were solvent-cast into films and then thermally treated for cross-linking. Cross-linked sulfonated polysulfone-based PEMs gave unprecedented reduction of methanol cross-over and high ionic conductivity through in-situ thermal polymerization and cross-linking of telechelic sulfonated sulfone oligomers during a membrane preparation.

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STUDY PROCESSES OF INTUMESCENCE IN FIRE-PROTECTING COATINGS

  • Efremov, V.L.;Paltseva, N.G.;Leiman, Z.A.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.657-658
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    • 2005
  • Flame retard of polymers was studied for prevention from burning by various additives stimulated the char formation during heating and thermal degradation of polymer materials. Forming char have high porosity, low thermal conductivity and act as thermal shield for heat transmission from the flame to the polymer and. oxygen towards the polymer. The results showed that various additives may regulate the processes of intumecsence. The efficient fire protective intumescent char was result of processes of melting, gas evolution, cross-linking, carbonization etc.

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A Study on Electrochemical Properties of Acrylate-based Gel Polymer Electrolyte with Ethylene Oxide Group (Ethylene Oxide기를 갖는 Acrylate계 Gel Polymer Electrolyte의 전기화학적 특성에 관한 연구)

  • Kim, Hyun-Soo;Shin, Jung-Han;Moon, Seong-In;Oh, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.17 no.6
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    • pp.608-614
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    • 2004
  • The gel polymer electrolyte was prepared by radical polymerization using tetra(ethylene glycol) diacrylate and tri(ethylene glycol) dimethacrylate to investigate affect of the number of ethylene oxide. The gel polymer electrolyte showed good electrochemical stability up to 4.5 V vs. Li/Li and high ionic conductivity at various temperatures. The lithium-ion polymer batteries with the gel polymer electrolyte, tetra(ethylene glycol) diacrylate- and tri(ethylene glycol) dimethacrylate-based, also represented good electrochemical performances such as rate capability, low-temperature performances and cycleability. However, the cell with tri(ethylene glycol) dimethacrylate, which has three ethylene oxide, showed better electrochemical performance.

Designing of a Novel Core-Shell-Structured Co-free Cathode Material with Enhanced Thermal and Structural Stability for Lithium Ion Batteries

  • Shin, Ji-Woong;Nam, Yun-Chae;Son, Jong-Tae
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.172-176
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    • 2019
  • The first commercialized cathode material, $LiCoO_2$, suffers from disadvantages such as high cost and toxicity and also possesses safety problems. The nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material, used as an alternative to $LiCoO_2$, has highly reversible capacity and high energy density. So, the nickel-rich $LiNi_{0.9}Mn_{0.1}O_2$ cathode material is widely used as an alternative to $LiCoO_2$ due to its highly reversible capacity and high energy density. However, $LiNi_{0.9}Mn_{0.1}O_2$ has several disadvantages as well, such as poor cycle performance and poor thermal instability. To address these problems, we synthesized a new material, $LiNi_{0.5}Mn_{0.5}O_2$, as a shell on the surface of a core to suppress the surface degradation. The new material showed high structural and thermal stabilities and could also maintain a high capacity. The capacity retention of the core-shell cathode (87.7%) was better than that of the core cathode (76.9%) after 50 cycles. Analysis using differential scanning calorimetry revealed that the heat generation in the core-shell cathode ($65.9Jg^{-1}$) was lower than that in the core cathode ($559.7Jg^{-1}$).

High Temperature Properties of Cement Mortar Using EVA, EVCL Redispersible Polymer Powder and Fly Ash (EVA, EVCL 분말수지와 플라이애시를 혼입한 시멘트 모르타르의 고온특성)

  • Song, Hun;Shin, Hyeonuk
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.6 no.4
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    • pp.365-372
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    • 2018
  • 3D printing technology of construction field can be divided into structural materials, interior and exterior finishing materials, and is mainly done by extruding and adapting. Particularly when it is applied as an exterior materials, it is mainly applied to an unstructured exterior materials and high accuracy is required. The exterior materials can be used as a cement composite materials, it is suitable also for a additive type manufacturing, and the role of a redispersible polymer powder is important. But, high temperatures, redispersible polymer cement base material beget dehydration and micro crack of cement matrix. In this research, we developed a EVA, EVCL redispersible polymer cement base material applicable as a 3D printing exterior materials, confirmed density and strength characteristics for application as an exterior materials, a flame retardancy test for improving the fire resistance of buildings and confirmed its possibility. From the test result, developed EVCL redispersible polymer cement mortar showed good stability in high temperatures. These high temperature stability is caused by the ethylene-vinyl chloride binding. Thus, this result indicates that it is possible to fire resistant 3D printing interior and exterior finishing materials.

Development of High-Performance Lining Material for Fume Pipe (고성능 흄관 라이닝 재료 개발)

  • Lee, Youn-Su;Joo, Myung-Ki
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2003.10a
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    • pp.391-394
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    • 2003
  • Effects of the polymer-binder ratio and slag content on the properties of combined wet/dry-cured polymer-modified mortars using granulated blast-furnace slag are examined. Results shows that the flexural, compressive, tensile and adhesion in tension strengths of polymer-modified mortar using the slag tend to increase with increasing slag content, and is inclined to increase with increasing polymer-binder ratio. In particular, the polymer-modified mortars with slag content of 40% provide about 20% higher tensile strength than unmodified mortars. Such high strength development is attributed to the high tensile strength of polymer and the improved bond between cement hydrates and aggregates because of the addition of polymer.

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