• Title/Summary/Keyword: high nitrogen steel

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Corrosion and Nanomechanical Behaviors of 16.3Cr-0.22N-0.43C-1.73Mo Martensitic Stainless Steel

  • Ghosh, Rahul;Krishna, S. Chenna;Venugopal, A.;Narayanan, P. Ramesh;Jha, Abhay K.;Ramkumar, P.;Venkitakrishnan, P.V.
    • Corrosion Science and Technology
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    • v.15 no.6
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    • pp.281-289
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    • 2016
  • The effect of nitrogen on the electrochemical corrosion and nanomechanical behaviors of martensitic stainless steel was examined using potentiodynamic polarization and nanoindentation test methods. The results indicate that partial replacement of carbon with nitrogen effectively improved the passivation and pitting corrosion resistance of conventional high-carbon and high- chromium martensitic steels. Post-test observation of the samples after a potentiodynamic test revealed a severe pitting attacks in conventional martensitic steel compared with nitrogen- containing martensitic stainless steel. This was shown to be due to (i) microstructural refinement results in retaining a high-chromium content in the matrix, and (ii) the presence of reversed austenite formed during the tempering process. Since nitrogen addition also resulted in the formation of a $Cr_2N$ phase as a process of secondary hardening, the hardness of the nitrogen- containing steel is slightly higher than the conventional martensitic stainless steel under tempered conditions, even though the carbon content is lowered. The added nitrogen also improved the wear resistance of the steel as the critical load (Lc2) is less, along with a lower scratch friction coefficient (SFC) when compared to conventional martensitic stainless steel such as AISI 440C.

Properties of As-casted High Nitrogen Steel for Core of Over-head Transmission Line (가공 송전선 강심용 고질소강 주조재의 제특성)

  • Yoo, Kyung-Jae;Kim, Bong-Seo;Kwon, Hae-Woong;Kim, Byung-Geol;Lee, Hee-Woong
    • Proceedings of the KIEE Conference
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    • 1998.11c
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    • pp.861-863
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    • 1998
  • As-casted high nitrogen alloys (Fe-25%Mn-12%Cr-1%Ni) have been investigated to study core material. Nitrogen concentration in molten alloys was increased with increasing the square root of nitrogen gas pressure in melting chamber. This result can be explained by Sievert's law. Nitrogen that dissolved as a interstital solid solution element in austenite stainless steel increased lattice parameter and hardness. Electric resistivity($\rho$) was increased with increasing nitrogen concentration and was about $80{\mu}{\Omega}cm$ at room temperature. Coefficient of linear thermal expansion of the nitrogen steel was about $22{\times}10^{-6}/^{\circ}C$.

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Mechanical Properties and Microstructures of High Heat Input Welded Tandem EGW Joint in EH36-TM Steel (대입열 EH36-TM강의 Tandem EGW 용접부 미세조직 및 기계적 성질)

  • Jeong, Hong-Chul;Park, Young-Hwan;An, Young-Ho;Lee, Jong-Bong
    • Journal of Welding and Joining
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    • v.25 no.1
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    • pp.57-62
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    • 2007
  • In the coarse grained HAZ of conventional TiN steel, most TiN particles are dissolved and austenite grain growth easily occurrs during high heat input welding. To avoid this difficulty, thermal stability of TiN particles is improved by increasing nitrogen content in EH36-TM steel. Increased thermal stability of TiN particle is helpful for preventing austenite grain growth by the pinning effect. In this study, the mechanical properties and microstructures of high heat input welded Tandem EGW joint in EH36-TM steel with high nitrogen content were investigated. The austenite grain size in simulated HAZ of the steel at $1400^{\circ}C$ was much smaller than that of conventional TiN steel. Even for high heat input welding, the microstructure of coarse grained HAZ consisted of fine ferrite and pearlite and the mechanical properties of the joint were sufficient to meet all the requirements specified in classification rule.

Sliding Wear Mechanism of the High-Nitrogen Austenitic 18Cr-l8Mn-2Mo-0.9N Steel (고질소 Fe-l8Cr-l8Mn-2Mo-0.9N 강의 미끄럼 마멸 기구)

  • Kim, S.D.;Kim, S.J.;Kim, Y.S.
    • Transactions of Materials Processing
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    • v.15 no.2 s.83
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    • pp.112-117
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    • 2006
  • Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of IN-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution ($1050^{\circ}C$) and isothermal aging ($900^{\circ}C$) heat treatments were performed on the steel and the effect of the heat treatments on the wear was investigated. Wear rates of the solution-treated steel specimen remained low until 5N load, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. The transformed phase underneath a sliding track was investigated and analyzed using a TEM. Effects of the phase transformation during the wear and $Cr_{2}N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

Sliding wear mechanism of the high-nitrogen austenitic 18Cr-18Mn02Mo-0.9N steel (고질소 Fe-18Cr-18Mn-2Mo-0.9N강의 미끄럼 마멸 기구)

  • Kim S. D.;Kim S. J.;Kim Y. S.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.10a
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    • pp.105-108
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    • 2005
  • Sliding wear mechanism of a high nitrogen austenitic 18Cr-18Mn-2Mo-0.9N steel has been investigated. Dry sliding wear tests of the steel were carried out at various loads of 1N-10N under a constant sliding speed condition of 0.15m/s against AISI 52100 bearing steel balls. Solution $(1050^{\circ}C)$ and isothermal aging $(900^{\circ}C)$ heat treatments were performed on the steel and the effect of the heat treatments on the wear were investigated. Wear rates of the solution-treated steel specimen remained low until 5N, and then increased abruptly at loads above 5N. The rates of isothermally aged specimens were low and increased gradually with the applied load. Worn surfaces, their cross sections, and wear debris of the steel specimens were examined with a scanning electron microscopy. Phases of the heat-treated specimen and the wear debris were identified using XRD. Phases transformed underneath the sliding track during the wear were investigated and analyzed using TEM. Effects of the phase transformation during the wear and $Cr_2N$ precipitates formed during the isothermal aging on the wear of the austenitic steel were discussed.

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Development of a High Strength Conductor for Long Span (장경간용 고강도 가공송전선 개발)

  • Kim, Byung-Geol;Kim, Shang-Shu
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.521-522
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    • 2007
  • A new high strength conductor was designed for long span transmission line with a high nitrogen steel having high tensile strength and non-magnetic properties and high strength AI alloy. The tensile strength of conductor is very important to reduce the sag. The height of electric tower depend on the sag also. More than 36% less of sag was achieved by using ACHR(Aluminum conductor stranded high-nitrogen steel reinforced) instead of conventional ACSR.

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Microstructure and High Temperature Deformation Behavior of Heat Resistant Stainless Steel for a Retort (열환원반응관용 내열강의 미세조직과 고온변형거동)

  • Choi, G.S.;Ha, T.K.
    • Transactions of Materials Processing
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    • v.22 no.3
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    • pp.165-170
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    • 2013
  • High temperature deformation behavior of a heat-resistant duplex stainless steel, used as a retort in the Pidgeon process for Mg production, was investigated in this study. 25Cr-8Ni based duplex stainless steels were cast into rectangular ingots, with dimensions of $350mm{\times}350mm{\times}100mm$. Nitrogen and yttrium were added at 0.3wt.% each to enhance the heat-resistance of the steel. Phase equilibrium was calculated using the thermodynamic software FactSage$^{(R)}$ and the database of FSStel. For comparison, cast 310S steel, a widely used heat-resistant austenitic stainless steel, was also examined in this study. Dilatometry was conducted on the as-cast ingots for the temperature range from RT to $1200^{\circ}C$ and the thermal expansion coefficients were evaluated. The nitrogen addition was found to have an effect on the thermal expansion behavior for temperatures between 800 and $1000^{\circ}C$. High temperature tensile and compression tests were conducted on the ingots for temperatures ranging from 900 to $1230^{\circ}C$, which is the operation temperature employed in Mg production by the Silico-thermic reduction process. The steel containing both N and Y showed much higher strength as compared to 310S.

High Nitrogen Steel for Core of Over-head Transmission Line (가공송전선 코아용 고질소강 연구)

  • Kim, Bong-Seo;Yoo, Kyung-Jae;Kwon, Hae-Woong;Lee, Hee-Woong;Kim, Byung-Geol
    • Proceedings of the KIEE Conference
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    • 1998.07d
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    • pp.1555-1557
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    • 1998
  • In order to investigate the core material for over-head transmission line with non-magnetic and high strength nitrogen steel, microstructure and several basic properties of Fe-Mn-Cr-Ni-N steel have been studied. It is necessary that core material have a $\gamma$ phase to have a non-magnetic characteristics. To acquire a $\gamma$ phase, Mn, Ni and C are added as a alloying element. It was found that Fe-25Mn-16Cr-1Ni-N alloy have a stable $\gamma$ phase. The precipitate from this alloy system was $(Cr, Fe)_7C_3$. High Mn and N steel satisfies Sievert's relation that solubility of nitrogen increases with the square root of partial pressure of gas in metal-gas system and the hardness have proportional relation with nitrogen concentration.

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Effect of Nitrogen Gas Pressure on the Property of TiN-Coated Layer of High Speed Steel by Arc ion Plating (AIP 법에서 질소가스 압력이 고속도강의 TiN 코팅층 성질에 미치는 영향)

  • Kim, Hae-Ji;Joun, Man-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.7
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    • pp.124-130
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    • 2008
  • The effect of nitrogen gas pressure in arc ion plating on surface properties of the TiN-coated high speed steel(SKH51) is presented in this paper. The surface roughness, micro-particle, micro-hardness, coated thickness, atomic distribution of TiN, and adhesion strength are measured fur various nitrogen gas pressures. It has been shown that the nitrogen gas pressure has a considerable effect on the surface roughness, adhesion strength, atomic distribution of TiN, and surface deposition of TiN of the high speed steels but that it has little influence on the micro-hardness and coated thickness.

Deformation Behavior & Rolling Effect on the Hot Rolling of High Nitrogen Stainless Steel (고질소강의 열간압연시 변형거동 및 압연효과)

  • Kim, Y.D.;Kim, D.K.;Lee, J.W.;Bae, W.B.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2008.10a
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    • pp.329-332
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    • 2008
  • Nowadays, It is required human body-friendly, good mechanical properties, and economical efficiency material, simultaneously. The material to meet above requirement condition rear up high nitrogen stainless steel(HNS). However, HNS have a lot of problem such as poor workability, hot crack sensitivity. So, It is needed the condition of plastic working to overcome above many problem. In this study, VIM ingot with 100kg was made by pressurized vacuum induction melting. And then, The slab perform for hot rolling was prepared by open-die forging. Hot rolling process was performed by computer simulation according to change of height reduction, rolling temperature, heating numbers, rolling pass and so forth. The results of analysis were investigated between analysis and lab-scale rolling product.

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