• Title/Summary/Keyword: high current density

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Sulfur Poisoning of Ni Anode as a Function of Operating Conditions in Solid Oxide Fuel Cells (고체산화물 연료전지의 운전 조건에 따른 니켈 전극 황 피독 현상)

  • Lee, Ho Seong;Lee, Hyun Mi;Lim, Hyung-Tae
    • Korean Journal of Metals and Materials
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    • v.56 no.12
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    • pp.893-899
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    • 2018
  • In the present study, we investigated the sulfur poisoning of the Ni anode in solid oxide fuel cells (SOFCs) as a function of operating conditions. Anode supported cells were fabricated, and sulfur poising tests were conducted as a function of current density, $H_2S$ concentration and humidity in the anode gas. The voltage drop was significant under the higher current density (${\sim}714mA/cm^2$) condition, while it was much reduced under the lower current density (${\sim}389mA/cm^2$) condition, at 100 ppm of $H_2S$. A secondary voltage drop, which occurred only at the high current density, was attributed to Ni oxidation in the anode. Thus, operation at high current density with high $H_2S$ concentration may lead to permanent deterioration in the anode. The effect of water content (10%) on the sulfur poisoning was also investigated through a constant current test (${\sim}500mA/cm^2$) at 10 ppm of $H_2S$. The cell operating with 10% wet anode gas showed a much smaller initial voltage drop, in comparison with a dry anode gas. The present study indicates that operating conditions, such as gas humidity and current density, should be carefully taken into account, especially when fuel cells are operated with $H_2S$ containing fuel.

High Current Density Bi-2223 Tapes in Electrotechnical devices (전력기기에서 고전류밀도 Bi-2223테이프)

  • 류경우;최병주;성기철;류강식
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.43-45
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    • 2002
  • High current density Bi-2223 tapes have recently become commercially available. There are some important characteristics of the tapes, e.g. critical current, ac loss, fault current characteristics, for an application such as a power cable or a power transformer. They have been investigated experimentally and discussed in this paper.

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Performance Analysis of SOFC/MGT Hybrid System

  • Kim, Jae-Hwan;Suzuki, Kenjiro
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.703-707
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    • 2001
  • A performance analysis of a SOFC/MGT hybrid system has been carried out for concept design. Thermo-dynamic models for each component being able to describe electrochemical characteristics and heat and mate-rial balance are proposed. Estimated is the power capacity of a SOFC suitable for the hybrid operation with a 5kW class MGT. Effects of current density and operating pressure are also investigated. Electric efficiency showed weak dependence on operating pressure and current density. It is desirable that the SOFC operates at high current density in manufacturing cost's point of view though operating with high current density slightly decreases the electric efficiency find specific power.

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AC Loss Characteristics of a Single-layered Cylindrical High Temperature Superconductor (단층원통형 고온초전도도체의 교류손실 특성)

  • Ma, Yong-Hu;Li, Zhu-Yong;Ryu, Kyung-Woo;Sohn, Song-Ho;Hwang, Si-Dol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.626-630
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    • 2007
  • The AC loss is an important issue in the design of the high temperature superconductor (HTS) power cables and fault current limiters. In these applications, a cylindrical HTS conductor is often used. In commercialization of these apparatuses, AC loss is a critical factor but not elucidated completely because of complexities in its measurement, e.g. non-uniform current distribution and phase difference between currents flowing in an individual HTS tape. We have prepared two cylindrical conductors composed of a Bi-2223 tape with different critical current density. In this paper, the AC loss characteristics of the conductors have been experimentally investigated and numerically analyzed. The result show that the measured losses for two conductors are not dependent on both arrangements and contact positions of a voltage lead. This implies that most of loss flux is only in the conductors. The loss for the Bi-2223 conductor with low critical current density is in good agreement with the calculated loss from Monoblock model, whereas the loss measured for the Bi-2223 conductor with high critical current density doesn't coincide with the loss calculated from the Monoblock model. The measured loss is also different from numerically calculated one based on the polygon model especially in low transport current.

$100 A/mm^2$ Class Bi-2223 Tapes in Electromechanical Devices (전력기기에서 $100 A/mm^2$급 Bi-2223테이프)

  • 류경우;최경주;성기철;류강식
    • Progress in Superconductivity and Cryogenics
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    • v.4 no.1
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    • pp.55-60
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    • 2002
  • $100 A/mm^2$ class Bi-2223 tapes have recently become commercially available. Some important characteristics of the tapes, e .g. critical current, ac loss, characteristics at joint, fault current characteristics, are required for an application such as a power cable or a power transformer. In this paper they have been investigated experimentally. The results indicate that the self-field loss of the high current density tapes is not negligible, compared to resistive loss in a copper wire for the same currents. In a cable, the self-field loss for relatively large currents is much larger than the magnetization loss due to an external field. But in a transformer, the magnetization loss is dominant, compared to the self-field loss. Finally the fault current characteristics show that the high current density tapes are never safe from burn-out even for fault currents with a few cycles.

Study of Multi-Step Current Lead (다단 전류도입선 해석)

  • Moon, J.S.;Seol, S.Y.
    • Proceedings of the KSME Conference
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    • 2000.04b
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    • pp.379-384
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    • 2000
  • High-Tc superconducting current leads with multi-step and continually varied cross-sectional area are studied to reduce heat leak into cryostat and material use. Assuming conduction-cooled lead the cross-sectional area is reduced along the heat flow direction according to the increase of critical current density which increases with decreasing temperature. In this study, we also analyze the multi-step cross-sectional area High-Tc current leads. The multi-st데 current leads changes the cross-sectional area to have constant safety-factor at changed section. The heat leak into cryostat, total voume, safety-factor and the temperature profiles are compared to those of the constant safety-factor current leads. The developed methods are applied to the Bi-2223 superconductor sheathed with Ag-Au alloy.

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Low Threshold Current Density and High Efficiency Surface-Emitting Lasers with a Periodic Gain Active Structure

  • Park, Hyo-Hoon;Yoo, Byueng-Su
    • ETRI Journal
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    • v.17 no.1
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    • pp.1-10
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    • 1995
  • We have achieved very low threshold current densities with high light output powers for InGaAs/ GaAs surface-emitting lasers using a periodic gain active structure in which three quantum wells are inserted in two-wavelength-thick (2${\lambda}$ ) cavity. Air-post type devices with a diameter of 20~40${\mu}m$ exhibit a threshold current density of 380~410$A/cm^2$. Output power for a 40${\mu}m$ diameter device reaches over 11 mW. A simple theoretical calculation of the threshold and power performances indicates that the periodic gain structure has an advantage in achieving low threshold current density mainly due to the high coupling efficiency between gain medium and optical field. The deterioration of power, expected from the long cavity length of $2{\lambda}$, is negligible.

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Role of Magnetic Field Configuration in a Performance of Extended Magnetron Sputtering System with a Cylindrical Cathode

  • Chun, Hui-Gon;Sochugov, Nikolay S.;You, Yong-Zoo;Soloviv, Andrew A.;Zakharov, Alexander N,
    • Journal of the Semiconductor & Display Technology
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    • v.2 no.3
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    • pp.19-23
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    • 2003
  • Extended unbalanced magnetron sputtering system based on the cylindrical magnetron with a rotating cathode was developed. The unbalanced configuration of magnetic field was realized by means of additional lines of permanent magnets, placed along both sides of a 89 mm outer diameter and 600 mm long cylindrical cathode. The performance of the unbalanced magnetron was assessed in terms of the ion current density and the ion-to-atom ratio incident at the substrate. Furthermore, the paper presents the comparison of the internal plasma parameters, such as the electron temperature, electron density, plasma and floating potentials, measured by a Langmuir probe in various positions from the cathode, for conventional and unbalanced constructions of the cylindrical magnetron. The plasma density and ion current density are about 3-5 times higher than those of conventional one, in the unbalanced magnetron in a 0.24 Pa Ar atmosphere with a DC cathode power of 3 kW.

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Influences of Electrodeposition Variables on Mechanical Properties of Ni-Mn Electrodepositions (Ni-Mn 전착층의 기계적 성질에 미치는 공정조건의 영향)

  • Shin, Ji-Wung;Yang, Seung-Gi;Hwang, Woon-Suk
    • Corrosion Science and Technology
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    • v.13 no.3
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    • pp.102-106
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    • 2014
  • Nickel electrodeposition from sulfamate bath has several benefits such as low internal stress, high current density and good ductility. In nickel deposited layers, sulfur induces high temperature embrittlement, as Ni-S compound has a low melting temperature. To overcome high temperature embrittlement problem, adding manganese is one of the good methods. Manganese makes Mn-S compound having a high melting temperature above $1500^{\circ}C$. In this work, the mechanical properties of Ni-Mn deposited layers were investigated by using various process variables such as concentration of Mn$(NH_2SO_3)_2$, current density, and bath temperature. As the Mn content of electrodeposited layers was increased, internal stress and hardness were increased. By increasing current density, internal stress increased, but hardness decreased. With increasing the bath temperature from 55 to $70^{\circ}C$, internal stress of Ni deposit layers decreased, but hardness didn't change by bath temperature. It was likely that eutectoid manganese led to lattice deformation, and the lattice deformation increased hardness and internal stress in Ni-Mn layers. Increasing current density and decreasing bath temperature would increase a mount of $H_2$ absorption, which was a cause for the rise of internal stress.